• 제목/요약/키워드: Peak current density

검색결과 239건 처리시간 0.024초

The effect electrolysis conditiong on the composition and the preferred orientation of Co-Fe-Cr alloy electrodeposits (Co-Fe-Cr 합금도금층의 조성 및 우선방위에 미치는 전해조건의 영향)

  • 예길촌;문근호
    • Journal of the Korean institute of surface engineering
    • /
    • 제31권6호
    • /
    • pp.393-399
    • /
    • 1998
  • The composition and the properred orientation of Co-Fe-Cr alloy electrodeposits were invesigated according to the electrolysis conditions using sulface bath. The current efficiency and the cathode overpotential decrased noticeably with the increase of Cr content in the bath. As the D.C. current density increased increased, the Cr content in the alloy increasd, while Co content decreased and Fe content remained constant, In the pulse current electrolysis, the Cr content of the alloy increased with the mean current density and off-time and then its content increased mord more noticeably with the peak current density than that of D.C. electrolysis. The preferred orientation of the alloy changed from (220)+(111) to (220) with decreasing cathode overpotential.

  • PDF

Thermally Stimulated Current from High Density Polyethylene Treated by a High Field Application (고전계인가처리된 고밀도 폴리에티렌의 열자극전류)

  • 이덕출
    • 전기의세계
    • /
    • 제27권3호
    • /
    • pp.31-35
    • /
    • 1978
  • In this paper, in order to clarify the mature of traps in polymer, the thermally stimulated current (TSC) measurements were mad on high density polyethylene by changing the condition of the high-field treatment such as the strength of the field (Fe), the treatment time (te) and the heating rate (.betha.). In addition, the TSC measured from the HDPE was compared with that from LDPE having different crystallinity. The obtained results can suggest that the trapping proceeds during the high-field treatment and the trap associated with the peak P$_{2}$ may have the closed relation to drystallinity and the release of trapped charge is enhanced by the molecular motion.

  • PDF

Redox Reaction of Poly(ethyleneterephthalate) Polymer in Aprotic Solvent

  • Choi, Chil-Nami
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • 제10권S_1호
    • /
    • pp.47-53
    • /
    • 2001
  • We carroed our to measure the variations of potential with current density (polarization curves) for poly(ethyleneterephthalate). The results were particularly examined to identify the influences on corrosion potential and corrosion rate of various factors including temperature, pH, exposure time, salt, and enzyme. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum passive current density were designated as the relative corrosion sensitivity$(I_r/I_f)$. The mass transfer coefficient value$(\alpha)$ was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

  • PDF

Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • 제4권3호
    • /
    • pp.165-171
    • /
    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

  • PDF

The Change of Composition and the Throwing Power of Pb-Sn Alloy Electrodeposits in Pulse Plating (파형전류전해에 의한 Pb-Sn합금의 조성변화 및 균일전착력)

  • 예길촌;김용웅
    • Journal of the Korean institute of surface engineering
    • /
    • 제22권4호
    • /
    • pp.197-206
    • /
    • 1989
  • The Composition and throwing power-of Pb-Sn alloy deposits are investigated in tems of the pulse parameters in pulse plating. Microhardness and intermal srress of alloy deposots are measured. The current efficiency of pulse plating is lower than that of D.C.plating while cathode overpotential and macro-throwing power noticebly increase with increasing peak current density. The Pb content of P.C. plated alloy deposits with increasing average current density, is relatively lower than of D.C. plated deposits at the same average current density. The internal stress of Pb-Sn alloy is not detected and the microhardness are 9.0kg/mm2 and 11kg/mm2 for D.C. plated P.C. plated deposits, respectively.

  • PDF

An Automatic Power Control Circuit suitable for High Speed Burst-mode optical transmitters (고속 버스트 모드 광 송신기에 적합한 자동 전력 제어 회로)

  • Ki, Hyeon-Cheol
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • 제43권11호
    • /
    • pp.98-104
    • /
    • 2006
  • The conventional burst-mode APC(Automatic Power Control) circuit had an effective structure that was suitable for a low power consumption and a monolithic chip. However, as data rate was increased, it caused errors due to the effect of the zero density. In this paper, we invented a new structured peak-comparator which could compensate the unbalance of the injected currents using double gated MOS and MOS diode. And we proposed a new burst-mode APC adopting it. The new peak-comparator in the proposed APC was very robust to zero density variations maintaining the correct decision point of the current comparison at high data rate. It was also suitable for a low power consumption and a monolithic chip due to lack of large capacitors.

Influence of Corrosion Potential and Current Density on Polarization Curve Variations using Polycarbonate[III]

  • Park, Chil-Nam;Yang, Hyo-Kyung;Kim, Sun-Kyu;Kim, Myung-Sun;Cheong, Kyung-Hoon
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • 제4권1호
    • /
    • pp.43-50
    • /
    • 2000
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves using polycarbonate. The results were particularly examined to identify the influences affecting the corrosion potential including various conditions such as temperature, pH, catalytic enzyme, and salt. The lines representing the active anodic dissolution were only slightly shifted in the potential direction by temperature, pH, enzyme, and salt. The tafel slope for the anodic dissolution was determined based on the polarization effect with various conditions. The slope of the polarization curves describing the active-to-passive transition region were noticeably shifted in direction. Also, from the variation in the conditions, the optimum conditions were established for the most rapid transformation, including temperature, pH, corrosion rate, and resistance of corrosion potential. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity(Ir/If). The value of Ir/If was then used in measuring the extent of the critical corrosion sensitivity of the polycarbonate. The potentiodynamic parameters of the corrosion were obtained using a Tafel plot.

  • PDF

A Study of the Characteristics on the Vacuum Interrupter with Axial Magnetic Field Type using 3 Dimension Finite Element Analysis (3차원 유한요소해석을 이용한 종자게형 진공 인터럽터의 특성고찰)

  • 하덕용;강형부
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • 제15권5호
    • /
    • pp.460-467
    • /
    • 2002
  • This paper deals with the distribution characteristics of the current density and axial magnetic flux density on the vacuum interrupter with axial magnetic field type using 3 dimension finite element analysis. An axial magnetic field parallel to the current flow in the arc column can improve the current breaking capacity of vacuum interrupter by affecting the arc mode. The axial magnetic flux density on the contact electrode surface is analyzed by inputting external current as a function of the transient time for sine half wave. And it also is analyzed within the gap distance of the contact electrode. The peak value of current but is decreased with the descending current on the contact electrode surface and within the gap distance of the contact electrode. The residual magnetic field is generated on the contact electrode surface and within the gap distance in the instant of zero current, which is due to the influence of eddy currents. The phase shift due to eddy currents, defined as time difference between the maximum value of current and axial magnetic field, is about 1ms in the center point of gap distance.

Comparison with Polarization Characteristic of Polymers

  • Choi, Chil-Nam;Yabg, Hyo-Kyung
    • Proceedings of the Korean Environmental Sciences Society Conference
    • /
    • 한국환경과학회 2001년도 가을 학술발표회 발표논문집
    • /
    • pp.188-190
    • /
    • 2001
  • We carried out to measure the variations of potential with current density polymers. The results were particularly examined to identify the influences on corrosion potential and corrosion rate of various factors including temperature and pH. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum passive current density were designated as the relative corrosion sensitivity($I_{r}I_{f}$). The mass transfer coefficient value (${\alpha}$) was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

  • PDF

Corrosion Characteristics of Amorphous Alloy Ribbon ($Fe_{70}Cr_5Si_{10}B_{15}$ and $Co_{70}Cr_5Si_{10}B_{15}$) in Hydrochloric Acid Aqueous Solution

  • Choi, Chil-Nam;Hyo, Kyung-Yang;Yang, Myung-Sun
    • Proceedings of the Korean Environmental Sciences Society Conference
    • /
    • 한국환경과학회 2001년도 정기총회 및 봄 학술발표회 초록집
    • /
    • pp.236-237
    • /
    • 2001
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves with amorphous $Fe_{70}Cr_5Si_{10}B_{15}$ and $Co_{70}Cr_5Si_{10}B_{15}$ alloy ribbon. The results were particularly examined to identify the influences of corrosion potential including various conditions such as hydrochloric acid, temperature, salt, pH, and oxygen. The optimum conditions were established with variations including temperature, salt, pH, oxygen, corrosion rate, and resistance of corrosion potential. The mass tranfer coefficient(${\alpha}$) value was determined with the Tafel's slope for the anodic dissolution based on the polarization effect with optimum conditions. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity($I_{r}/I_{f}$).

  • PDF