• Environmental Analysis Health and Toxicology
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• 제17권2호
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• pp.147-160
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• 2002

Volatile organic compounds (VOCs) are an important public health issue in Korea and many important questions remain to be addressed with respect to assessing exposure to these compounds. Because they are ubiquitous and highly volatile, special techniques must be applied in their analytic determination Valid Personal exposure assessment methods are needed to evaluate exposure frequency, duration and intensity, as well as their relationship to personal exposure characteristics. Biological monitoring is also important since it may contribute significantly in risk assessment by allowing the estimation of effective absorbed doses. This study was on ducted to establish the environmental measurement, personal dosimetry and biological monitoring methods for VOCs. These methods are needed to compare blood, urinary and exhalation breath VOC levels and to provide tools for risk assessment of VOC exposure. Passive monitors (badge type) and a active samplers (trap) for the VOCs collection were used for air sampling. Methods development included determining the minimum detectable amounts of VOCs in each media, as well as evaluating collection methods and developing analytical procedures. Method reliability was assessed by determining breakthrough volumes and comparing results between laboratories and with other methods. A total capacity of trap used in this study was 60ι. Although variable by compound, the average breakthrough was 20％. Also, there was no loss of compounds in trap even if keep for 45 day in -7$0^{\circ}C$. The recovery of active and passive methods was 69％ ~ 126％ and method detection limit was 0.24 $\mu\textrm{g}$/trap and 0.07 $\mu\textrm{g}$/badge. There was no statistical difference (P > 0.05) between active and passive methods.

• 융합신호처리학회논문지
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• 제9권2호
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• pp.164-172
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• 2008

본 논문에서는 수동 RFID 환경에서 획득되는 위치 및 시간 정보를 이용하여, 태그가 배치된 노면을 주행하는 이동로봇의 위치를 효과적으로 추정하는 기법을 제안한다. 본 논문에서 제안된 위치 추정 기법은 기존 연구에 비해 위치 추정 오차를 감소시키고 또한 초기 태그 배치 비용을 감소시키는 효과가 있다. 기본적으로 이동로봇이 일련의 직선 구간을 구간별로 일정한 속도로 주행하며, 또한 매 순간 이동로봇에 의해 감지되는 태그의 수는 한 개 이하라고 가정한다. 첫째, 이미 알려진 지점을 출발하여 정속 직선 주행하는 이동로봇의 속도 및 위치를 추정하는 알고리즘을 개발하는데, 이는 최초를 제외한 여타 구간의 경우에 유효하다. 다음, 최초 구간의 경우 출발 위치를 모르는 상태이므로, 이동로봇이 두 개 이상의 태그를 정속 직선 주행하도록 하여 이동로봇의 속도 및 위치를 추정한다. 마지막으로, 제작된 수동 RFID 위치 추정 시스템을 이용한 실험을 통해 본 논문에서 제안된 이동로봇 위치 추정 기법의 유효성 및 성능을 입증한다.

• 한국지구과학회지
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• 제28권5호
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• pp.572-584
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• 2007

The quantification of ammonia concentrations has received a lot of scientific attention. Numerous devices for the quantification of $NH_3$ in the ambient air have been developed to provide more technical possibilities for research in abating $NH_3$ emission from various source processes. For the proper quantification of $NH_3$, a number of sampling methods have been discussed by grouping them into different categories based on the principle of functioning. In general, active samplers employ pumps to draw air in, while passive samplers are exposed to air over a certain period of time to obtain integrated signature of $NH_3$. In case of the former, impingers and absorption flasks can be employed simultaneously with suitable absorbents to capture $NH_3$ passing through them. The methods of analysis include both in-situ and laboratory determination. In the laboratory, colorimetric or ion chromatographic methods are generally used for its quantification. In the field, a number of real time analyzers have been proven to be useful. These real time analyzers can be grouped according to their principle of operation. These analyzers may use the principle of spectroscopy (e.g. DOAS), photoacousticics (e.g. photoacoustic monitor) or Chemiluminescence ($NO_x$ analyzer). The automated annular denuder sampling system with on-line analyzer is also suitable for continuous monitoring of ammonia in air.

• 한국산업보건학회지
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• 제11권1호
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• pp.34-41
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• 2001

Passive samplers have been used for personal, indoor, and outdoor air monitoring of VOCs at ppb concentrations in community and office environments. The path length of modified passive sampler was shortened, so it was intended to increase an uptake rate. The performance of the modified 3M 3500 organic vapor monitor(OVM) as a tool for assessing exposures to toxic air pollutants in nonoccupational community environments was evaluated using combined controlled test atmospheres of six selected target volatile organic compounds(VOCs): benzene, methyl tert-butyl ether(MTBE), chloroform, 1,4-dichlorobenzene, tetrachloroethylene, and toluene. The experiments were conducted by exposing the dosimeters to concentrations of $50{\sim}100{\mu}g/m^3$ on six face velocity(0.00, 0.02, 0.06, 0.12, 0.20, 0.30 m/sec) for 24 hours. If the uptake rate was increased, that means that we could use the passive sampler more effectively. The uptake rates were increased linearly according to reduce the path length. Although the diffusion path length was shortened, the change of uptake rate was within ${\pm}25%$ of theoretical value, indicating that the modified passive sampler(TM) can be effectively used over the range of concentrations and environmental conditions tested with a 24-h sampling period if the face velocities were over 0.12 m/s for 6 components of VOCs. But when the face velocities were less than 0.12 m/s, uptake rates were reduced more than expected values. So, the passive sampler with the shortened path length should be used at indoor or outdoor environment where the face velocity should be over about 0.10 m/s. If the path length was shortened more, the uptake rate was more effected by starvation.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2001년도 봄 학술발표회 논문집
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• pp.231-238
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• 2001

To investigate the underground structure of shallow water, Han-river near Yangsou-Ri, high resolution hydroacoustic measurements were carried out for the engineering design of railroad bridge. The acoustic source was a Boomer with an energy of 90 to 280J and in a frequency range up to about 16KHz. The reflected signals were received by using both traditional hydrophones(passive element) and a specially devised receiver unit(active element) mainly composed of piezofilms and preamplifier. They are connected to the "SUMMIT" data acquisition system(DMT-GeoTec company), where the sampling interval was set to 1/32㎳. The source position was continuously monitored by a precision DGPS system whose positioning accuracy was on the order of loom. For the quality control purposes, two different source-receiver geometries were taken. That is to say, the measurements were repeated along the profile everytime depending on the different source energy(175J, 280J), the receiving elements(passive, active) and two different source-receiver geometries. It was shown that the data resolution derived from a proper arrangement with the active hydrophone could be greatly enhanced and hence the corresponding profile section caused by the regular data processing system "FOCUS" accounted excellently for the underground formation below the shallow water.w the shallow water.

• Journal of Pharmaceutical Investigation
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• 제31권4호
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• pp.273-279
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• 2001

The purpose of this study is to characterize the iontophoretic transport of growth hormone releasing peptides (GHRP-6) through hairless mouse skin from aqueous solution. The effect of various factors, such as pH, poloarity, current profile, current density, current duration, ionic strength, drug concentration, and enhancer application was studied to obtain basic knowledge on the transport. We have also studied the stability of GHRP-6 in solution with/without current. The donor chamber was filled with phosphate buffer solution containing GHRP-6 and the receptor chamber was filled with phosphate buffer solution (pH 7.4). Ag/AgCl electrode was used for their stability and reversibility. At a predetermined time interval, sampling was made and the concentration of drug was analysed using HPLC system. The results showed that, compared to passive flux, the total amount of drug transported increased markedly by the application of anodal current. Cathodal flux was similar to passive flux. Flux increased with the current density, the duration of current application and drug concentration. The effect of enhancers on the flux was studied using hydrophilic (5% N-methyl pyrrolidone) and hydrophobic (5% propylene glycol monolaurate, 5% oleic acid) enhancers. Application of enhancer also increased the flux.

• 한국통신학회논문지
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• 제32권12A호
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• pp.1311-1319
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• 2007

본 논문에서는 UHF 대역 RFID 수동형 태그의 디지털 회로부 구현을 위한 VHDL 설계과정을 보인다. 태그의 동작은 EPCglobal Class1 Gen2 표준을 지원하며 합성과 구현과정을 거친 타이밍 시뮬레이션 결과를 통해 검증하였다. 수 미터의 인식거리로 인해 Frame-Slotted Aloha를 사용하는 환경에서, 단위시간당 태그 인식률을 향상시키기 위해서는 리더 명령에 대한 빠른 처리와 응답을 할 수 있는 디지털 회로 설계가 필요하다. 본 설계는 Pipeline 처리 구조를 기반으로 직렬 입력 신호에 대한 응답지연의 최소화를 목표로 하였다. 또한, 효율적인 다중 접속 명령들의 처리와 태그의 데이터 전송 속도의 오차를 낮추기 위해 리더의 Preamble과 PIE 디코딩을 위한 샘플링 과정을 제안하였다. FPGA 검증을 위한 Place & Route 후 다중 태그 상황을 감안한 테스트 벤치 시뮬레이션 결과, 표준상의 최대 송수신 데이터 전송 속도에서 디코딩 및 인코딩 을 위한 최소 요구 시간 보다 빠른 처리 결과를 확인 할 수 있었다.

• JSTS:Journal of Semiconductor Technology and Science
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• 제12권3호
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• pp.278-285
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• 2012

A digital readout IC for capacitive sensors is presented. Digital capacitance readout circuits suffer from static capacitance of sensors, especially single-ended sensors, and require large passive elements to cancel such DC offset signal. For this reason, to maximize a dynamic range with a small die area, the proposed circuit features digital filters having a coarse and fine compensation steps. Moreover, by employing switched-capacitor circuit for the front-end, correlated double sampling (CDS) technique can be adopted to minimize low-frequency device noise. The proposed circuit targeted 8-kHz signal bandwidth and oversampling ratio (OSR) of 64, thus a $3^{rd}$-order ${\Delta}{\Sigma}$ modulator operating at 1 MH was used for pulse-density-modulated (PDM) output. The proposed IC was designed in a 0.18-${\mu}m$ CMOS mixed-mode process, and occupied $0.86{\times}1.33mm^2$. The measurement results shows suppressed DC power under about -30 dBFS with minimized device flicker noise.

• 한국산업보건학회지
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• 제21권4호
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• pp.215-221
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• 2011

Objectives: This study was conducted to evaluate the exposure level of hazardous chemical agents for dental technicians in Ulsan. Methods: We measured airborne total dusts and metals such as Nickel, Manganese, Cobalt, and Chromium in 10 dental laboratories by the NIOSH Methods 0500 and 7300, respectively. Methyl methacrylate (MMA), a key ingredient in acrylic resin, was also monitored using passive samplers for long-term sampling and Tenax tubes for short-term sampling. Results: Measured levels of all items were below 10% of the Korean exposure limit except for Nickel. The geometric mean concentration and geometric standard deviation of total dust, Nickel, and MMA were $0.14mg/m^3$ (2.16), $165.3{\mu}g/m^3$ (3.31), and 0.2 ppm (2.5) respectively. Airborne Nickel concentration of two dental laboratories exceeded the exposure limit ($1000{\mu}g/m^3$). The major emission sources of Nickel were metal trimming and casting processes. Conclusions: We found that Nickel, a carcinogen, should be controled most urgently to protect dental technicians.

• Journal of Korean Society for Atmospheric Environment
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• 제19권E2호
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• pp.51-61
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• 2003

The material exposure tests have been carried out since 1993 to evaluate the relationship between air pollution and material corrosion with the cooperation of the researchers in Japan, China, and Korea. The test pieces such as bronze, copper, marble, and carbon steel have been exposed under both unsheltered and rain-sheltered outdoor condition separately at 18 sampling sites in East Asia. At the same time, the concentration of SO$_2$ and NO$_2$ has been measured simultaneously with passive sampler. The meteorological data were collected from the AWS (Auto-mated weather station) In each country and chemical compositions of wet deposition were also analyzed by the bulk sampling of rainfall every month. As the results, it was found that the corrosion rates of test pieces in the ambient air were appeared to be in the order of carbon steel > marble > bronze copper. The corrosion rates of test pieces in the unsheltered outdoor condition were 2.34 to 5.88 times larger than those in rain-sheltered condition. It was also found that the corrosion rate in the heavy polluted area in China was the highest, and the corrosion rates of the metal pieces were generally proportional to SO$_2$ concentration. Between two sites in Korea, the test pieces at Daegu site showed higher corrosion rates that would be due to the higher SO$_2$ concentration.