• 제목/요약/키워드: Pd(100)

검색결과 301건 처리시간 0.027초

Effects of Ni Addition on the Microstructures and Magnetic Properties of Fe70-xPd30Nix High-Temperature Ferromagnetic Shape Memory Alloys

  • Lin, Chien-Feng;Yang, Jin-Bin
    • Journal of Magnetics
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    • 제17권2호
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    • pp.86-95
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    • 2012
  • This study investigated the effects of adding a third alloying element, Ni, to create $Fe_{70-x}Pd_{30}Ni_x$ (x = 2, 4, 6, 8 at.% Ni) ferromagnetic shape memory alloys (FSMAs). The Ni replaced a portion of the Fe. The $Fe_{70-x}Pd_{30}Ni_x$ alloys were homogenized through hot and cold forging to gain a ~38% reduction in thickness, next they were solution-treated (ST) with annealing recrystallization at $1100^{\circ}C$ for 8 h and quenched in ice brine, and then aged at $500^{\circ}C$ for 100 h. Investigation of the microstructures and magnetostriction indicated that the greater Ni amount in the $Fe_{70-x}Pd_{30}Ni_x$ alloys reduced saturation magnetostriction at room temperature (RT). It was also observed that it was more difficult to generate annealed recrystallization. However, with greater Ni addition into the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys, the $L1_0+L1_m$ twin phase decomposition into stoichiometric $L1_0+L1_m+{\alpha}_{bct}$ structures was suppressed after the $500^{\circ}C$/100 h aging treatment. The result was that the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys maintained a high magnetostriction and magnetostrictive susceptibility (${\Delta}{\lambda}{_\parallel}{^s}/{\Delta}H$) after the alloys were aged at $500^{\circ}C$ for 100 h. This magnetic property of the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys make it suitable for application in a high temperature (T > $500^{\circ}C$) and high frequency environments.

FeCo/Pd 초격자 다층박막의 자기 및 자기광학적 특성 (Magnetic and Magneto-Optical Properties of FeCo/Pd Multilayers)

  • 김진홍;신성철
    • 한국자기학회지
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    • 제3권1호
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    • pp.56-60
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    • 1993
  • FeCo/Pd 초격자 다층박막의 FeCo 와 Pd sublayer 두께를 각각 $2.5\;{\AA}$$10.5\;{\AA}$으로 유지시키면서 FeCo sublayer 의 Fe 조성이 0에서 100% 까지 변화함에따른 포화자화값, 수직 자기이방성에너지, 보자력 및 Kerr 회전각의 파장 의존성을 조사 하였다. 포화자화값은 Fe 조성이 48 at.%부근에서 최 고치를 보였고, 수직 자기이방성에너 및 조자력은 Fe조성의 증가에따라 단조감소 하였다. Kerr 회전각은 Fe 조성의 증가에따라 감소하였는데 그 크기 및 변화의 폭은 단파장으로 갈수록 증가하였다.

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방사광 광전자 분광법을 이용한 Co-Pd 합금박막의 전자구조 연구 (Electronic Structures of Co-Pd Alloy Films Using Synchrotron Radiation Photoemission Spectroscopy)

  • 강정수;권세균;하양장;민병일;조용필;이창섭;정인범;구양모;김건호
    • 한국자기학회지
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    • 제6권6호
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    • pp.405-410
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    • 1996
  • 방사광 광전자분광법을 이용하여 $Co_{x}Pd_{100-x}$ 합금박막들(x = 0, 25, 40, 65)의 가전자띠 스펙트럼들을 측정하고, Co 3d 전자와 Pd 4d 전자들에 의한 각각의 부분스펙트럼 무게분포(partial spectral weight distribution : PSW)를 결정하였다. Co-Pd 합금박막에서의 Co 3d PSW는 수직자기이방성을 나타내는 영역에 해당하는 Co 함량 25% 이하에서 순수 Co 박막의 스펙트럼과 상당히 다른 구조를 보인 반면, Co 함량이 약 40% 이상이 되면 순수 Co 박막의 PES스펙트럼과 거의 일치하였다. Co 함량이 25% 이하의 Co 3d PSW에서 관찰된 페르미준위 근처의 봉우리 구조와 결합에너지 2 eV 근처의 어깨구조는 혼성에 의한 Co 3d 전자구조의 변화를 반영한다. 따라서 Co 3d 전자와 Pd 4d 전자 간의 혼성상호작용이 수직자기이방성의 결정에 중요한 역할을 하는 것으로 추측되었다. Co-Pd 합금박막에서의 Pd 4d PSW는 순수 Pd 스펙트럼에 비하여 그 폭이 넓고, 주 봉우리의 결합에너지가 크며, 페르미준위에서의 스펙트럼의 세기가 작게 관찰되었다. 그리고 Pd 함량이 감소함에 따라 Pd 4d PSW의 반치폭이 증가하였는데, 이러한 결과는 Co-Pd 합금이 형성될 때의 무질서 효과 또는 Co 3d 전자와 Pd 4d 전자간의 혼성상 호작용으로 인한 Pd 4d 전자구조의 변화를 반영하는 것으로 추측되었다.

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초전도 테이프 기판을 위한 PtPd 합금의 압연 및 재결정 정렬에 대한 Pd 첨가물의 영향 (Effect of Pd impurity on the Cube-texture in Cold Rolled and Recrystallized PtPd alloy for the Application to RABiTS)

  • 유재은;염도준
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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    • pp.292-295
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    • 1999
  • We investigated the effects of Pd impurities on cube-textures in cold rolled and recrystallized PtPd tapes The sample were made from Pt$_{1-x}Pd_x$ alloys (x from 0 to0.34) by rolling at low temperature. The thickness of the tapes were about 100 ${\mu}$m. The PtPd[111] pole figures of X-ray Diffraction for all the samples indicated similar deformed textures. But the recrystallized textures after annealing showed that a better cube texture was formed in the sample of larger x. The final textures were sensitive to annealing time and temperature when x was increased.

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초광대역과 단일주파수(협대역) UHF 부분방전 검출기법 비교 (Ultra-wide bandwidth versus narrow bandwidth PD detection techniques for UHF partial discharge monitoring system)

  • 박기준;구선근;윤진열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 C
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    • pp.1655-1657
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    • 2002
  • Ultra-wide bandwidth (UWB), narrow bandwidth (single frequency), and a combination of both technologies have been studied for the ultra-high frequency (UHF) partial discharge (PD) monitoring system as a detection scheme. We have experimentally compared those detection methods using a mock-up of 362 kV class single phase gas-insulated switchgear (GIS) and a stable PD source. A rolling-ball type PD cell that produces PDs of about 10 pC, is placed at one end of the GIS. An internal UHF PD sensor was attached several meters away from the PD source. The PD spectrum was measured up to 3 GHz. A useable bandwidth of more than 1 GHz was used to measure UWB signals from the PD. To simulate the narrow bandwidth scheme a bandwidth of 100 kHz centered at several different frequencies was used.

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Co gas 검지용 ZnO/$PdCl_2$계 가스센서의 특성 (The characteristics of ZnO/$PdCl_2$ gas sensor to CO gas)

  • 홍형기;김봉희;천영일;이철진;성영권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1990년도 추계학술대회 논문집 학회본부
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    • pp.139-142
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    • 1990
  • A gas sensor, comprised of both ZnO and $PdCl_2$ powders, has been developed to sense the CO gas of low concentration (100 ppm). When the weight ratio of ZnO/$PdCl_2$ element sintered at $600^{\circ}C$ was 99.5/0.5, the maximum sensitivity to CO gas was obtained at the operating temperature of $200^{\circ}C$. Also, the response characteristics of this element were examined, and then the response time was decreased from 90 to 45 sees, with operating temperature increase in the range of $100-400^{\circ}C$.

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Considerations on the Long-term Reliability of On-line Partial Discharge Ceramic Sensor for Thermal Power Generators and its Demonstration in the Field

  • Sun, Jong-Ho;Youn, Young-Woo;Hwang, Don-Ha;Kang, Dong-Sik
    • Journal of Electrical Engineering and Technology
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    • 제7권1호
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    • pp.103-108
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    • 2012
  • The present study describes the considerations on the long-term reliability of the on-line partial discharge (PD) ceramic sensor for thermal power generators. Voltage acceleration aging tests were carried out under continuous and impulsive thermal aging at more than $100^{\circ}C$, considering the practical service environment. Experimental results show that the sensors have a life that could last for more than 100 years, excellent dielectric characteristics, and insulation strength. In addition, the ceramic on-line PD sensors were installed in a thermal power generator in Korea for demonstration. The results of the PD calibration and test voltage application prove that the on-line ceramic sensors have satisfactory performances for on-line PD measurement.

팔라디움-니켈 합금전착층의 조성 및 조직에 미치는 파형전류인자의 영향 (The effect of pulse parameters on the composition and the structure of Palladium-Nickel alloy electrodeposits)

  • 예길촌;오유청
    • 한국표면공학회지
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    • 제27권5호
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    • pp.285-291
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    • 1994
  • The effects of pulse current parameters on the composition and the microstructure of Pd-Ni alloy electrodeposits were studied. The cathode current efficiency of p.c. electrolysis conditions decreased with increasing both mean and peak current density and was lower than those under D.C. electrolysis condition. Palladium content of Pd-Ni alloy increased with increasing both peak current density and on-time, while it decreased with increasing mean current density and duty cycle. The preferred orientation of Pd-Ni alloys changed with increasing mean current density in the sequence of (111)+(110).(100) or (110)longrightarrow(111)longrightarrow(100) or random distribution of crystal structure. The surface morphology of Pd-Ni alloy changed mainly according to the mean current density and was related to the preferred orientation.

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