• Title/Summary/Keyword: Pd-Sb 광물

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Mineralogical Comparison of Naldrettite and Synthetic $Pd_2Sb$ phase (날드렛타이트와 합성 $Pd_2Sb$의 광물학적 비교연구)

  • Kim Won-Sa
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.3 s.45
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    • pp.147-153
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    • 2005
  • Naldrettite, recently discovered in the Mesamax Northwest deposit, Ungava region, northern Quebec, Canada, was reported as a new mineral. In order to confirm whether itis a natural equivalent of synthetic $Pd_2Sb$ phase or not, the pure $Pd_2Sb$ phase has been synthesized and investigated by reflected microscope, electron microprobe analyser, X-ray diffractometer, and micro-indentation hardness tester. Under reflected light synthetic $Pd_2Sb$ Phase is white with a creamy tint in both air and oil and weakly bireflectant. Anisotropism is strong, from brownish gray to greenish blue in air. Micro-indentation hardness test gives VHN100=293(242-322). Composition of the phase is $63.7\~64.3wt.\%\;Pd\;and\; 36.4\~36.8wt.\%$ Sb, and is entirely consistent. The phase, quenched from $500^{\circ}C$, is orthorhobic with space group $Cmc2_1$, and the cell parameters are a=3.366(1), b=17.523(3), c=6.929(2) ${\AA}$. All mineralogical properties of synthetic $Pd_2Sb$ compare very well with those of naldrettite, confirming that naldrettite is the natural analogue of the synthetic $Pd_2Sb$ phase.

Phase Equilibria of the System Pd-Sb-Te and Its Geological Implications (팔라듐-안티몬-테루르 계(系)의 상평형(相平衡)과 지질학적(地質學的) 의의(意義))

  • Kim, Won-Sa;Chao, George Y.
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.327-335
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    • 1993
  • Phase relations in the system Pd-Sb-Te were investigated at $1000^{\circ}$, $800^{\circ}$, and $600^{\circ}C$, using the sealed-capsule technique; the quenched products were studied by reflected light microscopy, X-ray diffraction, and electron microprobe analysis. At $1000^{\circ}C$, the solid phases Pd, $Pd_{20}Sb_7$, $Pd_8Sb_3$, $Pd_{31}Sb_{12}$, and $Pd_5Sb_2$ are stable with a liquid phase that occupies most of the isothermal diagram. Additional solid phases at $800^{\circ}C$ are $Pd_5Sb_3$, PdSb, $Pd_8Te_3$, $Pd_7Te_3$, and a continuous $Pd_{20}Te_7-Pd_{20}Sb_7$ solid solution becomes stable. At $600^{\circ}$, $PdSb_2$, $Pd_{17}Te_4$, $Pd_9Te_4$, PdTe, $PdTe_2$, $Sb_2Te_3$, and Sb and continuous PdSb-PdTe and $PdTe-PdTe_2$ solid solutions are stable. All the solid phases exhibit solid solution, mainly by substitution between Sb and Te to an extent that varies with temperature of formation. The maximum substitution (at.%) of Te for Sb in the Pd-Sb phases is: 44.3 in $Pd_8Sb_3$, 52.0 in $Pd_{31}Sb_{12}$, 46.2 in $Pd_5Sb_2$ at $800^{\circ}C$; 15.3 in $Pd_5Sb_3$, 68.3 in $PdSb_2$ at $600^{\circ}C$. The maximum substitution (at.%) of Sb for Te in the Pd-Te phases is 34.5 in $Pd_5Sb_3$ at $800^{\circ}C$, and 41.6 in $Pd_7Te_3$, 5.2 in $Pd_{17}T_4$, 12.4 in $Pd_9Te_4$, and 19.1 in $PdTe_2$ at $600^{\circ}C$. Physical properties and X-ray data of the synthetic $Pd_9Te_4$, PdTe, $PdTe_2$, $Pd_8Sb_3$, PdSb, and $Sb_2Te_3$ correspond very well with those of telluropalladinite, kotulskite, merenskyite, mertieite II, sudburyite, and tellurantimony, respectively. Because X-ray powder diffraction data consistently reveal a 310 peak ($2.035{\AA}$), the $PdSb_2$ phase is most probably of cubic structure with space group $P2_13$. The X-ray powder pattern of a phase with PdSbTe composition, synthesized at $600^{\circ}C$, compares well with that of testibipalladite. Therefore, testibiopalladite may be a member of the $PdSb_2-Pd(Sb_{0.32}Te_{0.68})$ solid solution series which is cubic and $P2_13$ in symmetry. Thus the ideal fonnula for testibiopalladite, presently PdSbTe, must be revised to PdTe(Sb, Te). Borovskite($pd_3SbTe_4$) has not been found in the synthetic system in the temperature range $1000^{\circ}-600^{\circ}C$.

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Phases and Phase Relations of the System Pd-Sb (팔래듐-안티모니계의 화합물 및 상평형 연구)

  • 김원사
    • Journal of the Mineralogical Society of Korea
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    • v.8 no.1
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    • pp.13-22
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    • 1995
  • Phase relations of the Pd-Sb system were investigated using the sealed-capsule technique; the quenched run products were studied by reflected light microscopy, X-ray diffraction, and electron microprobe analysis. Eight binary phases were confirmed to exist in the system: Pd20Sb7, Pd31Sb12, Pd8Sb3 (mertieite II), Pd5Sb2, Pd2Sb, Pd5Sb3, PdSb (sudburyite), and PdSb2, (unnamed PdSb2), The X-ray powder diffraction data of all the phases, except for Pd5Sb3, however, may be indexable on an orthorhombic cell, space group Cmc2, with a=3.362(1), b=17.484(7), c=6.934(2)$\AA$. Some physical properties as well as re-determined cell parameters are newly established. A revised phase relations of the Pd-Sb system are presented.

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