• Title/Summary/Keyword: Pentane

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Volatile Flavor Components of Korean Sancho Fruit and Tree(Zanthoxylum schinfolium) (한국산 산초열매와 나무의 휘발성 향기성분)

  • 이종원
    • The Korean Journal of Food And Nutrition
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    • v.11 no.5
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    • pp.493-498
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    • 1998
  • An attempt was in this to analyzer volatile flavor components of sancho(Zanthoxylum schinfolium). Essential oils in sancho tree and fruit isolated by a simulataneous steam distillation (SDE) methods using n-pentane/diethyl ether as solvent. A total of 57 and 44 components were identified by gas chromatography(GC) and combined gas chromatography spectrometry (GC-MS), respectively. Granyl acetate(29.23%) geraniol (6.80%, p-isopropyl-2-chclohexenone(5.53%), phellandral (4.10%) in sancho fruit and 4, 6, 6-trimethyl-bicyclo(7.47%), T-carvelo(4.60%, ${\alpha}$-cypernone(3.58%) in sancho tree were found to be major volatile flavor. 22 compnents including myrcene, limonene, 1, 8-cinol in sancho fruit and 10 components including 4-(1-methylethyl)-cyclohexanol, methyl undecyl ketone in sancho tree were identified. The contents of unsaturated fatty acids of palmitic acid(24.34%), myristic acid(3,68%) in sancho tree was higher than that of the sancho fruit.

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Modeling of High Pressure Droplet Vaporization with Flash Phase Equilibrium Calculation (플래시 상평형 방법에 의한 고압 액적 기화 모델)

  • 이강원;윤웅섭
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2002.04a
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    • pp.65-69
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    • 2002
  • Unsteady vaporization of a droplet quiescent in a high pressure environment are studied with emphasis placed oil the modeling of equilibrium at vapor-liquid interface. Complete set of conservation equations for liquid and gas phases is numerically time integrated. Vapor-liquid interfacial thermodynamics are solved by f]ash equilibrium calculation method. The model was proper]y validated with experiment and the improvement in the solution accuracy was made. Vaporization of n-pentane fuel droplet in nitrogen background gas is examined. Effects of ambient gas solubility, property variation, transient diffusion, and multicomponent transport on the droplet vaporization are investigated systematically. High-pressure effects on the droplet vaporization is examined and discussed.

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Gaseous by-products from the TiO2 Photocatalytic Oxidation of Benzene

  • Han, Sang-Wook;Lee, Jin-Hong;Kim, Jin-Seog;Oh, Sang-Hyub;Park, Young-Kwon;Kim, Hyun-Ook
    • Environmental Engineering Research
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    • v.13 no.1
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    • pp.14-18
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    • 2008
  • Photocatalytic oxidations of benzene gas using the closed system (batch reactor) were induced to determine its by-products and investigate the effect of humidity and oxygen concentration on their generation. The study was able to identify 11 gaseous by-products: 2-methylpropene, acetaldehyde, acetone, pentane, methylcyclobutane, methylcyclopentane, cyclohexane, 2,3-dimethylbutane, 2-methylpentane, 3-methylpentane, and hexane. All the by-products were saturated hydrocarbons, which are less toxic than benzene and were probably formed through hydrogenation reaction on the photocatalytic surface. The photocatalytic oxidation of benzene under higher humidity produced less by-products. However, the amount of acetone released increased with higher humidity and oxygen concentration.

A Study on the Source Profile of Volatile Organic Compounds from Major Emission Sources (휘발성 유기화합물의 주요 배출원의 배출물질 구성비에 관한 연구-오존 생성 전구물질을 중심으로-)

  • 김소영;한진석;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.3
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    • pp.233-240
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    • 2001
  • The composition of volatile organic compounds (VOCs) was anlyzed for major emission sources such as vehicle exhaust, gasoline and diesel vapor, organic solvent vapor, and butane fuel gas. Low carbon-numbered hydrocarbons were found to be the dominant components of gasoline vehicle exhaust. In gasoline evaporative vapor, the predominant constituents were found to be butane and iso-pentane regardless of ambient air temperature. In case of diesel evaporative vapor was similar to those of gasoline evaporative vapor. The composition of organic solvent vapor from painting, ink and petroleum consisted mostly or aromatic compounds such as toluene and m, p, o-xylene. The hydrocarbon fraction of butane fuel gas. which is used by portable bunner, consisted mainly of propane (34%) and butane(70%).

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Studies on the Constituents of Korean Edible Oils and Fats - Part 6 : A Study on the Natural Antioxidants of sesame and perilla seeds - (한국산 식물식용유지의 성분에 관한 연구 - 제 6 보 : 참깨와 들깨종자유 중의 천연산화방지제에 관한 연구 -)

  • Hwang, Sung-Za;Ko, Young-Soo
    • Journal of Nutrition and Health
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    • v.15 no.1
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    • pp.30-38
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    • 1982
  • Experiments were carried out in order to compare the natural antioxidants in the acetonitril extracts of raw and baked seeds of Korean sesame and perilla by thin layer and gas chromatography. The sample was dissolved in n-pentane and extracted with acetonitril and the acetonitril extract was separated by thin layer chromatography using silica gel. The spots were detected by spraying with 2, 6 -dichloroquinone -4-chlorimide, phosphomolybdic acid and dimethylamine as chromogenic reagents. Natural antioxidant, such as ${\delta}-tocopherol$ detected in raw and baked sesame and perilla seed oil by TLC and sesamol was detected only in raw and baked sesame seed oil by GC.

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Study on Analysis of Volatile Organic Compounds (VOCs) in Water (수중 휘발성 유기물질의 분석에 관한 연구)

  • 전옥경;서병태;이정자;이덕행
    • Journal of Environmental Health Sciences
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    • v.19 no.2
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    • pp.16-22
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    • 1993
  • In recent years, great concern for the improvement of drinking water quality has been arising due to the contamination of the raw and treated water. So trihalomethanes (THMs) and some other volatile organic compounds (VOCs), potential carcinogenic substances, rendered the government to take some countermeasurements for clean water service in the dimension of public health. In this study, we used liquid-liquid extraction method as a rapid simple method for determination of VOCs through eluation with n-Pentane in water. The aim with the present study has been to determine the changes of recovery and reproducibility of the method under the various conditions in extraction solvents, solvent ratio and extraction time, and to observe the concentrations under the various temperature and pH during storage.

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Separation of Ether-Soluble Neutral Extract of a Commercial High-Grain Feed Stimulating Hay Intake in Cattle

  • Shahjalal, M.;Dohi, H.;Kosako, T.;Hayashi, Y.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.2
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    • pp.188-191
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    • 2000
  • Appetite stimulant ether-soluble neutral extract of a high-grain compound feed was separated into four fractions with an open column of silica gel chromatograph using four carrier solutions containing n-pentane and diethyl ether as 100:0 (Fraction A), 90:10 (Fraction B), 75:25 (Fraction C) and 0:100 (Fraction D). The stimulative effects of the fractions were examined by comparing the intake of hay (with or without the fractions) in two-choice test bioassays with cattle. The Fractions A, B and C of the neutral extract stimulated (p<0.05) hay consumption in cattle, whereas Fraction D had no effect on selective feeding when compared with the control fraction. Furthermore, Fractions A, B and C had higher (p<0.05) feeding stimulative indices (FSI) than that of the Fraction D. The results suggest that chemical stimulants to increase palatability of hay are present in the neutral Fractions A, B and C of high-grain concentrate.

New clathration behaviors of structure-H hydrate formers (구조-H 가스 하이드레이트의 새로운 포접 현상 규명)

  • Lee, Jong-Won;Lu, Hailong;Moudrakovski, Igor L.;Ratcliffe, Christopher I.;Ripmeester, John A.
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.577-580
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    • 2007
  • 분자 크기가 너무 커 가스 하이드레이트를 형성하지 않는다고 알려진 n-펜탄과 n-헥산이 다른 구조-H 형성 화합물과 혼합되어 사용될 경우 구조-H 동공 내에 함께 포접되는 것으로 확인되었다. 구조-H 하이드레이트의 형성 및 미세구조 분석은 고체 NMR 및 X-선 회절 분광법을 이용하여 확인하였다. 이러한 혼합 화합물에서 보이는 구조-H 하이드레이트 형성은 전체적인 구조-H 형성 화합물에서 나타나는 일반적 특징인 것으로 여겨진다.

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A Study of the Gas Liquid Partition Coefficients of Eleven Normal, Branched and Cyclic Alkanes in Sixty Nine Common Organic Liquids: The Effect of Solute Structure

  • Cheong, Won-Jo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.459-468
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    • 2002
  • Literature data measured by the author have been processed to report on the effect of solute structure on gas liquid partition coefficients of eleven normal, branched and cyclic alkanes ranging in carbon number from five to nine in sixty nine low molecular weight liquids. The alkane solutes are n-pentane(p), n-hexane(hx), n-heptane(hp), n-octane(o), n-nonane(n), 2-methylpentane(mp), 2,5-dimethylpentane(dp), 2,5-dimethylhexane(dh), 2,3,4-trimethylpentane(tp), cyclohexane(ch), and ethylcyclohexane(ec). The solvent set encompasses most of those studied by Rohrschneider as well as three homologous series of solvents (n-alkanes, 1-alcohols and 1-nitriles) and several perfluorinated alkanes and highly fluorinated alcohols. An excellent linear relationship was observed between lnK and the carbon number of n-alkanes. The effective carbon numbers of branched and cyclic alkanes were determined in a similar fashion to the method of Kovats index. We found that the logarithm of solute vapor pressure multiplied by solute molar volume was a perfect descriptor for the linear relationship with the median effective carbon number.

A Study on Selecting Criteria of Working Fluid in Loop Heat Pipes with a Circular Plate Type Evaporator

  • Nguyen, Xuanhung;Sung, Byung-Ho;Choi, Jee-Hoon;Jo, Jung-Rae;Yim, Kwang-Bin;Kim, Chul-Ju
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.309-314
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    • 2008
  • increased heat dissipation and higher heat density of electronic equipment and/or parts released. A loop heat pipe(LHP) has been payed closer attention to the potential candidate of an electronic cooling. As of the LHP with a circular plate type evaporator developed, this study focused on its operating characteristics on the steady state in accordance with charging different working fluid. The relationship between working fluid and operating characteristics is discussed.

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