• The Korean Journal of Ceramics
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• v.3 no.4
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• pp.235-238
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• 1997

Basic properties of new cement pastes based on the system $CaO-Al_2O_3-P_O_5-H_2O$were studied Phosphoric acid solutions and calcium dialuminate clinkers synthesized by the hydration-burning method were used for liquid and powder components of the paste, respectively Variation in the compositions of the paste was achieved by changing the liquid/powder ratio and the concentration of phosphoric acid solution. The hardening rate of the paste was so largely affected by the amount of phosphoric acid that hardening was inhibited with the low-concentrated solution but was explosively accelerated with the high-concentrated solution. The phosphoric acid solutions of concentration of 45~50% and the liquid/powder ratio of 0.5~1.5 were favoured for the high early-strength cement paste with the reasonable hardening rate and high strength. The binding phase of hardened paste was the dense amorphous gel of the system $CaO-Al_2O_3-P_O_5-H_2O$. in which the unreacted calcium dialuminate grains were embeded.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.131-136
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• 1997

It is well known that concrete is typical porous material. We pay attention to Hansen's idea that concrete may be expected to act as semi-permeable membrane, and report the effect of concentration of solution and temperature on water flux in forward osmosis. In order to measuring volume of water flux from distilled water to solution of sodium chloride through hardened cement paste, specially designed apparatus was constructed, and the following result were obtained: (1) hardened cement paste acts as semi-permeable membrane, consequently, water flux in forward osmosis may occur. (2) Rate of water flux is proportion to concentration of dilute solution, and this suggests hardened cement paste is agreeable to the theory of membrane. (3) Effect of temperature on water flux is agreeable to Arrehenius equation and is great.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.27-28
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• 2018

Deterioration of reinforced concrete structures due to salt corrosion is a phenomenon that can be easily seen, and the main reason for deterioration is chloride ion. Therefore, researches are actively conducted to control chlorine ion penetration worldwide. The purpose of this study is to evaluate the chloride ion fixation capacity of Portland cement paste containing Hydrotalcite. For this purpose, cement paste containing 0%, 2.5%, and 5% of Hydrotalcite was sealed and cured for 28 days, and the cured cement paste was crushed. Chloride ion solution was prepared at a concentration of 0.5M using NaCl, and the powdered cement paste was reacted for a specific time in aqueous chloride ion solution. After the reaction, the concentration of the chloride ion aqueous solution was measured using a silver nitrate potentiometric titrator, and the reacted cement paste was analyzed using XRD and FT-IR.

• Journal of the Korea Institute of Building Construction
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• v.4 no.4
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• pp.95-101
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• 2004

The purpose of this paper is to compare free-chloride content with water-soluble chloride in blast furnace cement(BSC) paste. The content of free-chloride in cement paste measured by pore solution analysis and water-soluble chloride measured by ASTM. The result of this study are as follows: 1. The concentration of chloride ion in pore solution of BSC-solidified matrix is almost as low as 43-71% compared to that of OPC-solidified matrix containing the same chloride content in cement paste. 2. The binding capacity of specimens, OPC Pl-P5, are 93.5-77%, but the binding capacity of specimens, BSC Pl-P5 are 97.1-86.1%, which is to be as high as 2-9.1% compared to OPC containing the same chloride content. 3. In terms of water-soluble chloride content in BSC paste are 15-31.7 percent of chloride addition but free-chloride content in pore solution are 2.9-13.9 percent of chloride addition. The free-chloride content in pore solution is 19.3-43.8 percent lower for the water-soluble chloride content in cement paste.

• The Korean Journal of Food And Nutrition
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• v.16 no.3
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• pp.218-223
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• 2003

This study is proceeded on the development of standard method for making soybean paste by Korean traditional method. Fermentation condition of Meju was 1) Pre-fermentation : 30 days in about 20$^{\circ}C$ room, 2) Main fermentation : 5 days in 30$^{\circ}C$ or upper temperature, 3) Post fermentation and drying : 30 days in well sunlightened room in January. Meju was soaked in 18% salt solution(Meju 7kg/salt solution 20L) for 35～40 days (from late February to early April) and after soaking Meju was filtered as unsoluble solute and crushed and put into traditional Korean receptacle(named 'Dok'). Crushed Meju was stored from early April to mid September and Meju was changed into soybean paste(Doen-jang). During fermentation amino acid nitrogen in Doen-jang was slightly increased in early period and decreased lately. It has been proved that by panel test soybean paste made by the method suggested in this study was more excellent than commercially fermented soybean paste. This study has presented the possibility of commercial production of soybean paste made by traditional method.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.421-421
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• 2008

Generally, the polymer thick-film resistors for embedded organic or hybrid substrate are patterned by screen printing so that the accuracy of resistor pattern is not good and the tolerance of resistance is too high(${\pm}$20~30%). To reform these demerits, a method using Fodel$^{(R)}$ technology, which is the patterning method using a photosensitive resin to be developable by aqueous alkali-solution as a base polymer for thick-film pastes, was recently incorporated for the patterning of thermosetting thick-film resistor paste. Alkali-solution developable photosensitive resin system has a merit that the precise patterns can be obtained by UV exposure and aqueous development, so the essential point is to get the composition similar to PSR(photo solder resist) used for PCB process. In present research, we made the photopatternable resistor pastes using 8 kinds of epoxy acrylates and a conductive carbonblack (CDX-7055 Ultra), evaluated their developing performance, and then measured the resistance after final curing. To become developable by alkali-solution, epoxy acrylate oligomers with carboxyl group were prepared. Test coupons were fabricated by patterning copper foil on FR-4 CCL board, plating Ni/Au on the patterned copper electrode, applying the resistor paste on the board, exposing the applied paste to UV through Cr mask with resistor patterns, developing the exposed paste with aqueous alkali-solution (1wt% $Na_2CO_3$), drying the patterned paste at $80^{\circ}C$ oven, and then curing it at $200^{\circ}C$ during 1 hour. As a result, some test compositions couldn't be developed according to the kind of oligomer and, in the developed compositions, the measured resistance showed different results depending on the paste compositions though they had the same amount of carbonblack.

• Computers and Concrete
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• v.16 no.6
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• pp.847-864
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• 2015

This study aimed to develop models of sulfate diffusion and ettringite content profile in cement paste for the predication of the damage behavior in cement paste subject to external sulfate. In the models, multiphase reaction equilibrium between ions in pore solution and solid calcium aluminates phases and the microstructure changes in different positions of cement paste were taken into account. The distributions of expansive volume strain and expansion stress in cement paste were calculated based on the ettringite content profile model. In addition, more sulfate diffusion tests and SEM analyses were determined to verify the reliability and veracity of the models. As the results shown, there was a good correlation between the numerical simulation results and experimental evidences. The results indicated that the water to cement ratio (w/c) had a significant influence on the diffusion of sulfate ions, ettringite concentration profile and expansion properties in cement paste specimens. The cracking points caused by ettringite growth in cement paste specimens were predicted through numerical methods. According to the simulation results, the fracture of cement paste would be accelerated when the specimens were prepared with higher w/c or when they were exposed to sulfate solution with higher concentration.

• Proceedings of the Korea Concrete Institute Conference
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• 1991.10a
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• pp.11-14
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• 1991

Apparent diffusion coefficients of Cl-ions through hardened cement paste(HCP), which were partly substituted blending materials, were determined. Also, pore solution was extracted from HCP which were immersed in NaCl solution, and Cl- concentration of the solution were analyzed. Partly substitution of pozzolanic materials considerably reduced the diffusion rate for Cl-ions and Cl- concentration of pore solution. Binding capacity of Cl- is related to the content of Al2O3 and pozzolanic reactivity.

• Advances in concrete construction
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• v.7 no.3
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• pp.175-181
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• 2019

Low-calcium fly ash (LCFA) were used to prepare cement/LCFA specimens in this study. The basic physical properties including water demand, fluidity, setting time, soundness and drying shrinkage of cement/LCFA paste were investigated. The effects of curing time, immersion time and wet-dry cycles in 3% $Na_2SO_4$ solution on the compressive strength and the microstructures of specimens were also discussed. The results show that LCFA increases the water demand, setting time, soundness of cement paste samples. 50% and 60% LCFA replacement ratio decrease the drying shrinkage of hardened cement paste. The compressive strength of plain cement specimens decreases at the later immersion stage in 3% $Na_2SO_4$ solution. The addition of LCFA can decrease this strength reduction of cement specimens. For all specimens with LCFA, the compressive strength increases with increasing immersion time. During the wet-dry cycles, the compressive strength of plain cement specimens decreases with increasing wet-dry cycles. However, the pores in the specimens with 30% and 40% LCFA at early ages could be large enough for the crystal of sodium sulfate, which leads to the compressive strength increase with the increase of wet-dry cycles in 3% $Na_2SO_4$ solution. The microstructures of cement/LCFA specimens are in good agreement with the compressive strength.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.549-554
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• 2001

It is possible for concrete using sea sand to contain chloride ion as well as cation such as Na$^{+}$and $K^{+}$ during mixing process. It is known that some cations such as Na$^{+}$and $K^{+}$ remain in pore solution without binding In this study, therefore, we intend to inspect the behavior of cations in cement paste as well as NaCl, CaCl$_2$ and KCI through analysis of pore solution extracted from cement paste with high pressure vessel. As a result, increase of alkali ions by adding sea sand and admixtures to the fresh concrete means use of the cement contained high alkali contents. In this case, alkali ions in pore solution can decrease durability of cement products causing alkali-aggregate reaction or accelerated carbonation. So it needs to be studied.studied.