• Clean Technology
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• v.13 no.3
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• pp.208-214
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• 2007

Environmentally-friendly acrylic resin particles having the diameter between $0.1\;and\;1\;{\mu}m$ were prepared using non-aqueous dispersion (NAD) polymerization technique. The first step is to prepare the stabilizer and the next step is the NAD polymerization by dropping an acrylic monomer to stabilizer dispersed in organic media. To obtain a NAD resin with proper level of viscosity, it fumed out that stabilizers having sufficient viscosity such as 1000 cP need to be used, for which the stepwise feeding of monomer and initiator was necessary. It was necessary to put proper amount of stabilizer, but no more increase in viscosity was observed when more than that amount of stabilizer was added. Choice of proper monomers considering solubility parameter was essential to avoid the bimodal particle size distribution in the NAD resin product.

• Environmental Analysis Health and Toxicology
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• v.13 no.1_2
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• pp.43-53
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• 1998

Ambient air levels of polycyclic aromatic hydrocarbons(PAHs) are of concern because of their potential for adverse health effects including transformation of some of these substances to mutagens and carcinogens by mammalian microsomal enzyme system. Airbone particulate samples were collected by a conventional high-volume sampler and by an Anderson cascade impactor on 2 to 3 days in each month over a period of 1 year at a representative site of the heavy traffic area of Seoul from beptember 1994 to August 1995. Ten individual PAHs in sizable air particulates of each stage of two months were separated and analyzed by gas chromatography/mass spectrometry. As a results of analysis, the gross concentrations of PAHs in the fine and coarse particles were higher in the winter month than in the spring, followed in descending order by in the fall and summer. In a study of dependency of 10 PAHs compounds on size distribution of particles at heavy traffic area found that about 85% of the total PAHs content was associated with particles less than 2.0um (fine particles) in diameter of winter sampling period. while 79% were associated with this size fraction during summer period. In according to the mean concentrations of the 10 PAHs in 7 size classification from < 0.38 to> 10.1, the 'size was the smaller, PAHs concentration was the higher. Thus it was found that PAHs concentration was greatly affected by air particle size. Annual mean benzo(a)pyrene equivalents was 5.88ng/m$^3$ and obtained by applying, toxic equivalency factor developed by Nisbet and Lagoy.

• Progress in Superconductivity and Cryogenics
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• v.16 no.1
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• pp.36-41
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• 2014

Since glass microsphere has high crush strength, low density and small particle size, it becomes alternative thermal insulation material for cryogenic systems, such as storage and transportation tank for cryogenic fluids. Although many experiments have been performed to verify the effective thermal conductivity of microsphere, prediction by calculation is still inaccurate due to the complicated geometries, including wide range of powder diameter distribution and different pore sizes. The accurate effective thermal conductivity model for microsphere is discussed in this paper. There are four mechanisms which contribute to the heat transfer of the evacuated powder: gaseous conduction ($k_g$), solid conduction ($k_s$), radiation ($k_r$) and thermal contact ($k_c$). Among these components, $k_g$ and $k_s$ were calculated by Zehner and Schlunder model (1970). Other component values for $k_c$ and $k_r$, which were obtained from experimental data under high vacuum conditions were added. In this research paper, the geometry of microsphere was simplified as a homogeneous solid sphere. The calculation results were compared with previous experimental data by R. Wawryk (1988), H. S. Kim (2010) and the experiment of this paper to show good agreement within error of 46%, 4.6% and 17 % for each result.

• Journal of the Korean Chemical Society
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• v.55 no.1
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• pp.92-97
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• 2011

The effect of Group I alkali acetate promoters on vinyl acetate (VA) synthesis was evaluated. Catalyst product selectivity and ethylene conversion are compared to the unpromoted catalyst in the fixed-bed reactor with oxidation reaction of ethylene and acetic acid in gaseous phase over Pd-Au/$SiO_2$ catalyst. It was found that: a) the promoters were stabilized on the catalyst surface, b) common effect for the alkali promoted Pd-Au catalysts increaseed in product selectivity and ethylene conversion compared to unpromoted catalyst (these effects increase from top to the bottom of Group I). These promoting effect is due to the common-ion effect of acetate, present in the reaction, resulting in an increase in the activity of the catalyst. In addition a complementary theory for the effect of Au in the structure of the catalyst is proposed the imposition of distribution of palladium particles through decreasing the particle's diameter.

• Elastomers and Composites
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• v.47 no.4
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• pp.318-328
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• 2012

In this study, the one-component curable polyurethane resin was manufactured using blocked isocyanate and hybrid technology. To prepare the one-component curable hybrid polyurethane, silica hybrids including hydroxyl group was synthesized, and the size, shape and distribution of hybrid particle in polyurethane resin were confirmed. Then the dissociation property, mechanical property and molding property of blocked isocyanate were investigated. The dissociation property of blocked isocyanate in one-component curable polyurethane became better as the heating temperature and treatment time increased. The synthesized silica hybrid had spherical appearance and size of 23~27 nm in diameter, and it was observed that the hybrid particles were homogeneously distributed in polyurethane structure. In the case of hybrid polyurethane, the mechanical property, anti-abrasion and thermal property were higher than those of general polyurethane, and it was observed that the mechanical property was maintained when the plasticizer was introduced.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.4
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• pp.426-435
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• 2011

In this study, PM emission factors for commercial meat cooking were developed by the experiment using the similar restaurant model. The commercial material types of meat cooking were beef, pork and duck. And meat cooking materials were classified with marinated and raw cooking methods. The marinated and raw cooking methods were flat griddle (LPG) and under fired charbroiling grill. As a results, $PM_{10}$ emission factors for underfired pork cooking was estimated as 7.39 g/kg-meat which was the highest value in this study. The emission factors of under fired charbroiling grill method were higher than that of flat griddle method regardless of meat cooking material types and marinated meat. The particle size distribution of meat cooking was 0.23~5 ${\mu}m$ and median diameter was 2~2.5 ${\mu}m$.

• Journal of Navigation and Port Research
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• v.32 no.6
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• pp.453-458
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• 2008

Flow characteristics of the control-rod-attached 2-dimensional circular cylinder was accomplished using by PIV techniques. model tests had been carried out with different diameters of control rods(d/D=0.1 through d/D=0.5). and the Reynolds number Re=15,000 based on the cylinder diameter(D=50mm) to predict the performance of the model and the two-frame grey-level cross-correlation method had been used to obtain the velocity distribution in the flow field. 50mm circular cylinder had been used during the whole experiments and measured results had been compared with each other. The measured results have been compared with each case. therefore this article identifies not only the mean velocity profiles but also the control effects of the control rods.

• Journal of the Korean Applied Science and Technology
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• v.35 no.4
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• pp.1393-1406
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• 2018

In this study, three parameters (Pressure ($X_1$), Airflow rate ($X_2$), Operation time ($X_3$)) were experimentally designed and the predicted model and optimal conditions were established by using the terminal rise velocity of the microbubbles as the response value. The polynomial regression analysis showed that the optimum value for the terminal rise velocity at the Pressure ($X_1$) of 4.5 bar, Airflow rate ($X_2$) of 3.3 L/min and Operation time ($X_3$) of 2.2 min was 5.14 cm/min ($85.7{\mu}m/sec$). Also, the highest microbubble diameter size distribution in the range of 2 to $5{\mu}m$ and 25 to $50{\mu}m$ was confirmed by using a laser particle counting apparatus.

• Journal of the Semiconductor & Display Technology
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• v.21 no.4
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• pp.33-38
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• 2022

With an attempt to suppress the moiré phenomenon caused by the interference between the black matrix of a display panel and the metal grid of a camera, we have fabricated an anti-moiré filter using light diffusing particles (LDPs) with the average diameter of 20 ㎛. It is demonstrated that the anti-moiré filter coated on a glass substrate (370 mm × 470 mm) using a table slot-die coater reduces the moiré intensity to a great extent when the area covered by LDPs is 50%. To quantify the intensity of moiré phenomenon, we have measured the lightness ratio and found that it is reduced from 132.12 down to 105.71 by the filter. To find the optimum area covered by LDPs, we have performed ray tracing simulations using Mie scatters as a substitute for LDPs. From the simulated irradiation distribution, we have calculated the standard deviation (SD) and contrast ratio (CR) to evaluate the moiré strength. As expected, the SD and CR values decrease with increasing covered area by LDPs. However, there exists a trade-off between the transmittance of the filter and its capability of reducing the moiré intensity in determining the area covered by LDPs.

• Journal of Korea Water Resources Association
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• v.45 no.2
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• pp.151-163
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• 2012

The distribution of gravel-bed materials in mountainous river is formed by the process of deposition and transportation of sediment responding to stream power of the latest flood that is over the certain scale. The particle size of bed material was surveyed in the longitudinal points of river and detail points of a specific meandering section and used to estimate the critical velocity and stream power. Yang's critical unit stream power and Bagnold's critical stream power for gravel-bed materials increased with the distance from downstream to upstream. Dimensionless shear stress based on the designed flood discharge in Shields diagram was evaluated that the gravel-bed materials in most survey points may be transported as form of bedload. The mean diameter in the meandering section was the biggest size in first water impingement point of inflow water from upstream and the second big size in second water impingement point by reflection flow. The mean diameters were relatively the small sizes in points right after water impingement. The range of mean critical velocity was 0.77~2.60 m/s and critical unit stream power was big greatly in first water impingement point. The distribution of critical stream power, range of 7~171 $W/m^2$, was shown that variation in longitudinal section was more obvious than that of cross section and estimated that critical stream power may be affected greatly in first and second water impingement point.