• Title/Summary/Keyword: PbS

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Biosorption of Pb and Cr by Using Sargassum thunbergii (모자반(Sargassum thunbergii)을 이용한 Pb 및 Cr 제거)

  • CHO Moon-Chul;AHN Kab-Hwan;SUH Kuen-Hack
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.38 no.3
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    • pp.153-157
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    • 2005
  • The biosorption of Pb and Cr by Sargassum thunbergii was investigated in a batch conditions. The Pb and Cr uptake capacity of Sargassum thunbergii was 232.5 mg Pb/g biomass and 91.6 mg Cr/g biomass, respectively. An adsorption equilibria was reached within about 0.5 hr for both the Pb and the Cr. The adsorption parameters for both the Pb and the Cr were determined according to the Langmuir and Freundlich model. With increasing pH values, more negative sites are becoming available for the adsorption of Pb and Cr. The selectivity of mixture solution showed an uptake order of Pb>Cu>Cr>Cd. Pb and Cr adsorbed by S. thunbergii could be recovered ken 0.1 M HCl, 0.1 M $HNO_3$ and 0.1M EDTA by a desorption process, and the efficiency of Pb desorption was above $95.8\%$, whereas the efficiency of the Cr desorption was below $50.7\%$.

Anaerobic Corrosion Properties of Sangpyeongtongbo Excavated at Bigyeongdo, Seosan (서산 비경도 출수 상평통보의 혐기성 부식 특성)

  • Kim, Kyu Been;Chung, Kwang Yong
    • Journal of Conservation Science
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    • v.33 no.3
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    • pp.167-179
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    • 2017
  • In this study, Sangpyeontongbo excavated at Bigyeongdo, Seosan, were investigated to determine the components of the corrosion products that were formed while they were buried underwater in an anaerobic environment. The causes of corrosion product formation were also determined. Microstructure observation, element mapping, principle component analysis for each year, and the detection of corrosion products were carried out. Results indicate that the concretions of corrosion products on the surface are needle-, hexahedral-, and octahedral-shaped; Pb, Cu, and S were among the elements detected. The Cu-S layer was clearly verified using element mapping. An analysis of major elements for each layer showed that Cu, S, and Pb were present and that most Zn was eliminated. The corrosion products detected were $PbCO_3$ (concretion) and $Cu_{1.96}S$ (metal). Accordingly, the anaerobic corrosion properties of Sangpyeongtongbo are summarized as follows: dezincification, copper sulfide, and lead compound.

Microstructure and Electrical Properties of the Pt/Pb1.1Zr0.53Ti0.47O3/PbO/Si (MFIS) Using the PbO Buffer Layer (PbO 완충층을 이용한 Pt/Pb1.1Zr0.53Ti0.47O3/PbO/Si (MFIS)의 미세구조와 전기적 특성)

  • Park, Chul-Ho;Song, Kyoung-Hwan;Son, Young-Guk
    • Journal of the Korean Ceramic Society
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    • v.42 no.2 s.273
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    • pp.104-109
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    • 2005
  • To study the role of PbO as the buffer layer, Pt/PZT/PbO/Si with the MFIS structure was deposited on the p-type (100) Si substrate by the r.f. magnetron sputtering with $Pb_{1.1}Zr_{0.53}Ti_{0.47}O_3$ and PbO targets. When PbO buffer layer was inserted between the PZT thin film and the Si substrate, the crystallization of the PZT thin films was considerably improved and the processing temperature was lowered. From the result of an X-ray Photoelectron Spectroscopy (XPS) depth profile result, we could confirm that the substrate temperature for the layer of PbO affects the chemical states of the interface between the PbO buffer layer and the Si substrate, which results in the inter-diffusion of Pb. The MFIS with the PbO buffer layer show the improved electric properties including the high memory window and low leakage current density. In particular, the maximum value of the memory window is 2.0V under the applied voltage of 9V for the Pt/PZT(200 nm, $400^{\circ}C)/PbO(80 nm)/Si$ structures with the PbO buffer layer deposited at the substrate temperature of $300^{\circ}C$.

Morphological and Physiological Effects of Lead (Pb) Exposure on Tissues of Carassius auratus (납 노출에 따른 붕어(Carassius auratus) 조직의 미세구조 및 생리적 변화)

  • Kim, Jeong-Sook;Shin, Myung-Ja;Lee, Jong-Eun;Seo, Eul-Won
    • Korean Journal of Ecology and Environment
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    • v.43 no.3
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    • pp.409-417
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    • 2010
  • Present study aimed to investigate morphological and physiological change in the tissues of Carassius auratus after exposure against Pb (lead) with various rearing condition. We measured the level of accumulated heavy metal and analyzed ultrastructure with transmission electron microscopy. The heavy metal, Pb, was accumulated in the gill, bone and integument increased drastically for exposure periods, the 40 days. The accumulation of Pb in the gill showed relatively higher than that in other tissues. And accumulated Pb amounts also were increased with exposure time dependent manner in the gill, bone and integument tissues. Also, specific activities of antioxidation enzymes in all tissue after exposure to Pb were increased in the course of exposure. And the activities of SOD from tissues exposed to Pb were increased 2 folds than those from the unexposed but GPX activities were maintained constant. The increased numbers of mucous cells in gill tissues exposed to Pb were determined and morphological changes, such as clubbing and fusion, were shown secondary lamella. Also, exposure of Pb for 40 days on gills tissues cause membrane damage in mitochondria and nucleus. In kidney tissues, the atrophied glomerulus was observed, and the empty space in Bowman's capsule was expanded. Based on the all results, it is suggested that the exposure to the high level of Pb for long period affect on the morphology of tissues, and change the enzymatic balance in C. auratus.

Prevalence of Phytophthora Blight of Pigeonpea in the Deccan Plateau of India

  • Sharma, M.;Pande, S.;Pathak, M.;Rao, J. Narayana;Kumar, P. Anil;Reddy, D. Madhusudan;Benagi, V.I.;Mahalinga, D.M.;Zhote, K.K.;Karanjkar, P.N.;Eksinghe, B.S.
    • The Plant Pathology Journal
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    • v.22 no.4
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    • pp.309-313
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    • 2006
  • Phytophthora blight(PB), caused by Phytophthora drechsleri f. sp. cajani is the third potentially important disease of pigeonpea in the Deccan Plateau(DP) of India after wilt and sterility mosaic. In the rainy-season of 2005, an outbreak of PB was seen throughout DP. To quantify the incidence and spread of the disease, a systematic survey was conducted in the major pigeonpea growing regions of DP during the crop season 2005. Attempts were made to determine the effect of cropping systems on the PB development and identify resistant cultivars, if any, grown by farmers and on research farms. Widespread incidence of PB was recorded on improved, and or local cultivars grown in different intercropping systems. Majority of improved cultivars grown at research farms were found susceptible to PB(>10% disease incidence). Pigeonpea intercropped with groundnut, black gram and coriander had less disease incidence(${\leq}10%$). Three wilt and SM resistant pigeonpea cultivars KPL 96053, ICPL 99044, and ICPL 93179 were found resistant(<10%) to PB as well. However, their resistance to PB needs confirmation under optimum disease development environments.

Mechanical Reliability Evaluation of Sn-37Pb Solder/Cu and Sn-37Pb Solder/ENIG Joints Using a High Speed Lap-shear Test (고속 전단시험법을 이용한 Sn-37Pb/Cu 와 Sn-37Pb/ENIG 솔더 접합의 기계적신뢰성 평가)

  • Jeon, Seong-Jae;Hyun, Seung-Min;Lee, Hoo-Jeong;Lee, Hak-Joo
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.250-255
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    • 2008
  • This study utilized a high speed lap-shear test to evaluate the mechanical behavior of Sn-37Pb/Cu and Sn-37Pb/Electroless Nickel immersion Gold under bump metallization solder joints under high speed loading and hence the drop reliability. The samples were aged for 120 h at different temperatures ($120^{\circ}C,\;150^{\circ}C,\;170^{\circ}C$) and afterward tested at different displacement rates (0.01 mm/s to 500 mm/s) to examine the effects of aging on the drop life reliability. The combination of the stress-strain graphs captured from the shear tests and identifying a fracture mode dominant in the samples for different strain rates leads us to conclude that the drop reliability of solder joints degrades as the aging temperature increases, possibly due to the role of the IMC layer. This study successfully demonstrates that the analysis based on a high speed lap-shear test could be critically used to evaluate the drop reliability of solder joints.

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The Influence of the Asian Dust on the Springtime Distribution of Airborne Lead (봄철 황사의 발생과 대기 중 중금속 성분의 농도 변화 -납성분을 이용한 사례 연구)

  • Kim Ki-Hyun;Kang Chang-Hee;Lee J. -H;Choi KC;Youn YH
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.833-838
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    • 2004
  • The analysis of Pb in both PM$_{2.5}$ and PM$_{10}$ fraction of aerosols was made consecutively for every spring season during four year period of 2001 through 2004. To diagnose the impact of the Asian Dust (AD) on metal concentration levels, we compared our Pb measurement data after dividing the whole data sets into AD and NAD period. The results of our analysis indicated that the concentrations of coarse particles increased significantly during the AD period, whereas an increase in the fine counterpart was of moderate degree. However, when Pb concentrations between AD and NAD were compared, the patterns were quite different. From all particle fractions, the Pb concentrations of NAD were slightly or moderately higher than those of AD. The overall results of our study suggest that an increase in particle concentrations during the AD period can cause a rather slight reduction in Pb concentration levels; this can be explained by the dilution effect associated with the increase of Pb-depleted coarse particles.s.s.

Size Control of PbS Colloidal Quantum Dots and Their Application to Photovoltaic Devices

  • Lee, Wonseok;Ryu, Ilhwan;Choi, Geunpyo;Yim, Sanggyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.249.1-249.1
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    • 2015
  • Quantum dots (QDs) are attracting growing attention for photovoltaic device applications because of their unique electronic, optical and physical properties. Lead sulfide (PbS) QDs are one of the most widely studied materials for the devices and known to have size-tunable properties. In this context, we investigated the relationship between the size of PbS QDs and two synthesizing conditions, a concentration of ligand, oleic acid in this work, and injection temperature. The inverted colloidal quantum dot solar cells based on the heterojunction of n-type zinc oxide layer and p-type PbS QDs were also fabricated. The size of the QDs and cell properties were observed to depend on both the QD synthesizing conditions, and hence the overall efficiency of the cell could vary even though the size of QDs used was same. The QD synthesizing conditions were finally optimized for the maximum cell efficiency.

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A Empirical Study on Preference Property for the Private Brand(PB) of Large Discount Stores in Gyeonggi-Do (경기지역의 대형할인점 유통업체브랜드(PB) 선호특성에 대한 실증연구)

  • Kim, Jeong-in;Lee, Jae-hak;Han, Kyu-baek
    • Journal of Distribution Science
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    • v.5 no.2
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    • pp.101-117
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    • 2007
  • Recently, in the process of distribution industry's growth, distribution environment is changing rapidly by appearance of new business condition and strategy of multiple store. According to the intensification of competition, recently large discount stores are developing private brand(PB) products for the purpose of product differentiation and profitability. But after the economic crisis in 1997, young housewives and salaried man's that have rational and practical buying pattern become the core consumer's in the large discount stores. Hence low price strategy is not new things for the consumer's anymore. In addition to, acquiring new consumer, many discount stores are establishing new stores at the rural area. But they undergo hardships of establishing new stores at the rural area because of disparity consumer's behavior, income level and consumption's pattern among regions. So, when they try to establish new stores, they need to know consumer's behavior at the region. Therefore the purpose of this study is to analyze preference property for the private brand(PB) of large discount stores in Gyeonggi-Do.

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Shortwave Infrared Photodetector based on PbS Quantum Dots for Eye-Safety Lidar Sensors (Eye safety 라이다 센서용 황화납 양자점 기반 SWIR photodetector 개발)

  • Suji Choi;JinBeom Kwon;Yuntae Ha;Daewoong Jung
    • Journal of Sensor Science and Technology
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    • v.32 no.5
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    • pp.285-289
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    • 2023
  • Recently, the demand for lidar systems for autonomous driving is increasing, and research on Shortwave Infrared(SWIR) photodetectors for this purpose is being actively conducted. Most SWIR photodetectors currently being developed are based on InGaAs, and have the disadvantages of complex processes, high prices, and limitations in research due to monopoly. In addition, current SWIR photodetectors use lasers in the 905 nm wavelength band, which can pass through the pupil and cause damage to the retina. Therefore, it is required to develop a SWIR photodetector using a wavelength band of 1400 nm or more to be safe for human eyes, and to develop a material that can replace the proprietary InGaAs. PbS QDs are group 4-6 compound semiconductors whose absorption wavelength band can be adjusted from 1000 to 2700 nm, and have the advantage of being simple to process. Therefore, in this study, PbS QDs having an absorption wavelength peak of 1415 nm were synthesized, and a SWIR photodetector was fabricated using this. In addition, the photodetector's responsivity was improved by applying P3HT and ZnO NPs to improve electron hole mobility. As a result of the experiment, it was confirmed that the synthesized PbS QDs had excellent FWHM characteristics compared to commercial PbS QDs, and it was confirmed that the photodetector had a maximum current change of about 1.6 times.