• 제목/요약/키워드: Particle assembly

검색결과 134건 처리시간 0.04초

콜로이드법을 이용한 고분자전해질 연료전지용 백금전극 촉매의 제조 (Synthesis of Electrode Catalyst for Polymer Electrolyte Membrane Fuel Cells Using Colloidal Method)

  • 박진남
    • 청정기술
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    • 제19권1호
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    • pp.59-64
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    • 2013
  • 고분자전해질 연료전지에서 사용되는 전도성 카본에 백금이 담지된 전극촉매를 콜로이드법을 이용하여 합성하였다. 콜로이드법 합성을 위한 백금 전구체로는 PSA (platinum sulfite acid)를 사용하였으며, 고가의 전구체를 대체하기 위해 CPA (chloroplatinic acid)를 사용하여 합성하였다. PSA를 전구체로 하여 제조한 전극촉매는 10~40 wt% 담지량에서 3.5 nm 이하의 백금 입자크기와 90% 이상의 백금 담지수율을 보였다. CPA를 전구체로 사용한 경우에는 10~40 wt% 담지량에서 4.4 nm 이하의 백금 입자 크기를 보였으며 담지수율은 80% 이상이었다. 제조한 20 wt% Pt/VXC72 전극촉매로 MEA (membrane electrode assembly)를 제조하여 I-V 곡선을 측정하였으며, 제조한 전극촉매를 이용한 막전극접합체는 상용전극촉매를 사용한 경우와 동등한 성능을 보였다.

담체자기조직화법에 의한 고집적 DNA 어레이형 마이크로칩의 개발 (Development of High-Intergrated DNA Array on a Microchip by Fluidic Self-assembly of Particles)

  • 김도균;최용성;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제51권7호
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    • pp.328-334
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    • 2002
  • The DNA chips are devices associating the specific recognition properties of two DNA single strands through hybridization process with the performances of the microtechnology. In the literature, the "Gene chip" or "DNA chip" terminology is employed in a wide way and includes macroarrays and microarrays. Standard definitions are not yet clearly exposed. Generally, the difference between macro and microarray concerns the number of active areas and their size, Macroarrays correspond to devices containing some tens spots of 500$\mu$m or larger in diameter. microarrays concern devices containing thousnads spots of size less than 500$\mu$m. The key technical parameters for evaluating microarray-manufacturing technologies include microarray density and design, biochemical composition and versatility, repreducibility, throughput, quality, cost and ease of prototyping. Here we report, a new method in which minute particles are arranged in a random fashion on a chip pattern using random fluidic self-assembly (RFSA) method by hydrophobic interaction. We intend to improve the stability of the particles at the time of arrangement by establishing a wall on the chip pattern, besides distinction of an individual particle is enabled by giving a tag structure. This study demonstrates the fabrication of a chip pattern, immobilization of DNA to the particles and arrangement of the minute particle groups on the chip pattern by hydrophobic interaction.ophobic interaction.

Influence of Impact from Anti-Aircraft Bullet on Rotorcraft Fuel Tank Assembly

  • Kim, Sung Chan;Kim, Hyun Gi
    • International Journal of Aerospace System Engineering
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    • 제5권1호
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    • pp.1-8
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    • 2018
  • Military rotorcrafts are constantly exposed to risk from bullet impacts because they operate in a battle environment. Because bullet impact damage can be deadly to crews, the fuel tanks of military rotorcraft must be designed taking extreme situations into account. Fuel tank design factors to be considered include the internal fluid pressure, the structural stress on the part impacted, and the kinetic energy of bullet strikes. Verification testing using real objects is the best way to obtain these design data effectively, but this imposes substantial burdens due to the huge cost and necessity for long-term preparation. The use of various numerical simulation tests at an early design stage can reduce the risk of trial-and-error and improve the prediction of performance. The present study was an investigation of the effects of bullet impacts on a fuel tank assembly using numerical simulation based on SPH (smoothed particle hydrodynamics), and conducted using the commercial package, LS-DYNA. The resulting equivalent stress, internal pressure, and kinetic energy of the bullet were examined in detail to evaluate the possible use of this numerical method to obtain configuration design data for the fuel tank assembly.

Packing Density Parameters of Palladium Nanoparticle Monolayers Fabricated via Spin-Coating Electrostatic Self-Assembly

  • An, Minshi;Hong, Jong-Dal;Cho, Kyung-Sang;Lee, Eun-Sung;Choi, Jae-Young
    • Bulletin of the Korean Chemical Society
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    • 제29권3호
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    • pp.623-626
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    • 2008
  • Spin-coating electrostatic self-assembly (SCESA) is utilized to fabricate a single layer of carboxylic-acid-coated Pd nanoparticles (NPs) (D??5 nm) on an oppositely charged surface. The packing density of a NP monolayer formed on a rotating solid substrate (3000 rpm) was examined with regards to various parameters, including the particle concentration, the pH, and the ionic strength of the solution. Initially, the packing density grew exponentially with increases in the particle concentration, up to a maximum value (of 8.4 ´ 1011/cm2) at 1.2 wt%. The packing density was also found to increase drastically as the pH decreased and the ionic strength of the solution increased; these trends can be attributed to a reduction in the interparticle repulsions among the NPs in the solution and on the substrate. The best result of this study was achieved in a 1.2 wt% solution at pH 8; under these conditions, an NP monolayer with the highest density (namely, 1.6 ´ 1012/cm2) was obtained.

Three-Dimensional Particle-in-cell Simulation of Electron Cyclotron Resonance Plasma with Belt-type Magnet Assembly

  • Lee, Hui Jea;Kim, Seong Bong;Yoo, Suk Jae;Cho, Moohyun;Namkung, Won
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.242.1-242.1
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    • 2014
  • The electron cyclotron resonance plasma source with a belt-type magnet assembly (BMA) is designed for effective plasma confinements. For characterizing the plasma source, the plasma parameters are measured by Langmuir probe. However, the plasma parameters and the motion of charged particles near the ECR zone are not easy to diagnostics, because of the high plasma density and temperature. Thus, as an alternative method, the electromagnetic simulation of the plasma source has been performed by using three-dimensional particle-in-cell and Monte Carlo collisional (PIC-MCC) simulation codes. For considering the limitation of simulation resources and time, the periodic boundary condition is applied and the coulomb collision is neglected. In this paper, we present the results of 3D PIC simulations of ECR plasmas with BMA and we compare them with the experimental results.

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자성체를 이용한 단백질칩 마이크로어레이의 개발 (Development of Protein Chip Microarray Using a Magnetic)

  • 최용성;이경섭;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.2398-2400
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    • 2005
  • In this paper, we have been described a new constructing method of multichannel biosensor using self-assembly by magnetic force interaction. A metal particle and an array was fabricated by photolithographic. Biomaterials were immobilized on the metal particle. The array and the particles were mixed in a buffer solution, and were arranged by magnetic force interaction and self-assembly. A quarter of total Ni dots were covered by the particles. The binding direction of the particles was controllable, and condition of particles was almost with Au surface on top. The particles were successfully arranged on the array. The biomaterial activities were detected by chemiluminescence.

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자기력에 의한 단백질칩 (Protein Chip by Magnetic Force)

  • 최용성;문종대;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
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    • pp.1317-1318
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    • 2006
  • In this paper, we have been described a new constructing method of multichannel biosensor using self-assembly by magnetic force interaction. A metal particle and an array was fabricated by photolithographic. Biomaterials were immobilized on the metal particle. The array and the particles were mixed in a buffer solution, and were arranged by magnetic force interaction and self-assembly. A quarter of total Ni dots were covered by the particles. The binding direction of the particles was controllable, and condition of particles was almost with Au surface on top. The particles were successfully arranged on the array. The biomaterial activities were detected by chemiluminescence.

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사용후핵연료 집합체 모사장치를 이용한 광섬유 체렌코프 방사선 센서 시스템의 성능평가 (Performance Evaluation of a Fiber-Optic Cerenkov Radiation Sensor System Using a Simulated Spent Fuel Assembly)

  • 신상훈;유욱재;장경원;조승현;박병기;이봉수
    • 센서학회지
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    • 제23권4호
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    • pp.245-250
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    • 2014
  • When the charged particle travels in transparent medium with a velocity greater than that of light in the same medium, the electromagnetic field close to the particle polarizes the medium along its path, and then the electrons in the atoms follow the waveform of the pulse which is called as Cerenkov light or radiation. This type of radiation can be easily observed in a spent fuel storage pit. In optical fibers, the Cerenkov light also can be generated due to their dielectric components. Accordingly, the radiation-induced light signals can be obtained using optical fibers without any scintillating material. In this study, to measure the intensities of Cerenkov radiation induced by gamma-rays, we have fabricated the fiber-optic Cerenkov radiation sensor system using silica optical fibers, plastic optical fibers, multi-anode photomultiplier tubes, simulated spent fuel assembly and a scanning system. To characterize the Cerenkov radiation generated in optical fibers, the intensities of Cerenkov radiation generated in the silica and plastic optical fibers were measured. Also, we measured the longitudinal distribution of gamma rays emitted from the Ir-192 isotope by using the fiber-optic Cerenkov radiation sensor system and simulated spent fuel assembly.

Synthesis of Monodisperse Spherical SiO2 and Self-Assembly for Photonic Crystals

  • Lee, Byung-Kee;Jung, Young-Hwa;Kim, Do-Kyung
    • 한국세라믹학회지
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    • 제46권5호
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    • pp.472-477
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    • 2009
  • Monodisperse spherical $SiO_2$ particles of various sizes ($\sim$350 nm and $\sim$800 nm) and size distributions were synthesized from TEOS and MTMS. The particle size and size distribution were controlled by changing the volume ratio of water to ethanol and the reaction temperature. Narrow-sized $SiO_2$ particles with $\sim$3% size distribution were obtained. Self-assembly of the $SiO_2$ particles for photonic crystals were performed by the solvent evaporation method. The number of ordered $SiO_2$ layers can be controlled by changing the amount of the dispersed $SiO_2$ volume fraction in the solvent.