• Title/Summary/Keyword: Particle-alloys

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Effect of Primary Si size and Residual Stress on the Wear Properties of B.390 Al Alloys (B.390 알루미늄 합금의 마모특성에 미치는 초정Si 입자크기와 잔류응력의 영향)

  • Kim, Heon-Joo;Kim, Sung-Jae
    • Journal of the Korean Society for Heat Treatment
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    • v.19 no.1
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    • pp.20-29
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    • 2006
  • Wear behaviour of B.390 aluminum alloy with different particle sizes of primary Si against a SM45C counterface was studied as a function of wear load and sliding velocity, using pin-on-disk apparatus under dry condition. The wear rate of specimen with fine primary Si particles showed increased wear resistance at high wear load, on the other side wear resistance of coarse primary Si particle size was improved at low wear load. As the compressive residual stress in the matrix increased remarkably by liquid nitrogen(LN) treatment, wear resistance of the LN treated specimen was more excellent than that of T6 treated specimen.

The effect of particle size on hydrogen storage of Mm-based alloys (Mn계 합금의 수소 저장에 대한 입자크기의 영향)

  • Park, Chan Kyo;Bae, Jang Soon;Cho, Bum Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.11 no.4
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    • pp.171-177
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    • 2000
  • Metal hydride used as hydrogen storage material usually needs the activating process to store the hydrogen at high temperature or high pressure. In general as the particle size of metal hydride becomes smaller, approached to the micro, furthermore, nano scale, storage ability and reaction kinetics are reported to be increased, because the specific surface is extremely increased. But the experimental results demonstrated that the optimum particle size is existed for the best absorbing performance, opposite to the usual expectation. This results from the particles to be come amorphous with their approaching to micro and nano scale, in the storage site within the metal hydride lattice is decreased, which is proved by XRD and SEM.

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Hydrogenation Study of Mg-based Alloys by mechanical Grinding Reaction for Hydrogen Storage of Fuel Cell (연료전지의 수소저장용 마그네슘계 합금의 기계적 분쇄 반응에 의한 수소화 특성 평가)

  • Kim, Ho-Sung;Suh, Hee-Seok;Cha, Jae-Sang
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.6
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    • pp.69-74
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    • 2006
  • The effects of mechanical grinding(MG) treatment on the hydrogen storage of $Mg_2Ni$ alloy and $Mg_2Ni$ composite alloy($Mg_2Ni+graphite$) were investigated by pressure-composition-temperature(PCT) measurement, the micro-electrode technique of electrochemistry and etc, in which PCT was measured at high temperature(around $300[^{\circ}C]$) of gas phase and a carbon-filament micro-electrode for electrochemical evaluation was manipulated to make electrical contact with the particle in 1M KOH aqueous solution. It was found that the hydrogenation properties of $Mg_2Ni$ and graphite composite particle were greatly improved by the mechanical grinding treatment by which the $Mg_2Ni$ and graphite composite alloys could be changed into microstructure and nano-level particles. namely; the hydrogen dissociation pressure of PCT measurement was decreased from 0.55[MPa] to 0.42[MPa] and hydrogenation peaks by micro-electrode were also observed more clearly on the same sample.

The Theoretical and Experimental Value on the Stress-Strain Behavior of Dual Phase Steels (복합조직강의 응력-변형 거동에 관한 이론치와 실험치)

  • 오택열;김석환;유용석
    • Journal of the Korean institute of surface engineering
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    • v.26 no.2
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    • pp.63-70
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    • 1993
  • The mechanical properties of ferrite-martensited dual phases steels are affected by the microstructural factors, such as martensited volume fractions, ferrite grain size, strength ratio, connectivity, etc. Two phase alloys are technologically important. However, there is a lack of understanding as to stress-strain behavior of dual phase alloy in terms of stress-strain behavior of each component phases. The lack of the understanding stems from the complex deformation behavior of two phase alloys. The aim of this study is to rationalize stress-strain behavior of dual phase alloy in terms of the stress-strain behavior of component phase by systematically considering all the factors listed above. It was found that for a given martensite volume fraction, the calculated stress-strain curve was higher for a finer particles size than for a coarse particle sized within the range of the strains considered, and this behavior was seen for all the different volume fraction alloys considered. The calculated stress-strain curves were compared with corresponding experimental curves, and in general, good agreement was found. The maximum difference in flow stress between the calculated and the experimental results occurs at the nearly beginning of the plastic deformation.

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Microstructure and Mechanical Properties of Solution Treatment and Sr-Modification of Al-12%Si-1.5%Cu Alloy

  • Surin, Prayoon;Wong on, Jessada;Eidhed, Krittee
    • International Journal of Advanced Culture Technology
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    • v.3 no.2
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    • pp.132-137
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    • 2015
  • The purpose of this paper was to investigate the effects of solution treatment time and Sr-modification on the microstructure and property of the Al-Si piston alloy. It was found that as-cast microstructures of unmodified and Sr-modified Al-Si alloys consisted of a coarse acicular plate of eutectic Si, $Cu_3NiAl_6$ and $Mg_2Si$ phases in the ${\alpha}$-Al matrix but different in size and morphology. Both size and inter-particle spacing of Si particles were significantly changed by increasing of the solution treatment time. After a short solution treatment, the coarse acicular plate of the eutectic Si appears to be fragmented. Fully modified microstructure of Sr-modified alloy can reduce the solution treatment time to shorter compared to unmodified alloy. The maximum of a peak hardness value is found in the very short solution treatment of both Al-Si piston alloys. Compared to 10 h solution treatment, the solution treatment of 2-4 h is sufficient to achieve appropriate microstructures and hardness. The short solution treatment is very useful to increase the productivity and to reduce the manufacturing cost of the Al-Si piston alloys.

Reflectance Characteristics of Al-Si based Alloys according to Powder Size and Composition (Al-Si계 합금의 분말 크기 및 조성에 따른 반사율 변화 특성)

  • Choi, Gwang Mook;Chae, Hong Jun
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.22-27
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    • 2019
  • In this study, the effects of powder size and composition on the reflectance of Al-Si based alloys are presented. First, the reflectance of Al-Si bulk and powder are analyzed to confirm the effect of powder size. Results show that the bulk has a higher reflectance than that of powder because the bulk has lower surface defects. In addition, the larger the particle size, the higher is the reflectance because the interparticle space decreases. Second, the effect of composition on the reflectance by the changing composition of Al-Si-Mg is confirmed. Consequently, the reflectance of the alloy decreases with the addition of Si and Mg because dendrite Si and $Mg_2Si$ are formed, and these have lower reflectance than pure Al. Finally, the reflectance of the alloy is due to the scattering of free electrons, which is closely related to electrical conductivity. Measurements of the electrical conductivity based on the composition of the Al-Si-Mg alloy confirm the same tendency as the reflectance.

Effects of Stirring Condition and Refining Element Addition on the Primary Si Particle Morphology of Hypereutectic Al-Si Alloys Semi-Solid State Processing (과공정 Al- Si 합금의 반응고 교반시 초정 Si 형상에 미치는 교반조건 및 개량원소 첨가 영향)

  • Kim, In-Joon;Kim, Do-Hyang
    • Journal of Korea Foundry Society
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    • v.18 no.5
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    • pp.474-480
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    • 1998
  • Microstructural characteristics of semi-solid state processed hypereutectic Al-Si alloys have been investigated. Main concern of the present study is to investigate the effects of P and Sr addition on the size and morphology change of the primary Si particles. Refinement of the primary Si particles was observed with the addition of P and Sr at the early stage of semi-solid state processing, but such a refining effects became negligible resulting in Si particles with a near-spherical morphology with continuous stirring. This implies that the microstructural transformation mechanism became more dependent to stirring effects than to the alloying effects during semi-solid state processing. Brittle fracture and agglomeration were proposed as the mechanisms for microstructural alterations during semi-solid state processing.

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The factors of dimensional change of Fe-Cu-C sintered objects

  • Fujinaga, Masashi;Suzuki, Yoshitomo
    • Journal of Powder Materials
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    • v.5 no.4
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    • pp.299-302
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    • 1998
  • Dimensional accuracy is one of the most important issues in the production of sintered parts. The iron-copper-carbon system is commonly used alloys in sintered structural parts production. The dimensional control of these alloys, however, is not easy because of their complex sintering behavior. This study is an effort to clarify the influence of common factors on dimensional change of Fe-Cu-C sintered structural parts. We determined the effect of such various parameters as chemical composition, particle diameter, compact density, sintering temperature and sintering time on dimensional changes. Consequently, we obtained a useful formula to predict the final dimension in function of these parameters. The effect of typical impurities in copper powder on the dimensional change of sintered parts has also been described.

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High Temperature Friction Characteristic of $Al-SiC_{p}$ Composite Coating Prepared by Plasma Thermal Spray (플라즈마 용사에 의해 제조한 $Al-SiC_{p}$ 복합재료 코팅층의 고온마찰특성)

  • 민준원;유승을;서동수
    • Tribology and Lubricants
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    • v.19 no.5
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    • pp.274-279
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    • 2003
  • $Al-SiC_{p}$ composite layer was prepared by plasma thermal spray on aluminum substrate. The homogeneously dispersed composite powder for thermal spray was fabricated by mechanical alloying with ball mill. The friction tests of the composite layers and commercial aluminum alloys for comparison were performed in the temperature range of 20∼$260^{\circ}C$ with the interval of $40^{\circ}C$ with steel counter-face. Friction coefficient was recorded during test sequence, and the microstructure of surface and debris was investigated by optical and scanning electron microscope. Friction coefficients of composite and aluminum alloys at room temperature were similar except pure aluminum. As the temperature increase, friction coefficient was increased rapidly in AC4C, AC2A. But friction coefficient of $Al-SiC_{p}$ composite was not increased so much up to $220^{\circ}C$. Consequently, the reinforcement of $SiC_{p}$ into aluminum matrix increased the stability of friction coefficient as well as wear resistance.

Study of CO Oxidation on Well-Characterized Pt-Ru/C Electrocatalysts Having Different Composition

  • Min, Myoung-Ki;Kim, Joo-Hoon;Kim, Ha-Suck
    • Bulletin of the Korean Chemical Society
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    • v.31 no.1
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    • pp.151-156
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    • 2010
  • In this paper, we characterized bimetallic Pt-Ru/C alloy catalysts having four different compositions and compared the catalytic activities of the prepared alloys for CO oxidation. ICP-AES, EDS, XRD, TEM, and XAS were used to investigate the composition, degree of alloying, particle size, and electronic structure of the prepared Pt-Ru/C catalysts. Those results indicated the synthesis of the alloy catalysts with intended composition and uniform size. The electrochemical study of the characterized alloys showed higher catalytic activity for CO oxidation than that of the commercial Pt/C (E-TEK, Inc., 20 wt %) catalyst. Especially, it was shown that the alloy catalyst with Ru composition of 50 atomic % gave the highest catalytic activity for CO oxidation.