• 제목/요약/키워드: Particle-free

검색결과 608건 처리시간 0.031초

Mechanics of the slaking of shales

  • Vallejo, Luis E.
    • Geomechanics and Engineering
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    • 제3권3호
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    • pp.219-231
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    • 2011
  • Waste fills resulting from coal mining should consist of large, free-draining sedimentary rocks fragments. The successful performance of these fills is related to the strength and durability of the individual rock fragments. When fills are made of shale fragments, some fragments will be durable and some will degrade into soil particles resulting from slaking and inter-particle point loads. The degraded material fills the voids between the intact fragments, and results in settlement. A laboratory program with point load and slake durability tests as well as thin section examination of sixty-eight shale samples from the Appalachian region of the United States revealed that pore micro-geometry has a major influence on degradation. Under saturated and unsaturated conditions, the shales absorb water, and the air in their pores is compressed, breaking the shales. This breakage was more pronounced in shales with smooth pore boundaries and having a diameter equal to or smaller than 0.060 mm. If the pore walls were rough, the air-pressure breaking mechanism was not effective. However, pore roughness (measured by the fractal dimension) had a detrimental effect on point load resistance. This study indicated that the optimum shales to resist both slaking as well as point loads are those that have pores with a fractal dimension equal to 1.425 and a diameter equal to or smaller than 0.06 mm.

Evaluation of Loess Capability for Adsorption of Total Nitrogen (T-N) and Total Phosphorous (T-P) in Aqueous Solution

  • Kim, Daeik;Ryoo, Keon Sang;Hong, Yong Pyo;Choi, Jong-Ha
    • Bulletin of the Korean Chemical Society
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    • 제35권8호
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    • pp.2471-2476
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    • 2014
  • The aim of the present study is to explore the possibility of utilizing loess for the adsorption of total phosphorous (T-P) and total nitrogen (T-N) in water. Batch adsorption studies were performed to evaluate the influences of various factors like initial concentration, contact time and temperature on the adsorption of T-P and T-N. The adsorption data showed that loess is not effective for the adsorption of T-N. However, loess exhibited much higher adsorption capacity for T-P. At concentration of $1.0mgL^{-1}$, approximately 97% of T-P adsorption was achieved by loess. The equilibrium data were fitted well to the Langmuir isotherm model. The pseudo-second-order kinetic model appeared to be the better-fitting model because it has higher $R^2$ compared with the pseudo-first-order and intra-particle kinetic model. The theoretical adsorption equilibrium $q_{e,cal}$ from pseudo-second-order kinetic model was relatively similar to the experimental adsorption equilibrium $q_{e,exp}$. The thermodynamic parameters such as free energy ${\Delta}G$, the enthalpy ${\Delta}H$ and the entropy ${\Delta}S$ were also calculated.

Technical Investigation into the In-situ Electron Backscatter Diffraction Analysis for the Recrystallization Study on Extra Low Carbon Steels

  • Kim, Ju-Heon;Kim, Dong-Ik;Kim, Jong Seok;Choi, Shi-Hoon;Yi, Kyung-Woo;Oh, Kyu Hwan
    • Applied Microscopy
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    • 제43권2호
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    • pp.88-97
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    • 2013
  • Technical investigation to figure out the problems arising during in-situ heating electron backscatter diffraction (EBSD) analysis inside scanning electron microscopy (SEM) was carried out. EBSD patterns were successfully acquired up to $830^{\circ}C$ without degradation of EBSD pattern quality in steels. Several technical problems such as image drift and surface microstructure pinning were taking place during in-situ experiments. Image drift problem was successfully prevented in constant current supplying mode. It was revealed that the surface pinning problem was resulted from the $TiO_2$ oxide particle formation during heating inside SEM chamber. Surface pinning phenomenon was fairly reduced by additional platinum and carbon multi-layer coating before in-situ heating experiment, furthermore was perfectly prevented by improvement of vacuum level of SEM chamber via leakage control. Plane view in-situ observation provides better understanding on the overall feature of recrystallization phenomena and cross sectional in-situ observation provides clearer understanding on the recrystallization mechanism.

황산티타늄의 첨가가 판상 α-Al2O3의 결정성장에 미치는 영향 (Effect of Titanium Sulfate Addition on Crystal Growth of the Flaky α-Al2O3)

  • 박병기;조선미;이정민
    • 한국세라믹학회지
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    • 제42권5호
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    • pp.338-345
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    • 2005
  • To prepare the complex gel of flux and pseudo-boehmite used in precursor of the flaky ${\alpha}-A1_2O_3$ crystal, aqueous solution of the mixture of sodium carbonate and sodium phosphate was added with stirring in aqueous solution of the mixture of sodium sulfate, potassium sulfate and titanium sulfate. The complex gel was dried at $110^{\circ}C$ and was crystallized above $1,050^{\circ}C$, and then the effect of the amount of titanium sulfate on size, morphology, thickness and crystal size distribution of the flaky ${\alpha}-A1_2O_3$ crystal was investigated. Addition of titanium sulfate was prevented the aggregation and generation of twin crystal, and had an effect on the crystal size and the thickness during crystal growth. When the amount of titanium sulfate was more than 6 g, particle size was decreased but was free from crystal twining and aggregation. On the other hand, when the amount of titanium sulfate was lower than 6 g, crystal size was increased but crystal twinning and aggregation were noticed.

3차원 전극을 사용한 Rhodamine B의 전기분해에 미치는 운전인자의 영향 (Effect of Operating Parameters on Electrochemical Degradation of Rhodamine B by Three-dimensional Electrode)

  • 김동석;박영식
    • 한국환경보건학회지
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    • 제35권4호
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    • pp.295-303
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    • 2009
  • A simulated wastewater containing the dye Rhodamine B (RhB) was electrolytically treated using a three-dimensional electrode reactor equipped with granular activated carbon (GAC) as particle electrode. The effect of type of packing material (GAC, ACF, Nonwoven fabric fiber coated with activated carbon), amounts of GAC packing (25-100 g), current (0.5-3 A) and electrolyte concentration (0.5-3 g/l) was evaluated. Experimental results showed that performance for RhB decolorization of the 3 three-dimensional electrodes lie in: GAC > Nonwoven fabric fiber > ACF. When considered RhB decolorization, oxidants concentration and electric power, optimum GAC dosage was 50 g. Generated concentration of 3 oxidants ($ClO_2$, free Cl, $H_2O_2$) was increased with increase of applied current, however optimum current for RhB degradation was 2.5 A. The oxidants concentration was increased with increase of NaCl concentration and optimum NaCl dosage for RhB degradation was 1.5 g/l.

An optimum design study of interlacing nozzle by using Computational Fluid Dynamics

  • Juraeva Makhsuda;Ryu Kyung-Jin;Kim Sang-Dug;Song Dong-Joo
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2006년도 PARALLEL CFD 2006
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    • pp.395-397
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    • 2006
  • Air interlacing serves to protect the yarn against damage, strengthens inter-filament compactness or cohesion, and ensures fabric consistency. The air interlacing nozzle is used to introduce intermittent nips to a filament yarn so as to improve its performance in textile processing. The effect of various interlacing nozzle geometries on the interlacing process was studied. The geometries of interlacing nozzles with single or multiple air inlets located across the width of yarn channels are investigated. The basis case is the yarn channel, with a perpendicular main air inlet in the middle. Other cases have main air inlets, slightly inclined double sub air inlets, The yarn channel cross sectional shapes are either semicircular or rectangular shapes. The compressed impinging jet from the main air inlet hole hits the opposing bottom wall of the yarn channel, is divided into two branches, joins with the compressed air coming out from sub air inlet at the bottom and creates two free jets at both ends of the yarn channel. The compressed air movement in the cross-section consists of two opposing directional vortices. The CFD-FASTRAN flow parallel solver was used to perform steady simulations of impinging jet flow inside of the interlace nozzles. The vortical structure and the flow pattern such as pressure contour, particle traces, velocity vector plots inside of interlace nozzle geometry are discussed in this pater.

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열처리된 산화막 CMP 슬러리의 노화 현상 (Aging effect of annealed oxide CMP slurry)

  • 이우선;신재욱;최권우;고필주;서용진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.335-338
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    • 2003
  • Chemical mechanical polishing (CMP) process has been widely used to planarize dielectric layers, which can be applied to the integrated circuits for sub-micron technology. Despite the increased use of CMP process, it is difficult to accomplish the global planarization of in the defect-free inter-layer dielectrics (ILD). Especially, defects such as micro-scratch lead to severe circuit failure which affect yield. CMP slurries can contain particles exceeding $1\;{\mu}m$ in size, which could cause micro-scratch on the wafer surface. In this paper, we have studied aging effect the of CMP sin as a function of particle size. We prepared and compared the self-developed silica slurry by adding of abrasives before and after annealing. As our preliminary experiment results, we could be obtained the relatively stable slurry characteristics comparable to original silica slurry in the slurry aging effect.

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유한 요소 모델을 이용한 왕복동식 압축기 밸브의 거동 해석 및 형상 설계 민감도 해석 (Computer Simulation and Shape Design Sensitivity Analysis of the Valve inside the Reciprocal Compressor using Finite Element Model)

  • 이제원;왕세명;주재만;박승일;이성태
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2002년도 춘계학술대회논문집
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    • pp.796-801
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    • 2002
  • The goal of this research is the shape design of the valve using a computer simulation. For an analysis a basic mathematical model describing compression cycle is considered as consisting of five sets of coupled equations. These are the volume equation (kinematics), valve dynamic equation (dynamics), ideal gas equation (thermodynamics), Bernoulli equation (fluid dynamics), and dynamic equation of fluid particle based on Helmholtz equation (acoustics). Valve motion is made by the superposition of free vibration modes obtained by the finite element method. That is, the eigenvalues and eigenvectors are the sufficient modeling factors fur the valve in the simulation program. Thus, to design a shape of the valve, shape design sensitivity through chain-ruled derivatives is considered from two sensitivity coefficients, one is the design sensitivity of the capability of compressor with respect to the eigenvalues of the valve, and the other is the design sensitivity of the eigenvalue with respect to the shape change of the valve. In this research, the continuum design sensitivity analysis concepts are used for the latter.

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In-vitro study on the hemorheological characteristics of chicken blood in microcirculation

  • Ji, Ho-Seong;Lee, Jung-Yeop;Lee, Sang-Joon
    • Korea-Australia Rheology Journal
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    • 제19권2호
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    • pp.89-95
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    • 2007
  • The flow characteristics of chicken blood in a micro-tube with a $100{\mu}m$ diameter are investigated using a micro-Particle Image Velocimetry (PIV) technique. Chicken blood with 40% hematocrit is supplied into the micro-tube using a syringe pump. For comparison, the same experiments are repeated for human blood with 40% hematocrit. Chicken blood flow has a cell-free layer near the tube wall, and this layer's thickness increases with the increased flow speed due to radial migration. As a hemorheological feature, the aggregation index of chicken blood is about 50% less than that of human blood. Therefore, the non-Newtonian fluid features of chicken blood are not very remarkable compared with those of human blood. As the flow rate increases, the blunt velocity profile in the central region of the micro-tube sharpens, and the parabolicshaped shear stress distribution becomes to have a linear profile. The viscosity of both blood samples in a low shear rate condition is overestimated, while the viscosity in a high shear rate range is underestimated due to radial migration and the presence of a cell-depleted layer.

냉동 후막 성형에 의한 다공성 Al2O3 필름 제조 (Fabrication of Porous Al2O3 Film by Freeze Tape Casting)

  • 신란희;구준모;김영도;한윤수
    • 한국분말재료학회지
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    • 제22권6호
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    • pp.438-442
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    • 2015
  • Porous thick film of alumina which is fabricated by freeze tape casting using a camphene-camphor-acrylate vehicle. Alumina slurry is mixed above the melting point of the camphene-camphor solvent. Upon cooling, the camphene-camphor crystallizes from the solution as particle-free dendrites, with the $Al_2O_3$ powder and acrylate liquid in the interdendritic spaces. Subsequently, the acrylate liquid is solidified by photopolymerization to offer mechanical properties for handling. The microstructure of the porous alumina film is characterized for systems with different cooling rate around the melting temperature of camphor-camphene. The structure of the dendritic porosity is compared as a function of ratio of camphene-camphor solvent and acrylate content, and $Al_2O_3$ powder volume fraction in acrylate in terms of the dendrite arm width.