• Title/Summary/Keyword: Particle electrode

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A Study on Electrode Preparation for Alkaline Fuel Cell (알칼리 연료전지 전극제조에 관한 연구)

  • Hong, Jin Ki;Lee, Kyung Ju;Lee, Wha Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.2 no.1
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    • pp.57-67
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    • 1990
  • This study is proposed to investigate the effect of electrode preparation method for Alkaline Fuel Cell using NaOH as an electrolyte on the Fuel Cell performance. The materials used for the preparation of electrode are Pt and Ag on Vulcan XC-72. Surface area of Vulcan XC-72 have different values according to the pretreatment conditions and the dispersion of Pt is dependent on the impregnation Particle size of Pt impregnated on unpretreated carbon was observed to be $20{\sim}40{\AA}$ and that on pretreated carbon in $N_2$ stream at $950^{\circ}C$ was found to be finely dispersed less then $15{\AA}$. The electrode performance was affected by the particle size of metals and operating temperature. It was revealed from this study that the optimum particle size about $30{\AA}$ and optimum temperature range is between $90{\sim}100^{\circ}C$.

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Characterization of Photoelectron Behavior of Working Electrodes with the Titanium Dioxide Window Layer in Dye-sensitized Solar Cells

  • Gong, Jaeseok;Choi, Yoonsoo;Lim, Yeongjin;Choi, Hyonkwang;Jeon, Minhyon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.346.1-346.1
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    • 2014
  • Porous nano crystalline $TiO_2$ is currently used as a working electrode in a dye-sensitized solar cell (DSSC). The conventional working electrode is comprised of absorption layer (particle size:~20 nm) and scattering layer (particle size:~300 nm). We inserted window layer with 10 nm particle size in order to increase transmittance and specific surface area of $TiO_2$. The electrochemical impedance spectroscope analysis was conducted to analysis characterization of the electronic behavior. The Bode phase plot and Nyquist plot were interpreted to confirm the internal resistance caused by the insertion of window layer and carrier lifetime. The photocurrent that occurred in working electrode, which is caused by rise in specific surface area, increased. Accordingly, it was found that insertion of window layer in the working electrode lead to not only effectively transmitting the light, but also increasing of specific surface area. Therefore, it was concluded that insertion of window layer contributes to high conversion efficiency of DSSCs.

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Treatment of ETA wastewater using GAC as particle electrodes in three-dimensional electrode reactor (활성탄 충진 3D 복극전기분해조를 이용한 ETA 처리)

  • Kim, Ran;Kim, Yu-Jin;Shin, Ja-Won;Kim, Jeong-Joo;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.2
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    • pp.241-249
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    • 2013
  • Ethanolamine (ETA) is widely used for alkalinization of water in steam cycles of nuclear power plants with pressurized water reactor. When ETA contained wastewater was released, it could increase COD and T-N. The treatment of the COD and T-N from ETA wastewater was investigated using the GAC as particle electrodes in three-dimensional electrode reactor (TDE). This study evaluated the effectiveness of GAC as particle electrode using different packing ratio at 300 V. The results showed that GAC-TDE could reduce ETA much more efficiently than ZVI-TDE at the mass ratio of GAC to insulator, 1:2. Additionally, The effect of applied electric potential to COD and T-N reduction was investigated. The results showed the high COD, T-N reduction and current efficiency at the low electric potential. Using the GAC-TDE will provide a better ETA reduction with reducing electrical potential dissipation.

The Particle-Initiated Breakdown Characteristics on the Spacer Surface for $SF_6$GIS ($SF_6$GIS용 스페이서 표면 파티클에 의한 절연파괴 특성)

  • 김정달;이세훈
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.12 no.1
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    • pp.3-11
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    • 1998
  • The influence due to particle contaminated on spacer surface is remarkable in the decreasing of dielectric strength in SF6 GIS. In relation with this problem, We studied, AC flash-over voltage characteristics and breakdown mechanism are investigated under metallic and insulating particle initiated condition in SF6 gas by varying the particle position, particle shape with a plane-plane electrode. The main results are as follows $\circled1$ Influence of the flash-over voltage decrease for particle position is lowest in mid gap and is highest in separated small gap on electrode. $\circled2$ The metallic particle shape which results in the more reduced flash-over voltage, the FOV saturation moved in to the region of low pressure. $\circled3$Insulating particle less than 0.6[mm] are not almost influenced by the flash-over Voltage.oltage.

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Electrochemical Characteristics of the Oxygen Electrode for Alkaline Fuel Cells -Impregnation of Silver Catalyst on Carbon Black with Colloidal Method- (알칼리형 연료전지용 산소극의 전기화학적 특성고찰 -콜로이드 방법에 의한 카본블랙상 은촉매담지-)

  • Lee, Hong-Ki;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.701-709
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    • 1992
  • Silver particles were impregnated on carbon black with colloidal method and used as catalyst for oxygen electrode in alkaline fuel cell. With the addition of sodium dodecylbenzenesulfonate in $AgNO_3$ and $NaBH_4$solution, colloidal solution was made and confirmed with electrophoresis test. Effects of particle size on electrode performance were studied and $200{\AA}$ of silver particle size shown the highest value of mass activity. The aggromeration of silver particle was Influenced with surfactant amount, stirring time and heat treatment. Considering the increase of particle size caused of operating temperature, recommendable particle size of silver catalyst for manufacturing the electrode was $100{\AA}$. Dispersity of carbon black was investigated and reagglomeration was appeared after homogenizing 30 sec.

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Effects of Tungsten Particle Size and Nickel Addition in DC arc Resistance of Cu-W Electrode

  • Kim, Bong-Seo;Jeong, Hyun-Uk;Lee, Hee-Woong
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.2
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    • pp.68-72
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    • 2004
  • The performance of copper-tungsten for electrodes used in an ultra high voltage interruption system was evaluated by means of an interruption test, which requires a large-scale apparatus and high cost. In this study, prior to the interruption test, the characteristics of a Cu-W electrode were estimated through the DC arc test, which is a simple, low cost procedure. The DC arc characteristics of a 20wt%Cu-80wt%W electrode were investigated with the change of tungsten powder size distribution and the addition of nickel. In specimens containing a high volume fraction of large sized tungsten particles, the relative density and hardness of sintered Cu-W electrodes increased while the electrical conductivity and the DC arc resistance decreased. Furthermore, the relative density became enhanced with the increase of the amount of nickel while the hardness and electrical conductivity diminished and the DC arc resistance worsened.

A Numerica analysis on the lift-off motion of Free Conducting Particle in GIS (GIS내에 함유된 자유 도전성 파티클의 거동해석)

  • Lee, Bang-Wook;Koo, Ja-Yoon
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1925-1928
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    • 1996
  • In this work, the behavior of conducting wire type particles existing inside the cylinder type coaxial electrode has been systematically investigated by charge simulation method and electrostatic force analysis from the view point of the acquired charging before being lifted off into the gap under the high ac voltage. Spheroidal charge are adopted as a image charge for the CSM analysis in order to calculate the acquired charges of the particles which are erected on the surface of the outer electrode. For this purpose, different material of the particle and their lengths and diameters have been considered in view to calculate their lift-off field, acquired charge and to understand their effect on the lift-off voltage. The results imply that the particle lengths and diameter have an different influence on the particle behavior in GIS system.

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Experimental Study on the Discharge Electrode of A Two-Stage Electrostatic Air Cleaner (2단 평행판 전기집진기의 방전부 특성 실험)

  • Kim, I.S.;Lee, J.O.;Kim, Y.J.;Choi, H.O.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.1
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    • pp.27-34
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    • 1993
  • The two-stage electrostatic air cleaner is a particle control device that uses electrical forces to move particles in the flowing gas stream onto collector plates. Despite a general understanding of electrostatic air cleaner operation and their successful use in industry, many questions regarding flow, electric fields and particle collection have remained unanswered. In this paper, an experimental investigation for designing the discharge electrode, including ionizer wire diameter, plate length and wire-to-plate spacing, is carried out. The electrical conditions, namely the electric field intensity, the space current and the particle charge intensity, in wire-plate electrostatic air cleaner are reported and examined.

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Thermal Stability of Lithiated Silicon Anodes with Electrolyte

  • Park, Yoon-Soo;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.145-148
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    • 2011
  • The thermal behavior of lithiated Si anodes has been investigated using differential scanning calorimetry (DSC). In particular, the effect of Si particle size on the thermal stability of a fully lithiated Si electrode was investigated. For DSC measurements, a lithiated Si anode was heated in a hermetically sealed high-pressure pan with a polyvinylidene fluoride (PVDF) binder and a 1 M $LiPF_6$ solution in an ethylene carbonate (EC)-diethyl carbonate (DEC) mixture. The thermal evolution around $140^{\circ}C$ increases with lithiation and with decreasing particle size; this phenomenon is attributed to the thermal decomposition of the solid electrolyte interface (SEI) film. Exothermic peaks, following a broad peak at around $140^{\circ}C$, shift to a lower temperature with a decrease in particle size, indicating that the thermal stability of the lithiated Si electrode strongly depends on the Si particle size.

Fabrication and Driving of Charged particle type display (대전입자형 디스플레이의 제조 및 구동)

  • Lee, Dong-Jin;Kim, Sung-Woon;Hwang, In-Sung;Kim, Chul-Ju;Kim, Young-Cho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.72-73
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    • 2007
  • The charged particle have characteristics of high-contrast ratio and wide-view angle, quick-response time. When positive voltage is applied to the upper electrode, the yellow particles with negative charge move toward the upper substrate and the black particles with positive charge move toward opposite direction. We have developed the putting method that can fill particles in cell of panel and control the amount of charged particles. We investigated putting method, fabrication process, aging and driving for charged particle type display.

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