• Journal of Electrochemical Science and Technology
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• v.1 no.2
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• pp.85-91
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• 2010

We have studied the origin of an additional plateau of $Li_{4+x}Ti_5O_{12}$ (LTO) observed at 0.7 V (vs. Li/$Li^+$). Some LTO has to be discharged down to below 1.0 V forming two-stage plateau (1.5 V and 0.7 V) in order to obtain most of capacity while others could achieve the same level of capacity at higher potential (1.0 V vs. Li/$Li^+$) forming one plateau (1.5 V). The particle size effect has been investigated as a possible reason of this. The 0.7 V plateau was gradually elongated with increasing the particle size. The structural variations and kinetic behaviors during discharge were carefully examined by in-situ XRD technique and OCV measurement. According to structural and electrochemical verifications, the kinetic limitation of $Li^+$ insertion is responsible primarily for the two-stage plateau which is related to the particle size of LTO rather than the formation of new intermediate phase during discharge. Herein, we propose a possible reaction model to elucidate this abnormal behavior of LTO below 1.0 V (Li/$Li^+$).

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.536-541
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• 2001

A high resolution digital cinematic Particle Image Velocimetry(PIV) has been developed. The system consists of a high speed CCD camera, a continuous Ar-ion laser and a computer with camera controller. To improve the spatial resolution, we adopt a Recursive Technique for velocity interrogation. At first, we obtain a velocity vector for a larger interrogation window size based on the conventional two-frame cross-correlation PIV analysis using the FFT algorithm. Based on the knowing velocity information, more spatially resolved velocity vectors are obtained in the next iteration step with smaller interrogation windows. The correct velocity vector at the first step is found to be critical, so we apply a Multiple Correlation Validation(MCV) technique in order to decrease the spurious vectors. The MCV technique turns out to improve SNR(Signal to Noise Ratio) of the correlation table. The developed cinematic PIV method has been applied to the measurement of the unsteady flow characteristics of a Rushton turbine mixer. A total of 3,245 instantaneous velocity vectors were successfully obtained with 4 ms time resolution. The acquired spatial resolution corresponds the performance of the conventional high resolution digital PIV system using a $1K{\times}1K$ CCD camera.

• Journal of the Korean Society of Propulsion Engineers
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• v.4 no.1
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• pp.36-45
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• 2000

Most researches for impinging jet spray have been focused on under-standing the breakup mechanism of a liquid sheet formed by the collision of jets and modeling the spray breakup using experimental data. For this reason, there have been few studies on the characteristics of the spatial spray distribution which affects significantly the combustion efficiency. Hence, we measured the radial distribution of fuel massflux using a like-doublet type injector. Instead of PDPA(Phase Doppler Particle Analyzer) which has been used only for the point measurement of the drop size of spray, PLIF(Planar Laser Induced Fluorescence) technique was developed lot the 2-D measurement of the massflux distribution of spray Indirect photography technique was also used to verify PLIF data.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.4
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• pp.209-218
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• 2021

Studies of pore structure in shale gas reservoirs are essential to increase recovery rates, which is in the spotlight concerning unconventional resources. In this study, the distribution of pores in shale gas reservoir sample were observed using Scanning Electron Microscope Particle Analysis (SELPA), which is appropriate to analyze the distribution of particle or shape for sample in large area. A sample from the A-068 borehole drilled in the Liard Basin was analyzed; calcite is the main mineral. The pore size ranges from tens of nanometers to hundreds of micrometers and the contribution of each pore size to overall sample porosity was determined using SELPA. The distribution of pores was determined by observing the surface in the same area at magnifications of ×1000, ×3000 and ×5000. Pores less than 100 nm were observed at high magnifications and confirm that small-scale pore distribution can be analyzed and identified rapidly using SELPA. The method introduced in this study will be useful to understand pore structures in unconventional reservoirs.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.6
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• pp.890-898
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• 2022

Dispersion of suspended sediment, caused by coastal and marine development, is a key item in assessing marine environmental impact as it adversely affects marine life by increasing the level of turbidity and decreasing the amount of sunlight in seawater. However, its estimation has not been reliable because of the absence of a standard for the data measurement and divergent approaches to the impact assessment. In this study, we examined the estimation models from 58 Marine Environmental Impact Statements (MEISs, 2012-2014) to identify the gaps in the assessment and devise ways of improving the estimation. We developed four index items-grid system; unit load, particle size, and settling velocit-to evaluate their reliability in the estimation. The mean reliability score of each index was overall low-25 for grid system, 60 for unit load, 34 for particle size, and 17 for settling velocity. To ensure high reliability, it is important to develop a standard guideline that defines precise measurement of suspended sediment for unit load and settling velocity by particle size, followed by a grid system with compatible size for modelling. This can improve the estimation and thus underlie coherent impact assessment of suspended sediment dispersion on marine environment.

• Journal of ILASS-Korea
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• v.4 no.2
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• pp.33-39
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• 1999

This paper presents the spray atomization characteristics of the high-pressure gasoline injector for the direct-injection gasoline engine. The gasoline sprays of the injector were minted into a pressurized spray chamber with a optical access at various ambient pressures. The atomization characteristics of fuel spray such as mean diameter, mean velocity of droplet were measured by the phase Doppler particle analyzer system. In order to investigate the effect of fuel injection pressure on the quantitative characteristics of spray, the global visualization and experiment of particle measurement in the fuel spray were investigated at 3, 5 and 7 MPa of injection pressure under different ambient pressure in the spray chamber. Based on the results of this work, the fuel injection pressure of fuel injector in gasoline direct-injection engine have influence upon distribution of the mean velocity and droplet size of fuel spray. Also, the influence of injection pressure on the velocity distribution at various measuring location were investigated.

• Journal of the Korean Ceramic Society
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• v.26 no.5
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• pp.691-697
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• 1989

Fine TiO2 and BaTiO3 powders having spherical particles were synthesized by ultrasonic spray pyrolysis of alcoholic solution of metal alkoxide in an electric furnace heated at 400-90$0^{\circ}C$. Microstructure and composition of particles synthesized were observed by TEM and XRD respectively. Spectific surface area of powders synthesized was examined through BET specific surface area measurement. TEM observation revealed that the particle size did not change irrespective of pyrolysis temperature but decreased according to the increase of concentration and spherical particle was consisted of primary particles of about 0.02${\mu}{\textrm}{m}$. As for BaTiO3 powder, the ratio of Ti/Ba was 0.987 by EDX analysis.

• Journal of the Korean Society of Combustion
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• v.1 no.1
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• pp.57-64
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• 1996

The atomizing characteristics in a spray injected from a twin fluid atomization nozzle have been investigated. The Sauter mean diameters as mean diameter are compared with wavelength calculated from the instability theory. The Sauter mean diameter are measured by the Fraunhofer diffraction theory using the Malvern particle sizer. The wavelength is calculated using the mean relative velocity instead of the exit relative velocity of nozzle. Also shadowgraphy technique is used to visualize atomization phenomena. This paper gives a possibility that the mean diameter can be predicted with the wavelength obtained by the simple instability theory.

• Korea-Australia Rheology Journal
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• v.17 no.2
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• pp.35-40
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• 2005

Nanofluid is a novel heat transfer fluid prepared by dispersing nanometer-sized solid particles in traditional heat transfer fluid to increase thermal conductivity and heat transfer performance. In this research we have considered the rheological properties of nanofluids made of CuO particles of 10-30nm in length and ethylene glycol in conjunction with the thermal conductivity enhancement. When examined using TEM, individual CuO particles have the shape of prolate spheroid of the aspect ratio of 3 and most of the particles are under aggregated states even after sonication for a prolonged period. From the rheological property it has been found that the volume fraction at the dilute limit is 0.002, which is much smaller than the value based on the shape and size of individual particles due to aggregation of particles. At the semi-dilute regime, the zero shear viscosity follows the Doi-Edwards theory on rodlike particles. The thermal conductivity measurement shows that substantial enhancement in thermal conductivity with respect to particle concentration is attainable only when particle concentration is below the dilute limit.

• Journal of the Korean institute of surface engineering
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• v.26 no.5
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• pp.255-262
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• 1993

Major parameters determining the extent of Ca utilization were investigated for their calcination/sulfation behavior of limestone in the AFBC(Atmospheric Fluidized Bed Combustion) environments. Three different particle sizes of Fredonia limestone were investigated in the lab-scale tubular reactor. The results of the calcination codnversion of limestone imply that thesd decomposition rate of CaCO3 into CaO is dependent on the amount of heat which limestone absorbed. Hg porosimeter measurement of calcined limestone illustrated that surface area and pore volume are increased with decreasing particle size. Raw Fredonia limestone and sequentially as well as simultaneously calcined/sulfated limestones were also examined using SEM. The SEM Studied showed that the surface of the calcined limestone particles is more diffusive nature than that of the parent calcite. However, the sulfur distribution pattern of simultaneously-treated particles and that of the se-quentially-treated one shows no difference.