• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.659-665
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• 2015

Loading of hydrophobic ${\alpha}$-tocopherol into nanostructured lipid carrier (NLC) was performed for improving its oxidative stability. First, various NLCs with different constituents and mixing ratios were prepared and their characteristics were investigated. While the stable NLCs were made when cetyl palmitate (CP) or glyceryl monosterate (GMS) was used as a solid lipid, the phase separation occurred in the NLCs consisting of stearic acid. Particle sizes of the NLCs were several hundreds of nanometers and the size decreased with increasing the ratio of solvent to lipid. It was examined from DSC thermogram and anisotropy test that the degree of crystallinity of the lipid phase decreased and the lipid matrix became less ordered when octyldodecanol, a long chain fatty alcohol, was added into the solid lipid. The oxidative stability of ${\alpha}$-tocopherol in NLC was remarkably improved compared to that in solution or emulsion under high temperature ($45^{\circ}C$) and UV radiation, which was verified through DPPH test and peroxide value measurement.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3576-3582
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• 2014

Zeolite-templated carbons (ZTCs), which have high specific surface area, were prepared by a conventional templating method using microporous zeolite-Y for catalyst supports in direct methanol fuel cells. The ZTCs were synthesized at different temperatures to investigate the characteristics of the surface produced and their electrochemical properties. Thereafter, Pt-Ru was deposited at different carbonization temperatures by a chemical reduction method. The crystalline and structural features were investigated using X-ray diffraction and scanning electron microscopy. The textural properties of the ZTCs were investigated by analyzing $N_2$/77 K adsorption isotherms using the Brunauer-Emmett-Teller equation, while the micro- and meso-pore size distributions were analyzed using the Barrett-Joyner-Halenda and Harvarth-Kawazoe methods, respectively. The surface morphology was characterized using transmission electron microscopy and inductively coupled plasma-mass spectrometry. The electrochemical properties of the Pt-Ru/ZTCs catalysts were also analyzed by cyclic voltammetry measurements. From the results, the ZTCs carbonized at $900^{\circ}C$ show the highest specific surface areas. In addition, ZTC900-PR led to uniform dispersion of Pt-Ru on the ZTCs, which enhanced the electro-catalytic activity of the Pt-Ru catalysts. The particle size of ZTC900-PR catalyst is about 3.4 nm, also peak current density from the CV plot is $12.5mA/cm^2$. Therefore, electro-catalytic activity of the ZTC900-PR catalyst is higher than those of ZTC1000-PR catalyst.

• Journal of computational fluids engineering
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• v.20 no.4
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• pp.81-92
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• 2015

Construction waste mainly consists of concrete aggregates of various size. Improper handling of concrete waste would be a major environmental problem whereas its recycling would be both economically useful and environmentally friendly. Bigger concrete aggregates are crushed and converted to medium and fine particles to make them recyclable. An apparatus to separate the concrete aggregates by their size is thus needed for their effective recycling. In this work, segregation of concrete particles in air flows from a newly designed rotary separator having three stages of blades is simulated using a commercial software, ANSYS-CFX. Both 2-D and 3-D models with 360, 240 and 180 blades in each stage are considered. Fundamental mechanism of separation of particles(pase) and the effect of design parameters such as particle size, rotor speed, air flow rate etc. on the performance of the separator are investigated. Critical size of particles that can be separated by the developed separator is also presented in this work. Simulation results are overall in good agreement with data predicted from the theoretical model previously reported in the companion paper.

• Journal of computational fluids engineering
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• v.20 no.4
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• pp.70-80
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• 2015

Construction waste is known to include a large part of coarse and fine aggregates, which can be recirculated in the industry. Separating those aggregates economically from the waste has been thus considered to be one of the most important issues in this field. In particular, paste mixed in the waste causes significant complain from the inhabitants living near the place where waste-processing equipments are built and operated. In this study, we investigate the operational principle of a newly developed paste separator by using theoretical (in this first part) and CFD (in the second part) analysis. The separator consists of a rotor which turned out to play a significant role in separating those pastes from the aggregates. Under suitable assumptions regarding the air flow velocity as well as the particle velocity, we show that particles can be stagnant at the outlet of the roto channel for a wide range of parameter values, which allow the particles to get enough time to settle down via the gravitation. We also demonstrate such phenomenon by using a simple numerical simulation.

• Journal of the Korean Applied Science and Technology
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• v.29 no.1
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• pp.122-128
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• 2012

The influences of fluorescence, scattering, and flocculation in turbid material by light scattering of L-aspartic acid, preservative and emulsifier were interpreted for the scattered fluorescence intensity and wavelength. They have been studied the molecular properties by the spectroscopy of laser induced fluorescence (LIF) and flocculation. The effects of optical properties in scattering media have been found by the optical parameters(${\mu}_s$, ${\mu}_a$, ${\mu}_t$). Flocculation is an important step in many solid-liquid separation processes and is widely used. When two particles approach each other, interactions of several colloid particles can come into play which may have major effect on the flocculation and LIF process. The values of scattering coefficient ${\mu}_s$ are large by means of the increasing scattering of scatterer, The values have been found that the slope decays exponentially as a function of concentration from laser source to detector by our experimental result. It may also aid in designing the best model for oil chemistry, bio-pharmaceutical products, laser medicine and application of medical engineering on LIF and coagulation in particle transport mode.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.3
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• pp.33-37
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• 2018

In order to recycle sewage dredging soil, we analyzed particle size distribution and organic content of dredged sewage sediments. Based on this, it was determined that particles with relatively low organic content of 1.0 mm or more could be recycled as fine aggregate. Although it was inorganic at the size of 5 mm or more, it contained a number of foreign substances other than fine aggregate, which were needed to be removed with a sieve. Since there are volatile suspended solids between 1.0 and 5.0 mm size, they were removed by means of flotation. Fine aggregate was obtained from dredging soil by screening followed with flotation method, and the proportion of fine aggregate obtained in this study was around 38 %.

• KSBB Journal
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• v.19 no.3
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• pp.169-173
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• 2004

The Rhodiola Sachalinensis 5 g were mixed and extracted with methanol 150 $m\ell$ at the room temperature for 12 h. The effluents were collected and grouped into the two. Un this experimental condition, the mobile phase composition were linearly changed as follows; water/methanol : 90/10 - 30/70 (vol. %, for 5 min), 30/70 - 10/90 (vol. %, for 15 min) and an analytical column (3.9 ${\times}$ 25 em, 15 $\mu\textrm{m}$ particle size, and 300 ${\AA}$ pore size) was utilized. The performance of the extracted Rhodiola Sachalinensis as a whitening agent was not favorable, so it classifies the Rhodiola Sachalinensis extractions with two fractions and collects each fraction for whitening agent assay. For the in-vivo melanin production ratio assay that used melanin-a cell in 10 ppm concentration, it was 58.6%, the first fraction of the effluents collected between 1.0 and 4.0 min, while it was 60％ between 10.4 and 17.6 min for the second fraction, which were more efficient than that of arbutin, 45.6%.

• Journal of the Society of Naval Architects of Korea
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• v.44 no.3 s.153
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• pp.267-278
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• 2007

This experimental study investigated on the eddy making effect on the roll motion of a rectangular barge in a two-dimensional wave tank. The structure was used to simulate a simplified rectangular barge in the beam sea condition. The structure with a draft one half of its height was hinged at the center of gravity and free to roll by waves. The rectangular barge was tested with regular waves with a range of wave periods that are shorter, equal to, and longer than its roll natural period. Particle image velocimetry (PIV) was employed to obtain the velocity field in the vicinity of the structure. The coupled interactions between the incident wave and the barge were demonstrated by examining the vortical flow fields to elucidate the eddy making effect during the roll motion. For incoming wave with a wave period same as the roll natural period, the barge roll motion was reduced by the eddy making damping effect. At the wave period shorter than the roll natural period, the structure roll motion was slightly reduced by the vertical flow around the barge. However, at the wave period longer than the roll natural period, the eddy making effect due to flow separation at structure corners indeed amplifies the roll motion. This indicates that not only can the eddy making effect damp out the roll motion, it can also increase the roll motion.

• Bulletin of the Korean Chemical Society
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• v.34 no.11
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• pp.3444-3450
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• 2013

Three phase hollow fiber-liquid phase microextraction (HF-LPME), which is faster, simpler and uses a more environmentally friendly sample-preparation technique, was developed for the analysis of Non-Steroidal Anti-Inflammatory Drugs (NSAIDs) in human urine. For the effective simultaneous extraction/concentration of NSAIDs by three phase HF-LPME, parameters (such as extraction organic solvent, pH of donor/acceptor phase, stirring speed, salting-out effect, sample temperature, and extraction time) which influence the extraction efficiency were optimized. NSAIDs were extracted and concentrated from 4 mL of aqueous solution at pH 3 (donor phase) into dihexyl ether immobilized in the wall pores of a porous hollow fiber, and then extracted into the acceptor phase at pH 13 located in the lumen of the hollow fiber. After the extraction, 5 ${\mu}L$ of the acceptor phase was directly injected into the HPLC/UV system. Simultaneous chromatographic separation of seven NSAIDs was achieved on an Eclipse XDB-C18 (4.6 mm i.d. ${\times}$ 150 mm length, 5 ${\mu}m$ particle size) column using isocratic elution with 0.1% formic acid and methanol (30:70) at a HPLC-UV/Vis system. Under optimized conditions (extraction solvent, dihexyl ether; $pH_{donor}$, 3; $pH_{acceptor}$, 13; stirring speed, 1500 rpm; NaCl salt, 10%; sample temperature, $60^{\circ}C$; and extraction time, 45 min), enrichment factors (EF) were between 59 and 260. The limit of detection (LOD) and limit of quantitation (LOQ) in the spiked urine matrix were in the concentration range of 5-15 ng/mL and 15-45 ng/mL, respectively. The relative recovery and precision obtained were between 58 and 136% and below 15.7% RSD, respectively. The calibration curve was linear within the range of 0.015-0.96 ng/mL with the square of the correlation coefficient being more than 0.997. The established method can be used to analyse of NSAIDs of low concentration (ng/mL) in urine.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.494-500
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• 2014

Indium-doped zinc oxide nanocrystals (IZO NCs), capped with stearic acid (SA) of different sizes, were synthesized using a hot injection method in a noncoordinating solvent 1-octadecene (ODE). The ligand exchange process was employed to modify the surface of IZO NCs by replacing the longer-chain ligand of stearic acid with the shorter-chain ligand of butylamine (BA). It should be noted that the ligand-exchange percentage was observed to be 75%. The change of particle size, morphology, and crystal structures were obtained using a field emission scanning electron microscope (FE-SEM) and X-ray diffraction pattern results. In our study, the 5 nm and 10 nm IZO NCs capped with stearic acid (SA-IZO) were ligand-exchanged with butylamine (BA), and were then spin-coated on a thermal oxide ($SiO_2$) gate insulator to fabricate a thin film transistor (TFT) device. The films were then annealed at various temperatures: $350^{\circ}C$, $400^{\circ}C$, $500^{\circ}C$, and $600^{\circ}C$. All samples showed semiconducting behavior and exhibited n-channel TFT. Curing temperature dependent on mobility was observed. Interestingly, mobility decreases with the increasing size of NCs from 5 to 10 nm. Miller-Abrahams hopping formalism was employed to explain the hopping mechanism insight our IZO NC films. By focusing on the effect of size, different curing temperatures, electron coupling, tunneling rate, and inter-NC separation, we found that the decrease in electron mobility for larger NCs was due to smaller electronic coupling.