• Journal of Industrial Technology
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• v.18
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• pp.267-275
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• 1998

Continuous thermodynamics has been applied for modeling of phase equilibria in multicomponent mixtures, to avoid disadvantages of the pseudo-component and key-component method. In this paper continuous thermodynamic relations formulated by using the Pate-Teja equation of state were adopted for calculations of phase equilibria in natural gas mixtures, crude oil mixtures and mixtures extracted by supercritical $CO_2$ fluids. Calculations of phase equilibria were performed by two procedures ; a moment method coupled with the beta distribution function and a quadrature method combined with Gaussian-Legendre polynomials. Calculated results were compared with experimental data. It was showed that continuous thermodynamic frameworks considered in this paper were well-matched to experimental data.

• 한국태양에너지학회:학술대회논문집
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• 2011.04a
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• pp.191-194
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• 2011

Low-grade waste heat has generally been discarded in industry due to lack of efficient recovery methods. In recent years, organic Rankine cycle(ORC) has become a field of intense research and appears as a promising technology for conversion of heat into useful work of electricity. In this work thermodynamic performance of ORC with superheating of vapor is comparatively assessed for various working fluids. Special attention is paid to the effects of system parameters such as the evaporating temperature on the characteristics of the system such as maximum possible work extraction from the given source, volumetric flow rate per 1 kW of net work and quality of the working fluid at turbine exit as well as thermal efficiency.

• Journal of Hydrogen and New Energy
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• v.22 no.2
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• pp.223-231
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• 2011

The thermal efficiency of energy-to-power conversion becomes uneconomically low when the temperature of heat source drops below $370^{\circ}C$. ORC (Organic Rankine Cycle) has attracted much attention in last few years due to its potential in reducing consumption of fossil fuels and relaxing environmental problems, and its favorable characteristics to exploit low-temperature heat sources. In this work thermodynamic performance of ORC using nine working fluids is comparatively assessed. Special attention is paid to the effect of system parameters such as turbine inlet temperature and pressure on the characteristics of the system such as volumetric flow rate and quality at turbine exit, latent heat, net work as well as thermal efficiency. Results show that in selection of working fluid it is required to consider various criteria of performance characteristics as well as the thermal efficiency. Results also show that the system efficiencies become same irrespective of kind of working fluid when the temperature of heat source decreases to low range.

• Journal of the Korean Solar Energy Society
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• v.31 no.6
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• pp.49-56
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• 2011

In this study a novel cogeneration system driven by low-temperature sources at a temperature level below $190^{\circ}C$ is investigated by first and second laws of thermodynamics. The system consists of Organic Rankine Cycle(ORC) and an additional heat generation as a parallel circuit. Seven working fluids of R143a, R22, R134a, R152a, $iC_4H_{10}$(isobutane), $C_4H_{10}$(butane), and R123a are considered in this work. Maximum mass flow rate of a working fluid relative to that of the source fluid and optimum turbine inlet pressure are considered to extract maximum power from the source. Results show that due to a combined heat and power generation, both the efficiencies by first and second laws can be significantly increased in comparison to a power generation, however, the second law efficiency is more resonable in the investigation of cogeneration systems. Results also show that the working fluid for the maximum system efficiency depends on the source temperature.

• Journal of the Korean Solar Energy Society
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• v.31 no.3
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• pp.73-79
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• 2011

ORC(organic Rankine cycle) has potential of reducing consumption of fossil fuels and has many favorable characteristics to exploit low-temperature heat sources. This work analyzes performance of ORC with superheating using low-temperature energy sources in the form of sensible energy. Maximum mass flow rate of a working fluid relative to that of a source fluid is considerd to extract maximum power from the sources. Working fluids of R134a, $iC_4H_{10}$ and $C_6C_6$, and source temperatures of $120^{\circ}C$, $200^{\circ}C$ and $300^{\circ}C$ are considered in this work. Results show that for a fixed source temperature thermal efficiency increases with evaporating temperaure, however net work per unit mass of source fluid has a maximum with respect to the evaporating temperature in the range of low source temperature. Results also show that the maximum power extraction is possible with R134a for the source temperature of $120^{\circ}C$, with $iC_4H_{10}$ for $200^{\circ}C$, and with $C_6C_6$ for $300^{\circ}C$.