• Title/Summary/Keyword: Pegmatite

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K-Ar Ages of Mineral Deposits in the Taebaeg Mountain District (태백산지역내(太白山地域內) 광상(鑛床)의 생성연령(生成年齡))

  • Park, Hee-In;Chang, Ho Wan;Jin, Myung Shik
    • Economic and Environmental Geology
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    • v.21 no.1
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    • pp.57-67
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    • 1988
  • K-Ar age determinations were carried out on muscovite and other gangue and wallrock alteration minerals from seventeen mineral deposits in the Taebaeg mountain district. Tin deposits give the ages of 1792 Ma and 158-127 Ma, whereas tungsten-molybdenum deposits give the ages of 1520-1480 Ma. 173-168 Ma and 84-81 Ma. Polymetallic mineral deposits. gold-silver deposits and sericite deposits yield the ages of 98-52 Ma. 93-75 Ma, and 202 Ma, respectively. Mineralization ages for each genetic type of deposits in this district can be summarized as follows; pegmatite deposits. 1792 Ma ; pegmatite-hydrothermal deposits. 1526-1480 Ma ; greisen deposits. 157-127 Ma ; skarn deposits, 98-73 Ma and 52 Ma ; hydrothermal deposits, 202-168 Ma and 93-76 Ma. Present results together with data available in the literature reveal that five distinct mineralization ages can be recognized in this district ; (1) 1792 Ma, (2) 1526-1480 Ma, (3) 202-127 Ma. (4) 98-73 Ma, (5) 52 Ma, These age data are similar to the reported radiometric age data of igneous rocks in this district except for two ages such as 2154-2084 Ma and 880-738 Ma.

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Time-relationship between Deformation and Growth of Metamorphic Minerals around the Shinbo Mine, Korea: the Relative Mineralization Time of Uranium Mineralized Zone (신보광산 주변지역에서 변성광물의 성장과 변형작용 사이의 상대적인 시간관계: 우라늄 광화대의 상대적인 광화시기)

  • Kang, Ji-Hoon;Lee, Deok-Seon
    • Economic and Environmental Geology
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    • v.45 no.4
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    • pp.385-396
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    • 2012
  • The geochemical high-grade uranium anormal zone has been reported in the Shinbo mine and its eastern areas, Jinan-gun, Jeollabuk-do located in the southwestern part of Ogcheon metamorphic zone, Korea. In this paper is reported the time-relationship between deformation and growth of metamorphic minerals in the eastern area of Shinbo mine, which consists of the Precambrian metasedimentary rocks (quartzite, metapelite, metapsammite) and the age-unknown pegmatite and Cretaceous porphyry which intrude them, and is considered the relative mineralization time on the basis of the previous research's result. The D1 deformation formed the straight-type Si internal foliation which is defined mainly as the arrangement of elongate quartz, biotite, opaque mineral in andalusite porphyroblast. The D2 deformation, which is defined by the microfolding of Si foliation, formed S2 crenulation cleavage. It can be divided into two sub-phases, early crenulation and late crenulation. The former occurs as the curvetype Si foliation in the mantle part of andalusite. The latter occurs as S1-2 composite foliation which warps around the andalusite. The andalusite porphyroblast began to grow under non-deformation condition after the formation of S1 foliation which corresponds to the straight-type Si foliation. It continued to grow before the late crenulation phase. The age-unknown pegmatite intruded after the D2 deformation and grew the fibrous sillimanite which random masks the S1-2 composite foliation. The D3 deformation formed F3 fold which folded the S1-2 composite foliation, D2 crenulation, fibrous sillimanite. It means that the intrusion of pegmatite related to the growth of the fibrous sillimanite took place during the inter-tectonic phase of D2 and D3 deformations. The retrograde metamorphism is recognized by the chloritization of biotite and two-way cleavage lamellae which is parallel to the S1-2 composite foliation and the F3 fold axial surface in the andalusite porphyroblast. It occurred during the D2 late crenulation phase and D3 deformation. In considering of the previous research's result inferring the most likely candidate for the uranium source rock as pegamatite, it indicates that the age-unknown pegmatite intruded during the inter-tectonic phase of D2 and D3 deformations, i.e. during the retrograde metamorphism related to the uplifting of crust, and formed the uranium ore zone around the Shinbo mine.

Fluid Inclusions Trapped in Tourmaline from the Daeyou Pegmatite Deposit, Jangsu-Gun, Jeollabukdo (전북 장수군 대유 페그마타이트광산의 전기석에 포획된 유체포유물)

  • Lee, Ju-Youn;Eom, Young-Bo;Nam, Bok-Hyun;Hwang, Byoung-Hoon;Yang, Kyoung-Hee
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.1 s.51
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    • pp.7-19
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    • 2007
  • Four types of fluid inclusions are trapped within tourmaline from Daeyou pegmatite, Jangsu-Gun, Jeonllabukdo. They range $5{\sim}100\;{\mu}m$ in size and are grouped into I, II, III, and IV based on the phase behavior at the room temperature: (1) Type I inclusions are liquid-rich and NaCl equivalent salinity ranged $0{\sim}12\;wt%$, and the homogenization temperatures (Th) ranged $181{\sim}230^{\circ}C$ with eutectic temperatures (Te) $-54{\sim}-22^{\circ}C$. (2) Type II inclusions are vapor-rich and salinity ranged $3{\sim}8\;wt%$ NaCl, and Th ranged $177{\sim}304^{\circ}C$ also showing Te $-54{\sim}-29^{\circ}C$. (3) Type III inclusions contain a halite daughter mineral with $31{\sim}40\;wt%$ NaCl, Th $230{\sim}328^{\circ}C$. More than 90% of Type III homogenize by halite dissolution and are spatially associated with silicate melt inclusions. (4) Type IV inclusions are $CO_{2}$-bearing containing various daughter minerals such as sylvite and/or halite. The density of $CO_{2}$ system within the Type IV is $0.80{\sim}0.75\;g/cm^{3}$, Th $190{\sim}317^{\circ}C$, and salinity $2{\sim}35\;wt%$ NaCl. Type III fluid inclusions, considered as the earliest fluid, formed from the fluid exsolved from the crystallizing pegmatite. It is suggested that Type II fluid in the central part of tourmaline were exsolved earlier than Type I fluids in the margin indicating salinity fluctuation during the growth of tourmaline. It implies the fluctuation of the pressure since the salinity of fluid exsolved from the crystallizing melt is governed by the pressure. The last fluid was Type IV, which may be derived from the nearby limestone and metasedimentary rocks. It is suggested that Daeyou pegmatite containing muscovite without miarolitic cavities was formed by the partial melting resulted from the regional metamorphism. Subsequently, the exsolving fluids from the crystallizing melt were trapped in tourmaline at high pressure condition. The exsolved fluids contain various components such as $CaCl_{2}\;and\;MgCl_{2}$ as well as NaCl and KCl. The exsolution began at least at $2.7{\sim}5.3\;kbar\;and\;230{\sim}328^{\circ}C$ with the pressure fluctuation.

Mineralogy and Mineral-chemistry of REE Minerals Occurring at Mountain Eorae, Chungju (충주 어래산 일대에서 산출하는 희토류 광물의 광물학적 및 광물화학적 특성)

  • You, Byoung-Woon;Lee, Gill Jae;Koh, Sang Mo
    • Economic and Environmental Geology
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    • v.45 no.6
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    • pp.643-659
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    • 2012
  • The Chungju Fe-REE deposit is located in the Kyemyeongsan Formation of the Ogcheon Group. The Kyemyeongsan Formation includes meta-volcanic rocks and pegmatite hosted REE deposit which show different kind of REE-containing minerals. The meta-volcanic rocks hosted REE deposits' main REE minerals are allanite, zircon, apatite, and sphene, whereas the pegmatite hosted REE deposits is mainly composed of fergusonite, and karnasurtite, zircon, thorite. The meta-volcanic rock hosted major REE mineral is allanite as the form of aggregation and contains 23.89-29.19 wt% TREO (Total Rare Earth Oxide), 4.71-9.92 wt% $La_2O_3$, 11.30-14.33 wt% $Ce_2O_3$, 0.11-0.29 wt% $Y_2O_3$, 0.15-0.94 wt% $ThO_2$, as a formula of (Ca, Y, REE, Th)$_{2.095}$(Mg, Al, Ti, Mn, $Fe^{3+})_{2.770}(SiO_4)_{2.975}(OH)$. Accompanying REE in a coupled substitution for $Ca^{2+}$ (M1 site) and $Al^{3+}-Fe^{2+}$ (M2 site) leads to a large chemical variety. Due to the allanite's high contents of Fe, it belongs to Ferrialanite. The pegmatite hosted deposit's domi-nant REE mineral is fergusonite as prismatic or subhedral grains associated with zircon, fluorite and karnasurtite. Geochemical composition of the fergusonite($YNbO_4$) suggests substitution of Y-REE and Y-Th in A-site, and Nb-Ta-Ti in B-site, furthermore the proportion of $Y_2O_3$ and $Nb_2O_5$ is oddly 1:1.5 comparing to the ideal ratio 1:1 and Nb is higher than Y, also A-site Y actively substitutes with REE. Karnasurtite in pegmatite variously ranges 9.16-22.88 wt% $Ce_2O_3$, 2.15-9.16 wt% and $La_2O_3$, 0.44-10.8 wt% $ThO_2$, as a calculated formula (Y, REE, Th, K, Na, Ca)$_{1.478}(Ti, Nb)_{1.304}$(Mg, Al, Mn, $Fe^{3+})_{0.988}$(Si, P)$_{1.431}O_7(OH)_4{\cdot}3H_2O$. Firstly the 870-860 Ma is the initial age of the supercontinent Rhodinia dispersal and subsequent A-1 type volcanism, which contains Fe, REE, and HFS(High Field Strength elements; Nb, Zr, Y etc.) elements in Fe-rich meta-volcanic rocks dominant Kyemyeongsan Formation, might mineralized allanite. Another synthesis is that regional metamorphism at late Paleozoic 300-280 Ma(Cho et al., 2002) might cause allanite mineralization. Also pegmatite REE mineralization highly related to the granite intrusion over the Chungju area in Jurassic(190 Ma; Koh et al., 2012). Otherwise above all, A-1 type volcanism at the same time of the Kyemyeongsan Formation development, regional metamorphism and pegmatite, might have caused REE mineralization. Although REE ore bodies display a close spatial association, each ore bodies display temporal distinction, different mineral assemblage and environment of ore formation.

Major Molybdenum Mineralization and Igneous Activity, South Korea (남한의 주요 몰리브덴 광화작용과 화성활동)

  • Choi, Seon-Gyu;Koo, Min-Ho;Kang, Heung-Suk;Ahn, Yong-Hwan
    • Economic and Environmental Geology
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    • v.44 no.2
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    • pp.109-122
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    • 2011
  • The major Mo deposits in South Korea were formed during the Jurassic Daebo orogeny, the Late Cretaceous and the Tertiary post-orogenic igneous activities, and are characterized by a variety of genetic types such as pegmatite, greisen, skarn, porphyry and vein types. The Jangsu mine is a pegmatite-style deposit which is genetically related to the Jurassic ilmenite-series two-mica granite with the Mo mineralization age of $159.6{\pm}4.5$ Ma. The Geumseong mine occurs as a skarn/porphyry-style deposit associated with highly fractionated granite. Its age of Mo mineralization within aplitic cupola is about 96.5~l07.5 Ma. The Yeonil mine is a porphyry-style deposit, and the Geumeum mine is a veinlet-style deposit along the fracture zone with their mineralization ages of $58.4{\pm}1.6$ and $54.4{\pm}1.2$ Ma, respectively. The contrasts in the style of Mo mineralization in Korea reflect the different environment of the related magmatism. The Jurassic mineralization, being related to deep-seated granitoids, occurs as a pegmatite-style deposit, whereas the Cretaceous one, being related to subvolcanic granitoids, occurs as skarn/porphyry/vein-type ore deposits. The Tertiary Mo mineralization has a close relationship with the igneous activities associated with the Tertiary basin formation along the east coast, Korean peninsular.

Effects of Dietary Pegmatite, Precious Stone and Grape Pomace Extracts on the Meat Quality of Pigs (거정석, 옥돌 및 포도박 추출물 첨가 급여가 돈육의 육질에 미치는 영향)

  • Kim, Dong-Yeop;Han, Gi-Dong
    • Food Science of Animal Resources
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    • v.30 no.2
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    • pp.252-260
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    • 2010
  • A 90-d trial was conducted to determine the influence of additives such as pegmatite (Peg), precious stone (PS), grape pomace extracts (GPEx) and complexes of these additives (Peg + GPEx and PS + GPEx) via evaluation of meat quality including sensory properties in 90 d old finishing pigs. There were no significant differences in the approximate composition and physiochemical characteristics, including meat color, among the treated groups. However, the Peg treated group was found to have a higher water holding capacity than the other groups. The shear-force was evaluated as an indicator of hardness and found to be lower in the Peg and GPEx treated groups, and this tendency was greater when the complex of Peg and GPEx was supplied. No significant differences were observed among groups following analysis of the free amino acid composition and fatty acid (FA) composition. Sensory evaluation of the boiled loins showed significantly (p<0.05) better results from pigs fed diets containing Peg and GPEx complex. These results suggest that Peg may improve the water holding capacity and tenderness. In addition, supplementation with a complex of Peg and GPEx may improve tenderness.

Effects of Dietary Addition of Pegmatite on the Meat Quality Characteristics of Hanwoo Steers (거정석 첨가급여가 거세한우육의 품질 특성에 미치는 영향)

  • Kim, Byung Ki;Ha, Jae Jung;Lee, Jun Koo;Oh, Dong Yeop;Jung, Dae Jin;Kim, Dae Hyun;Hwang, Eun Gyeong
    • The Korean Journal of Food And Nutrition
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    • v.30 no.6
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    • pp.1235-1244
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    • 2017
  • The purpose of this study was to investigate the effect of dietary addition of pegmatite for Hanwoo steers on the carcass characteristics. Based upon the findings yielded by the research referenced above, the results may be summed up as follows : Oleic acid was for the most part, higher as T2 plots (45.40%) and T3 plots (44.20%) compared with Con. plots (42.50%). As well, this study has shown that the treatment plots in unsaturated fatty acid (UFA), monounsaturated fatty acid (MUFA) and polyunsaturated fatty acid (PUFA) were largely higher than that of Con. plots, and of them all, T2 plots were highest. As for the melting point of fat, T2 plots ($29^{\circ}C$) were largely lower than that of Con. plots ($31.9^{\circ}C$). This study has shown that the treatment plots were significant higher as the content of total essential amino acid and total amino acid and inosine monophosphate in the nucleotide compound for the Hanwoo beef was treatment plots when compared with Con. plots.

Geology and Mineralization of Mwanza and Kongolo in DR Congo Tin belt (콩고민주공화국 무완자-콩골로 지역 주석광화대의 지질 및 광화작용)

  • Yang, Seok-Jun;Park, Sung-Won;Koh, Sang-Mo
    • Economic and Environmental Geology
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    • v.45 no.6
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    • pp.709-719
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    • 2012
  • Prospection was performed on the tin mineralized belt in Mwanza and Kongolo areas of Katanga, DR Congo. Most of deposits in Katanga areas are related to the granites which are located in Kibaran belt in NE and SW trends of mid Proterozoic. Metasedimentary rocks in the Kibaran belt are intruded by granites, and tin, niobium and tantalum deposits are especially developed along with tin-granite. Cassiterite, coltan and gold are developed in the pegmatite, quartz vein and greisen in related to the tin-granite in Mwanza and Katanga areas, and they are exploited by artisan in the smale scale. And we conducted the works with the alluviums and stream sediments in the case of no outcrops. With the results of analysis of samples, we will choose a few potential mineralized zones and con-tinue to prosepect precisely.

K-Ar age of the Tin-bearing Pegmatite In Sungyeong Mine (순경(順鏡) 함주석(含朱錫) 페그마타이트의 K-Ar연령(年齡))

  • Jin, Myung-Shik;Kim, Seong-Jae
    • Economic and Environmental Geology
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    • v.21 no.2
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    • pp.171-174
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    • 1988
  • A muscovite and a sericite altered from plagioclase taken from the Sungyeong tin-bearing pegmatite near the Sangdong mine are dated by K-Ar method. The muscovite and the sericite yield $1546.94{\pm}29.4\;Ma$ and $187.80{\pm}4.19\;Ma$,respectively. The muscovite age can be assumed to become younger than the previously reported K-Ar muscovite ages of the pegmatites around this area, because radiogenic argon in the muscovite could be partially lost by the heat of later hydrothermal activities which caused the plagioclase to be sericitized in the Jurassic time (about 190 Ma).

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The characteristics of zircon as the evidence for post-magmatic remobilization of REE and HFSE in the northern Motzfeldt alkaline igneous complex, southern Greenland

  • Kim, Eui-Jun;Yang, Seok-Jun;No, Sang-Gun;Park, Sung-Won;Lee, Seung Ryeol;Kim, You-Dong;Jo, Jinhee
    • Geosciences Journal
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    • v.22 no.6
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    • pp.921-938
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    • 2018
  • The Motzfeldt intrusions in the Gardar Province, southern Greenland, split into syenitic plutonic and hypabyssal rocks, in which the latter include ring dykes and sheet intrusions. Sheet intrusions, considered as the source for rare earth elements (REE) and high field strength elements (HFSE), comprise sheets of peralkaline microsyenite (SPM), syenitic pegmatite (SP), and peralkaline microsyenite (PM). SP exhibits extremely high concentrations of REE and HFSE, which are positively correlated with increasing alkalinity from early towards late intrusion, caused by magmatic processes. In contrast, some of the SPM and PM are also significantly enriched in REE and HFSE, caused by post-magmatic fluids. The REE- and HFSE-rich phases in SP consist mainly of zircon and allanite with smaller amounts of pyrochlore in pseudomorph from the inferred eudialyte, whereas some of the PM and SPM consist of pyrochlore, REE-carbonate, and zircon in the matrix. The zircon grains in the Motzfeldt Sø Formation (MSF) syenite occur in interstitial spaces, exhibiting an association with magnetite and a bipyramidal form in texture. They are characterized by a highly fractured and embayed rim. Zircons from PM and SP are clearly enriched in Fe, Al, Ca, Na, Y, P, Hf, Y, P, Nb, Ta, and REE, and are depleted in Zr and Si in comparison with magmatic zircon. They also show a clear trend of higher LREE/HREE and $Eu/Eu^{\star}$ ratios, and lower $Ce/Ce^{\star}$ ratios, which define them as typical hydrothermal zircons. In contrast, zircons from the MSF syenite show a relatively lower LREE/HREE ratio and Eu and Ce anomalies of a similar magnitude compared with those from SP and PM. The occurrence and mineral composition of the zircon suggest that post-magmatic fluids have played an important role in the remobilization of REE and HFSE as well as the primary concentration of REE and HFSE, caused by magmatic processes.