• 제목/요약/키워드: Particulate Matters

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The Effect of Chelators and Reductants on the Mobilization of Metals from Ambient Particulate Matter: More Transition Metals are Mobilized with PM2.5 than with PM10

  • Song, H-S;Chang, W-C;Bang, W-G;Kim, Y-S;Chung, N
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 한국환경독성학회 2002년도 추계국제학술대회
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    • pp.155-155
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    • 2002
  • Ambient urban particulate matters contain various transition metals. When the particulate matters are inhaled into the lung, not all but some part of metals from the particles might be mobilized to participate in a reaction that can damage various biomolecules, such as DNA and proteins. The dust particle size as well as organic acids may influence the metal mobilization. Thus, the mobilization of the metal from SRM1648 (NIST, USA) and urban particulate matters (PM2.5 and PM10) was measured in the presence of artificial or biological chelator with or without reductant. The degree of the mobilization was higher with the artificial or biological chelator than the control with saline. In some cases, a reductant increased the mobilization as much as about 5 times the control without the reductant. Especially, the mobilization of Fe was greatly influenced by the presence of reductants. In general, the degree of the mobilization of the transition metal was higher with PM2.5 than with PM10. Therefore, it is expected that, considering the previously known toxicities of the transition metals, the PM2.5 is more damaging to various biomolecules than PM10. The results also suggest that not the total amount but the mobilizable fraction of the metal in the dust particles should be considered with regard to the toxicity of the urban particulate matters.

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A Study on Perception Change in Bicycle users' Outdoor Activity by Particulate Matter: Based on the Social Network Analysis (미세먼지로 인한 자전거 이용객의 야외활동 인식변화에 관한 연구: 사회네트워크분석을 중심으로)

  • Kim, Bomi;Lee, Dong Kun
    • Journal of Environmental Impact Assessment
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    • 제28권5호
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    • pp.440-456
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    • 2019
  • The controversy of the risk perception related to particulate matters becomes significant. Therefore, in order to understand the nature of the particulate matters, we gathered articles and comments in on-line community related to bicycling which is affected by exposure of the particulate matters. As a result, firstly, the government - led particulate matter policy was strengthened and segmented every period, butthe risk perception related to particulate matters in the bicycle community has become active and serious. Second, as a result of analyzing the perception change of outdoor activities related to particulate matters, bicycle users in community showed a tendency of outdoor activity depending on the degree of particulate matters ratherthan the weather. In addition, the level of the risk perception related to particulate matters has been moved from fears of serious threat in daily life and health, combined with the disregard of domestic particulate matter levels or mask performance. Ultimately, these risk perception related to particulate matters have led some of the bicycling that were mainly enjoyed outdoors to the indoor space. However, in comparison with outdoor bicycling enjoyed by various factors such as scenery, people, and weather, the monotonous indoor bicycling was converted into another type of indoor exercise such as fitness and yoga. In summary, it was derived from mistrust of excessive information or policy provided by the government or local governments. It is considered that environmental policy should be implemented after discussion of risk communication that can reduce the gap between public anxiety and concern so as to cope with the risk perception related to particulate matters. Therefore,this study should be provided as an academic basis for the effective communication direction when decision makers establish the policy related to particulate matters.

Investigation and Analysis of Particulate-matters and Ammonia Concentrations in Mechanically Ventilated Broiler House According to Seasonal Change, Measurement Locations and Age of Broilers (강제환기식 육계 사육시설의 계절별, 지점별, 주령별 PM, NH3 농도 조사 및 분석)

  • Jang, Dong-hwa;Kwon, Kyeong-seok;Kim, Jong-bok;Kim, Jung-kon;Yang, Ka-young;Choi, Sung-min;Jang, YuNa
    • Journal of The Korean Society of Agricultural Engineers
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    • 제63권1호
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    • pp.75-87
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    • 2021
  • Air quality related to particulate matters and ammonia is being come to the fore as the national concern in Korea. CAPSS (Clean Air Policy Support System) provides emission coefficients of these kinds of particulate and gaseous matters in the fields of livestock; however reliability issues are consistently mentioned. Evaluation of emission rates of PM2.5 and NH3 of the country is very important, but only few studies are available as the background related to observation of the concentration of the particulate matter and ammonia, especially within livestock house in Korea. In this paper, long-term measurement of PM10, PM2.5, and ammonia within the mechanically ventilated broiler house were carried out to introduce backgrounds of generation and emission of the particulate matters and ammonia. Measurement results were analyzed according to seasonal changes, age of broilers(weeks) and measurement locations. Concentration of inhalable and respirable dust were also evaluated in terms of occupational respiratory health according to increase in broiler's activity. From the results of this study, identification of the generation mechanisms of the particulate and gaseous matters, and evaluation of the emission rate of these in the broiler house will be carried out.

Exhaust Emission Characteristics from Heavy-duty Diesel Engine applicable to Prime Propulsion Engine for Marine Vessels (선박 주 추진기관으로 사용가능한 대형 디젤엔진의 배기가스 특성 분석)

  • Lee, Hyung-Min;Park, Rang-Eun
    • Journal of Advanced Marine Engineering and Technology
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    • 제36권4호
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    • pp.484-489
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    • 2012
  • The objective of this work presented here was focused on analysis of particulate matter and nitrogen oxide characteristics in ESC test mode from heavy-duty diesel engine installed on-road vehicles applicable to prime propulsion engine for marine vessels. The authors confirmed that a large quantity particulate matter were emitted in high power density condition, nitrogen oxide characteristics were dependent on exhaust gas temperature. Particulate matters were reduced by 1/100~1/1,000 times in post DPF with test modes but filtration efficiency was decreased in the engine power fluctuation. In the case of the high speed and power condition, the exhaust level of particulate matters was increased according to increment of temperature of gas flowing into DPF. The orders of magnitude for particle concentration levels from the analysis of size distribution of particulate matters of test engine was different. Both emitting nano-sized particles below 100nm regardless of DPF and non-DPF.

Wear Particulate Matters and Physical Properties of ENR/BR Tread Compounds with Different Ratio of Silica and Carbon Black Binary Filler Systems

  • Ryu, Gyeongchan;Kim, Donghyuk;Song, Sanghoon;Lee, Hyun Hee;Ha, Jin Uk;Kim, Wonho
    • Elastomers and Composites
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    • 제56권4호
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    • pp.234-242
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    • 2021
  • The demand for truck bus radial (TBR) tires with enhanced fuel efficiency and wear resistance have grown in recent years. In addition, as the issue of particulate matter and air pollution increases, efforts are being made to reduce the generation of particulate matter. In this study, the properties of epoxidized natural rubber (ENR) containing a silica-friendly functional group were evaluated by considering it as a base rubber and varying the silica ratio in this binary filler system. The results showed that the wear resistance of the NR/BR blend compound decreased as the silica ratio increased. In contrast, the ENR/BR blend compound exhibited an increase in wear resistance as the silica ratio was increased. In particular, the ENR-50/BR blend compound showed the best wear resistance due to the presence of several epoxide groups. Furthermore, we observed that for tan 𝛿 at 60℃, higher epoxide content resulted in the higher Tg of the rubber, indicating a higher tan 𝛿 at 60℃. On the other hand, it was confirmed that increasing the silica ratio decreased the value of tan 𝛿 at 60℃ in all compounds. In addition, we measured the amount of wear particulate matters generated from the compound wear. These measurements confirmed that in the binary filler system, regardless of the filler type, the quantity of the generated wear particulate matters as the filler-rubber interaction increased. In conclusion, the silica filled ENR/BR blend compound exhibited the lowest generation of wear particulate matters.

Assessment and Estimation of Particulate Matter Formation Potential and Respiratory Effects from Air Emission Matters in Industrial Sectors and Cities/Regions (국내 산업 및 시도별 대기오염물질 배출량자료를 이용한 미세먼지 형성 가능성 및 인체 호흡기 영향 평가추정)

  • Kim, Junbeum
    • Journal of Korean Society of Environmental Engineers
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    • 제39권4호
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    • pp.220-228
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    • 2017
  • Since the fine particulate matters occurred from mainly combustion in industry and road transport effect to human respiratory health, the interest and importance are getting increased. In 2013, the World Health Organization (WHO) concluded that outdoor air pollution is carcinogenic to humans, with the particulate matter component ($PM_{10}$ and $PM_{2.5}$) of air pollution most closely associated with increased cancer incidence, especially cancer of the lung. Therefore, many researches have been studied in the quantification and data development of fine particulate matters. Currently, the Ministry of Environment and cities/regions are developing the fine particulate matter data and air emission information. Particularly just $PM_{10}$ and $PM_{2.5}$ data is used in the fine particulate matters warning and alert. The data of NOx, SOx, $NH_3$, which have the particulate matter formation potential are not well considered. Also, the researches related with particulate matter formation potential and respiratory effects by industrial sectors and cities/regions are not conducted well. Therefore, the purpose of this study is to evaluate and calculate particulate matter formation potential and respiratory effects in 11 industrial sectors and cities using NOx, SOx, $PM_{10}$, $NH_3$ data (developed by Ministry of Environment and National Institute of Environmental Research) in 2001 and 2013. The results of this study will be provided the particulate matter formation potential and respiratory effects and will be used for future the fine particulate matter researches.

The Study on the Emission Characteristics of HAPs and PM from the Motor Vehicle Paint Facility (자동차 도장시설에서 발생하는 유해대기오염물질 및 미세먼지의 배출특성에 관한 연구)

  • Kim, Han-Na;Bong, Choon-Keun;Kim, Yong-Gu;Jeon, Jun-Min
    • Journal of Korean Society for Atmospheric Environment
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    • 제29권6호
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    • pp.713-721
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    • 2013
  • This study is about emission characteristics of HAPs and particulate matters emitted by spray of paint and organic solvent usually used in vehicle paint facilities. To analyze emission characteristics of HAPs and particulate matters emitted from vehicle paint facilities are calculated based on the measuring emission quantity of pollutants based on the amount of paint used (kg) and unit area ($m^2$) by paint manufacturers (J company, K company, and R company). In cases of paint manufacturers (J, K, and R), average emission factors of VOCs, carbonyl compound, particulate matter, and PAHs per 1 kg of paint were 327.81 g/kg, 5.98 g/kg, 336.70 g/kg, and 0.0078 g/kg respectively. The average emission factors of VOCs, carbonyl compounds, particulate matters, and PAHs by unit area were $171.55g/m^2$, $3.10g/m^2$, $176.27g/m^2$, and $0.0036g/m^2$ respectively.

Density Distributions of Metallic Compounds in Particulate Matters (粒子狀 物質中 金屬成分의 密度分布)

  • 허문영;김형춘;손동헌
    • Journal of Korean Society for Atmospheric Environment
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    • 제2권2호
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    • pp.9-18
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    • 1986
  • For identification and apportionment of sources emitting particulate matters in environment, the multi-elemental characterization of size-density fractionated particulate matters was carried out. Eight types of samples were tested; soil, flyash released from burning of bunker-Coil, diesel oil, coal, and soft coal, urban road-way dust, urban dust fall, and airborne particulate matter. The fractions of particulate matters obtained by heavy liquid separation methos with a series of dichloromethane-bromoform were then analyzed using atomic absorption spectrophotometry for Ni, Cr, Cu, An, Fe, Al, and Mg. Each sample showed a different concentration profile as a function of density, and a number of useful conclusions concerning characterization of elemental distribution were obtained. From the density distributions of elements in soil, the maximum value was found for all elements in the density range of 2.2 $\sim 2.9g.cm^{-3}$, including the density of $SiO_2$. However, the distribution of metallic compounds with the density lower than $2.2g.cm^{-3}$ was prevalent in urban roadway dust, urban dust fall, and airborne particulate matter. And the density distribution curves of these urban dusts also have the higher distribution at the density of 2.2 - 2.9g.cm^{-3}$, including the density of wind-blown silica. This tendency generally was prevalent in the natural source elements, such as Al, Fe, Mn, and Mg. The maximum values were found in the density ranges of 1.3 $\sim 2.2g.cm^{-3}$ from the density distribution of elements in oil fired flyash. These distributions of anthropogenic source elements, such as Zn, Ni, Cu, and Cr were higher predominately than those of natural source elements. And the higher distribution was found in the density range of $2.2 \sim 2.9g.cm^{-3}$ from the density distribution of elements in coal and soft-coal fired flyash. These distributions showed similar patterns to soil. But anthropogenic source elements somewhat predominated at the density ranges of $1.3 \sim 2.2g.cm{-3} and 2.9g.cm^{-3}$ to soil. Therefore the higher distribution of anthropogenic source elements in the density ranges of $1.3 \sim 2.2g.cm^{-3} and 2.9g.cm^{-3}$ was considered as anthropogenic origin.

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Study on Soot Primary Particle Size Measurement in Ethylene Diffusion Flame by Time-Resolved Laser-Induced Incandescence (시분해 레이저 유도 백열법을 이용한 에틸렌 확산 화염에서의 매연 일차입자크기 측정에 관한 연구)

  • Kim Gyu-Bo;Cho Seung-Wan;Lee Jong-Ho;Jeong Dong-Soo;Chang Young-June;Jeon Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • 제30권10호
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    • pp.973-981
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    • 2006
  • Recently there is an increasing interest in particulate matter emission because of new emission regulations, health awareness and environmental problems. It requires to improve particulate measurement techniques as well as to reduce soot emissions from combustion systems. As mentioned above, it is demanded that reduction techniques together with measurement techniques of exhausted particulate matters in combustion systems such as vehicles. However, measurement techniques of particulate matters should be prior to reduction techniques of that because it is able to know an increase and a decrease of exhausted particulate matters when measured particulate matters. Therefore, in this study, we report the measurement of soot primary-particle size using time-resolved laser induced incandescence (TIRE-LII) technique in laminar ethylene diffusion flame. As an optical method, laser induced incandescence is one of well known methods to get information for spatial and temporal soot volume fraction and soot primary particle size. Furthermore, TIRE-LII is able to measure soot primary particle size that is decided to solve the decay ate of signal S $(t_1)$ and S $(t_2)$ at two detection time. In laminar ethylene diffusion flame, visual flame height is 40 mm from burner tip and measurement points are height of 15, 20, 27.5, 30 mm above burner tip along radial direction. As increasing the height of the flame from burne. tip, primary particle size was increased to HAB(Height Above Burner tip)=20mm, and then decreased from HAB=27.5 mm to 30 mm. This results show the growth and oxidation processes for soot particles formed by combustion.