• 한국표면공학회지
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• 제43권5호
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• pp.230-237
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• 2010

FTMP(friction thermo-mechanical process) is an adaptation of friction stir welding, and can be used as a generic process to modify the microstructure at selective locations. In this study, in order to analyze characteristics of surface modification of ACA4 castings by FTMP, change of rotating speed(R/S) and traveling speed(T/S) of tool were applied as conditional parameter. Analysis of microstructure, hardness, surface roughness and depth of modified zone(MZ) were searched. The best condition were obtained at R/S 600 rpm and T/S 100 mm/min. At this time, hardness was 82 HV, the surface roughness was 0.07 mm and the depth at MZ was 1.72 mm. Free defects microstructure and fine Si particles formation and strong forging effects were analyzed at MZ.

• 화약ㆍ발파
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• 제38권1호
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• pp.23-29
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• 2020

발파나 충격과 관련된 연구에서 충격센서를 이용한 하중 및 진동의 계측이 널리 사용되고 있다. 하지만 대부분의 충격센서는 고가이며 외부로부터의 손상에 대해 보호할 필요성이 존재한다. 본 연구에서는 충격센서의 외부 구조적 변화에 따른 계측 대상 매질로부터 입사되는 하중정보의 왜곡현상을 보정할 수 있는 방법에 대해 고찰하였다. 홉킨슨 압력봉 시스템을 이용해 충격센서로 전달되는 충격가속도를 산출하였으며, 이와 동시에 충격진동의 감쇠를 야기하는 센서 홀더를 고안 및 적용하여 센서의 출력 값에 대한 비교분석을 수행하였다. 결과적으로 센서에 적용된 외부 구조적 변화가 센서의 진동운동 자체를 왜곡시키는 비선형 거동이 아닌 경우 본 방법을 통한 충격센서 보정기술이 합리적으로 작용할 수 있을 것으로 판단하였다.

• 한국수소및신에너지학회논문집
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• 제13권3호
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• pp.214-223
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• 2002

Kinetic and effectiveness factors for methanol steam reforming using commercial copper-containing catalysts in a plug flow reactor were investigated over the temperature ranges of $180-250^{\circ}C$ at atmospheric pressure. The selectivity of $CO_2$/$H_2$ was almost 100%, and CO products were not observed under reaction conditions employed in this work. It was indicated that $CO_2$ was directly produced and CO was formed via the reverse water gas shift reaction after methanol steam reforming. The intrinsic kinetics for such reactions were well described by the Langmuir-Hinshelwood model based on the dual-site mechanism. The six parameters in this model, including the activation energy of 103kJ/mol, were estimated from diffusion-free data. The significant effect of internal diffusion was observed for temperature higher than $230^{\circ}C$ or particle sizes larger than 0.36mm. In the diflusion-limited case, this model combined with internal effectiveness factors was also found to be good agreement with experimental data.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제55권6호
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• pp.308-312
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• 2006

Partial Discharge (PD) phenomena occurred by different nature of insulating defects has been regarded as a random process by which Phase Resolved Partial Discharge Analysis(PRPDA) has been proposed and then commercially accepted for the diagnosis of the power apparatus since more than three decades. Moreover, for the same purpose, a novel approach based on the Chaotic Analysis(CAPD) has been proposed since 2000, in which Partial Discharge(PD) phenomena is suggested to be considered as a deterministic dynamical process. In this work, for the diagnosis of Gas Insulated Transformer(GITr), four different types of specimen were fabricated as a model of the possible defects that might possibly cause its sudden failures such as turn to turn insulation, inter coil insulation, free moving particle and protrusion. For this purpose, these defects are introduced into the Gas Insulated Transformer(GITr) mock-up and experimental investigations have been carried out in order to analyze the related Partial Discharge(PD) patterns by means of both Phase Resolved Partial Discharge Analysis(PRPDA) and Chaotic Analysis(CAPD) respectively and then their comparisons are made systematically.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 제5회 영호남 학술대회 논문집
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• pp.12-14
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• 2003

As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing (CMP). process was required for the global planarization of inter-metal dielectric (IMD) layer with free-defect. However, as the IMD layer gets thinner, micro-scratches are becoming as major defects. Micro-scratches are generated by agglomerated slurry, solidified and attached slurry in pipe line of slurry supply system. It is well known that the presence of hard and larger size particles in the CMP slurries increases the defect density and surface roughness of the polished wafers. In this paper, we have studied. aging effect the of CMP slurry as a function of particle size. We prepared and compared the self-developed silica slurry by adding of abrasives before and after annealing. As our preliminary experiment results, we could be obtained the relatively stable slurry characteristics comparable to original silica slurry in the slurry aging effect.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3163-3172
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• 2010

In this work, a novel method to synthesis of an acrylic superabsorbent hydrogel was reported. In the two stage hydrogel synthesis, first copolymerization reaction of acrylonitrile (AN) and acrylamide (AM) monomers using ammonium persulfate (APS) as a free radical initiator was performed. In the second stage, the resulted copolymer was hydrolyzed to produce carboxamide and carboxylate groups followed by in situ crosslinking of the polyacrylonitrile chains. The results from FTIR spectroscopy and the dark red-yellow color change show that the copolymerization, alkaline hydrolysis and crosslinking reactions have been do take place. Scanning electron microscopy (SEM) verifies that the synthesized hydrogels have a porous structure. The results of Brunauer-Emmett-Teller (BET) analysis showed that the average pore diameter of the synthesized hydrogel was 13.9 nm. The synthetic parameters affecting on swelling capacity of the hydrogel, such as AM/AN weight ratio and hydrolysis time and temperature, were systematically optimized to achieve maximum swelling capacity (330 g/g). The swollen gel strength of the synthesized hydrogels was evaluated via viscoelastic measurements. The results indicated that superabsorbent polymers with high water absorbency were accompanied by low gel strength. The swelling of superabsorbent hydrogels was also measured in various solutions with pH values ranging from 1 to 13. Also, the pH reversibility and on-off switching behavior makes the hydrogel as a good candidate for controlled delivery of bioactive agents. Finally, the swelling of synthesized hydrogels with various particle sizes obey second order kinetics.

• Bulletin of the Korean Chemical Society
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• 제29권5호
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• pp.1007-1012
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• 2008

Spray pyrolysis has been found as an excellent method for the preparation of mesoporous barium sulfate at higher temperature. Ethylene glycol, a reducing agent, and solvents had good inhibition effect for the preparation of $BaSO_4$ nano particles. The $BaSO_4$ solution was sprayed at 500 & 800 ${^{\circ}C}$ using different solvents such as methanol, ethanol, propanol and n-butyl alcohol. $N_2$ adsorption-desorption isotherm revealed that $BaSO_4$ is micropore free, possessing narrow mesopores size distribution and high BET surface areas of 72.52 $m^2\;g^{-1}$ at 800 ${^{\circ}C}$ using propanol as an additive. Scanning electron microscopy (SEM) indicates that the morphology of $BaSO_4$ nano material shows uniform shell like particles. Transmission electron microscopy (TEM) proved that the resulting BaSO4 nano particles were uniform in size and the average particle size was 4-8 nm. The surface functionality and ethylene glycol peaks were assessed by Fourier transform infrared resonance (FTIR) spectroscopy. Low intensity ethylene glycol specific absorption peak was observed in propanol which proved that propanol had good inhibition effect on the structural morphology of nano particles.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1994년도 하계학술대회 논문집 C
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• pp.1574-1576
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• 1994

$SF_6$ gas has become an important insulation medium in modern electric power apparatus, because of its high insulation withstand levels and good arc quenching capability. For the application of $SF_6$ gas in GIS the estimation of insulation properties is a fundamental point. Moreover the reduction of withstand levels in case of inhomogeneous fields caused by particles or fixed protrusions is of special interest. It is known that the presence of free conducting particles in GIS can significantly lower the insulating level of $SF_6$ gas at elevated pressure and also it has been recently shown that dielectric strength is greatly reduced by fast transients such as disconnector surges where metallic particles are involved. In this paper, we have disigned the particle test chamber rated 362kV for the purpose of investigating the discharge characteristics in SF6 gas where inhomogenius fields are caused by metallic particles.

• 한국해안해양공학회지
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• 제4권4호
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• pp.187-200
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• 1992

Taylor 정리를 이용하여 평균위치에서의 Eulerian유속으로부터 수립자의 시간에 따른 Lagrangian 운동궤적을 결정하는 방법이 제안되었다. 이 방법을 Stokes 유한진폭파이론에 적용하여 고차 파성분을 포함하는 수립자의 운동궤적과 질양이동속도를 결정하였다. Stokes 5차파이론의 적용 결과, 평균위치에서의 Eulerian 유속으로부터 결정한 수립자의 운동궤적은 자유수면 부근을 제외하고는 5차파이론에 의한 순간속도에 의해 계산된 값과 매우 좋은 일치를 보여주었다. Stokes 5차파 이론에 의한 질양이동속도는 종전의 2차파이론에 의한 질양이동속도보다 전수심에서 작은 값을 보여준다.

• 대한조선학회논문집
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• 제35권1호
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• pp.32-39
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• 1998

잠수된 원형실린더의 대진폭운동에 대한 수치해석이 제시된다. 방법은 포텐셜이론에 근간을 두고 정현파중에서 2차원 운동은 초기치 문제로 귀결된다. 완전한 비선형자유표면 조건은 수치 계산영역에서 적용되고, 비선형 수치해는 수치계산의 임의의 가정된 경계를 따라 외부영역에서의 선형해로서 부과된다. 잠수된 원형실린더의 대진폭운동의 계산은 직접적으로 시간영역에서 시뮬레이션된다. 계산결과로 부터 물체와 유체입자의 상호 운동은 부양운동과 표류운동에 중요한 효과를 준다.