• Title/Summary/Keyword: Particle coating

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Nitrogen Release and Polymer Degradation Properties of Polymer-Coated Urea Fertilizer in Soil (고분자 피복요소비료의 질소용출 및 토양중 분해특성)

  • Kang, Byung-Hwa;Ha, Byoung-Yeun;Park, Ki-Do;Park, Moon-Su;Sohn, Bo-Kyoon;Jeong, Yeun-Kyu;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.5
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    • pp.264-271
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    • 2002
  • Nitrogen releasing characteristics of polymer-coated urea(PCU) that made acrylic synthetic resins were studied in incubated soil, water and paddy soil. Also, their correlations and degradation patterns of coating material were tested. Releasing rate of nitrogen from PCU decreased with increasing coating rate. N001(coating rate 8.5%) and N003(coasting rater 6.3%) were low releasing amount at the early stage, whereas N005(coating rate 4.8%) was released over 80% within 20 days. Relationship of the releasing rate between incubated soil($25^{\circ}C$) and paddy soil could be described as follows : $Y=-0.0011X^2+2.2931X-50.264(R^2=0.9884)$ for N001, $Y=-0.0016X^2+1.1587X+5.5064(R^2=0.9805)$ for N003 and $Y=-0.03X^2+6.499X-243.22(R^2=0.9422)$ for N005, respectively (Y: release rate at field condition, X: experiment period). Relationship of the releasing rate between incubated water($30^{\circ}C$) and paddy soil can be described as follows : $Y=0.0011X^2+2.2601X-25.329(R^2=0.9884)$ for N001, $Y=-0.0306X^2+4.4994X-76.307(R^2=0.955)$ for N003 and $Y=-0.0164X^2+3.7764X-108.22(R^2=0.9422)$ for N005. After 150 days, coating materials of N001, N003, and N005 in incubated soil were degraded approximately 23%, 22% and 15%, respectively. Also The scanning electron microscope examination of coating material revealed that particle surface became gradually shattered with the time after the soil treatment.

Micromorphological Characteristics of Soil with Different Patent Materials (모재별 토양의 미세형태 특성)

  • Zhang, Yong-Seon;Jung, Seog-Jae;Kim, Sun-Kwan;Park, Chang-Jin;Jung, Yeon-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.5
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    • pp.293-303
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    • 2004
  • This experiment was conducted to investigate the direction or orientation of clay particle movement in argillic horizons (Bt) for clarifying the soil classification of soils. Soil samples were collected from 22 soil series containing Bt horizons. Physical and chemical characteristics and mineral and chemical compositions of clay in the soils were analyzed. Micoromorphological characteristics of the Bt horizons were also investigated with thin sections of the natural undisturbed and oriented soil samples. Average clay content in the Bt horizons was 28% and 1.33 times higher comparing to that in the surface layer. Soil pH was higher, but cation exchange capacity (CEC) and organic matter content were lower in Bt horizon than those in the surface layer. There was an evidence of clay accumulation in Bt horizons of all soil series examined except Bangog series. Although there was an increase of clay content in the horizons in Bangog series, the clay was not originated from illuviation process. The translocation of clay was in the order of an 2:1 expandable clay minerals > 2:1 non-expandable clay minerals > 1:1 clay minerals. The illuvial substances in argillic horizon were composed with clay, amorphous iron and opaque mineral. The micoromorphological features of Bt horizon were void coating, channel infilling and grain coating. There was an apparent boundary between clay coating and the groundmass in residuum and colluvium, but Bt horizon of alluvium was composed of a skew plane amputated by the physical operation.

Gas Sensing Behaviors of SnO2:Cu Nanostructures for CH4, CH3CH2CH3 Gas (SnO2:Cu 나노 구조물의 CH4, CH3CH2CH3 가스 감응 특성)

  • Lee, Ji-Young;Yu, Yoon-Sic;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.12
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    • pp.974-978
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    • 2012
  • The effect of Cu coating on the sensing properties of nano $SnO_2:Cu$ based sensors for the $CH_4$, $CH_3CH_2CH_3$ gas was studied. This work was focussed on investigating the change of sensitivity of nano $SnO_2:Cu$ based sensors for $CH_4$, $CH_3CH_2CH_3$ gas by Cu coating. Nano sized $SnO_2$ powders were prepared by solution reduction method using stannous chloride($SnCl_2{\cdot}2H_2O$), hydrazine($N_2H_2$) and NaOH and subsequent heat treatment. XRD patterns showed that nano $SnO_2$ powders with rutile structure were grown with (110), (101), (211) dominant peak. The particle size of nano $SnO_2:Cu$ powders at 8 wt% Cu was about 50 nm. $SnO_2$ particles were found to contain many pores, according to SEM analysis. The sensitivity of nano $SnO_2:Cu$ based sensors was measured for 5 ppm $CH_4$ gas and $CH_3CH_2CH_3$ gas at room temperature by comparing the resistance in air with that in target gases. The sensitivity for both $CH_4$ and $CH_3CH_2CH_3$ gases was improved by Cu coating on the nano $SnO_2$ surface. The response time and recovery time of the $SnO_2:Cu$ gas sensors for the $CH_4$ and $CH_3CH_2CH_3$ gases were 18~20 seconds, and 13~15 seconds, respectively.

An Innovative Solution for the Power Quality Problems in Induction Motor by Using Silica and Alumina Nano Fillers Mixed Enamel for the Coatings of the Windings

  • Mohanadasse, K.;Sharmeela, C.;Selvaraj, D. Edison
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1621-1625
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    • 2015
  • Power quality has always been a concern of power engineers. Certainly an argument can be successfully made that most parts of power engineering have the ultimate objective to improve power quality. AC motors were widely used in industrial and domestic applications. Generally, AC motors were of two types: Induction and Synchronous motors. In motor many parameters like different load cycling, switching, working in hot weather and unbalances creates harmonics which creates major reasons for temperature rise of the motors. Due to high peak value of voltage, harmonics can weaken insulation in cables, windings and capacitors and different electronic components. Higher value of harmonics increase the motor current and decrease the power factor which will reduce the life time of the motor and increase the overall rating of all electrical equipments. Harmonics reduction of all the motors in India will save more power. Coating of windings of the motor with nano fillers will reduce the amount of harmonics in the motor. Based on the previous project works, actions were taken to use the enamel filled with various nano fillers for the coating of the windings of the different AC motors. Ball mill method was used to convert the micro particles of Al2O3, SiO2, TiO2, ZrO2 and ZnO into nano particles. SEM, TEM and XRD were used to augment the particle size of the powder. The synthesized nano powders were mixed with the enamel by using ultrasonic vibrator. Then the enamel mixed with the nano fillers was coated to the windings of the several AC motors. Harmonics were measured in terms of various indices like THD, VHD, CHD and DIN by using Harmonic analyzer. There are many other measures and indices to describe power quality, but none is applicable in all cases and in many instances, these indices may hide more than they show. Sometimes power quality indices were used as a basis of comparison and standardization. The efficiency of the motors was increased by 5 – 10 %. The thermal withstanding capacity of the motor was increased by 5º to 15º C. The harmonics of the motors were reduced by 10 – 50%.

Properties of Blocking Layer with Ag Nano Powder in a Dye Sensitized Solar Cell

  • Noh, Yunyoung;Kim, Kwangbae;Choi, Minkyoung;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.105-109
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    • 2016
  • We prepared a working electrode (WE) with a blocking layer (BL) containing 0 ~ 0.5 wt% Ag nano powders to improve the energy conversion efficiency (ECE) of dye sensitized solar cell (DSSC). FESEM and micro-Raman were used to characterize the microstructure and phase. UV-VIS-NIR spectroscopy was employed to determine the adsorption of the WE with Ag nano powders. A solar simulator and a potentiostat were used to confirm the photovoltaic properties of the DSSC with Ag nano powders. From the results of the microstructural analysis, we confirmed that Ag nano powders with particle size of less than 150 nm were dispersed uniformly on the BL. Based on the phase and adsorption analysis, we identified the existence of Ag and found that the adsorption increased when the amount of Ag increased. The photovoltaic results show that the ECE became 4.80% with 0.3 wt%-Ag addition compared to 4.31% without Ag addition. This improvement was due to the increase of the localized surface plasmon resonance (LSPR) of the BL resulting from the addition of Ag. Our results imply that we might be able to improve the efficiency of a DSSC by proper addition of Ag nano powder to the BL.

Characterization and Microstructure of an Extruded Flat-Tubular-Type Alumina Filter (압출공정에 의한 수 처리용 평관형알루미나 필터의 미세구조와 특성평가)

  • Bae, Byung-Seo;Ha, Jang-Hoon;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.406-412
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    • 2014
  • In this study, flat-tubular-type alumina filters were manufactured using alumina powder of two sizes ($2.4{\mu}m$ ALM-44 and $0.4{\mu}m$ AP 400) by an extrusion process. The manufactured alumina filter was sintered at $1200-1600^{\circ}C$ for 1 h. As particle size increased, the largest pore size, average pore size and porosity increased; but density and linear shrinkage decreased. The alumina filter fabricated using ALM-44 powder sintered at $1500^{\circ}C$ was confirmed as the best water treatment filter after investigation of the bending strength, water permeability and impurity-removal efficiency of the experimental filters. This flat-tubular-type alumina filter is expected to be useful not only for direct water treatment, but also for use as a support filter during coating processes, to control pore size.

Charge-Discharge Characteristics of Physically Coated Lithium Anodes by Carbon Powders (탄소분말이 물리적으로 코팅된 리튬 음전극의 충방전 특성)

  • Kim, Kwang Man;Lee, Sang Hyo;Lee, Young-Gi
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.554-559
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    • 2011
  • To improve the safety and electrode characteristics of lithium metal anode, physically coated electrodes on lithium metal surface by three kinds of carbon are prepared and their charge-discharge performances are investigated by adopting the C-Li electrodes as the anode of rechargeable lithium batteries. The lithium anode coated by the carbon powder with smaller particle size and higher surface area, which has higher packing density and lower surface roughness, shows better performance in charge-discharge characteristics. The carbon coating on lithium surface can be more effective in small-sized cells.

Development of X-ray Image Processing Technology for Nondestructive Measurement of the Coating Thickness in the Simulated TRISO-coated Fuel Particle (모의 TRISO 핵연료입자 코팅층 두께 비파괴 측정을 위한 X-선 영상처리기술 개발)

  • Kim Woong-Ki;Lee Young-Woo;Park Ji-Yeon;Ra Sung-Woong
    • Proceedings of the Korea Information Processing Society Conference
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    • 2006.05a
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    • pp.669-672
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    • 2006
  • 고온가스냉각 원자로에서는 고온 안정성 및 핵분열생성물 차단 성능이 우수한 TRISO(tri-tsotropic) 핵연료를 사용하고 있다. TRISO 핵연료 입자는 직경이 약 1 mm인 구 형태로 입자의 중심에는 직경 $0.5{\mu}m$의 핵연료 커널(kernel)이 포함되며 커널 외곽을 코팅 층이 에워싸고 있다. 이 코팅 층은 완충(buffer) PyC(pyrolytic carbon) 층, 내부 PyC 층, SiC 층, 그리고 외부 PyC 층으로 구성되어 있다. 각 코팅 층의 두께는 수십${\sim}$${\mu}m$ 범위이며, 본 연구에서는 각 코팅 층의 두께를 비파괴적으로 측정하기 위하여 마이크로포커스 X-선 발생장치와 고해상도 X-선 평판(flat panel) 검출기로 구성된 정밀한 X-선 래디오그래피 장치를 구성하고, $UO_2$ 핵물질 대신에 $ZrO_2$를 커널로 사용한 모의 TRISO 핵연료 입자에 대한 래디오그래피 영상을 획득한 후 디지털 영상처리기술을 이용하여 코팅 층 사이의 경계선이 구분 가능하도록 영상을 개선하고 디지털 영상처리 알고리즘을 개발하여 코팅 층의 두께를 측정하였다.

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DYE SENSITIZED SOLAR CELLS WITH HIGH PHOTO-ENERGY CONVERSION -CONTROLL OF NANO-PARTICLE SURFACES-

  • Hayase, Shuzi
    • Proceedings of the KIEE Conference
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    • 2006.04b
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    • pp.52-56
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    • 2006
  • Some of factors affecting photo-conversion efficiency of dye sensitized solar cells (DSCs) are discussed in terms of $TiO_2$ electrodes. The first topic is on the surface modification of $TiO_2$ nano-particles, which is associated with electron traps on the surface of $TiO_2$ nano-particles. The surface is modified with dye molecules under pressurized $CO_2$ atmosphere to increase the surface coverage of $TiO_2$ nano-particles with dye molecules. This increases Jsc because of an increase in the amount of dye molecules and a decrease in the amount of trapping sites on $TiO_2$ nano-particles. In addition, the decrease in the amount of trap sites increases Voc because decreases in Voc are brought about by the recombination of $I_2$ molecules with electrons trapped on the $TiO_2$ surfaces. Selective staining for tandem cells is proposed. The second topic is on the contact between a $SnO_2$/F transparent conductive layer (TCL) and nano-particles. Polishing the TCL surfaces with silica nano-particles increases the contact, resulting in Jsc increases. The third topic is the fabrication of ion-paths in $TiO_2$ layers. Electro-spray coating of $TiO_2$ nano-particles onto TCL is shown to be effective for fabricating ion-paths in $TiO_2$ layers, which increases Jsc.

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Release proporties of ovalbumin from alginate microspheres prepared using the nozzle in spray dryer system

  • Park, Jeong-Eun;Lee, Chang-Moon;Park, Hee-Jung;Kim, Gwang-Yun;Rhee, Joon-Haeng;Lee, Ki-Young
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.570-573
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    • 2005
  • The spray method was chiefly used to prepare alginate microspheres. Additionally due to formation at mild conditions, the alginate microspheres were coated with chitosan. The particle size of alginate microspheres increased when the sodium alginate increased. Release pattern of OVA in alginate microspheres was evaluated at PBS buffer(pH 7.4) and HCl buffer(pH 1.2). Release rate of OVA from chitosan/alginate microsphere was also lower than that with the concentration of alginate in the microspheres, the amount of OVA released from alginate microspheres increased from alginate micorsphere. Therefore, the alginate microspheres can be prepared by spray rozzle for a protein drug delivery. OVA release from the alginate microspheres was controlled by a coating with chitosan.

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