• Title/Summary/Keyword: Particle Strength Exchange

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Fabrication of Ag doped Hydroxyapatite and its Antimicrobial Effects with the Particle Size

  • Oh, Kyung-Sik;Kim, Kyung-Ja;Jeong, Young-Keun
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.192-196
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    • 2001
  • Ag doped Hydroxyapatite powder in nano-scale was successfully synthesized either by co-precipitation or by ion exchange route. The fabricated powder was successfully dispersed through freeze drying due to the prevention of secondary particles. The antimicrobial effects of nano-HAp against E.coli was superior to micron ones not only in its strength but also in duration.

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Synthesis and Characterization of Ion Exchange Particles for Application of Anion Exchange Membrane (음이온교환막 적용을 위한 이온교환입자의 합성 및 특성평가)

  • Dong Jun Lee;Kwang Seop Im;Ka Yeon Ryu;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.3
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    • pp.137-147
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    • 2023
  • In this study, Br-PPO was developed by applying additive organic particles through a suspension polymerization synthesis method. The anion exchange membrane fuel cell system performance was evaluated using it to an anion exchange membrane. To improve the performance, organic ion exchange particles were prepared and added to the anion exchange membrane. Chemical structure analysis and synthesis were determined through FT-IR and NMR, and tensile strength and thermal stability were measured through TGA and UTM to determine whether it could be driven. Before the anion exchange membrane fuel cell test, the performance was evaluated by measuring the ion conductivity and ion exchange capacity. Finally, the Br-PPO-TMA-SDV (0.7%) anion exchange membrane with excellent ion conductivity and ion exchange capacity was introduced into the fuel cell system. Its performance was compared with FAA-3-50, a commercial membrane, to determine whether it could be introduced into a fuel cell system.

The Early Stage Behavior of Unsteady Viscous Flows past an Impulsively Started Square Cylinder (급 출발하는 정방실린더 후류의 비정상 점성유동의 초기거동)

  • Jin, Dong-Sik;Jung, Jae-Hoon;Ahn, Cheol-O;Lee, Sang-Hwan
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.259-264
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    • 2001
  • High-resolution simulations using vortex methods have been performed for simulating unsteady viscous flows around an impulsively started square cylinder. In order to investigate the phenomenon from laminar to transition flow, simulations are performed for Reynolds numbers 25, 50, 150 and 250. At extremely low Reynolds number, flow around a square cylinder is known to separate at the trailing edges rather than the leading edges. With an increase of Reynolds number, the flow separation at the leading edges will be developed. The main flow characteristics of developing recirculation region and separations from leading and trailing edges are studied with the unsteady behavior of the wake after the cylinder starts impulsively. A notable change in the flow evolution is found at Re=150, that is, it is shown that the flow separations begin at both leading and trailing edges of the square cylinder. On the other hand, when Re=250, the strong secondary vorticity from the rear surfaces of the square cylinder increases the drag coefficient as the primary vortex layer is pushed outwards. The comparisons between results of the present study and experimental data show a good consistency.

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A Comparison of a Lagrangian Vortex Method with a Finite Volume Method for the Vorticity-Velocity Formulation. (와도-속도 정식화에서 Lagrangian 보오텍스법과 유한체적법의 비교)

  • Kim Kwang-Soo;Lee Seung-Jae;Suh Jung-Chun
    • 한국전산유체공학회:학술대회논문집
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    • 2002.10a
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    • pp.47-52
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    • 2002
  • We present an improved Lagrangian vortex method in 2-D incompressible unsteady viscous flows, which is based on a mesh-free integral approach of the velocity-vorticity formulation. Vorticity fields are represented by discrete vortex blobs that are updated by the Lagrangian vorticity transport with the particle strength exchange scheme. Velocity fields are expressed in a form of the Helmholtz decomposition, which are calculated by a fast algorithm of the Biot-Savart integration with a smoothed kernel and by a well-established panel method. No-slip condition is enforced through viscous diffusion of vorticity from a solid body into field. The vorticity flux is determined in such a way that spurious slip velocity vanishes. Through the comparison with the existing finite volume scheme for the transient vortical flows around an impulsively started cylinder at Reynolds number Re=550, we would obtain a more accurate scheme for vortex methods in complicated flows.

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Evaluation of Properties of Artificial Soil Aggregate Based on Ground Granulated Blast-Furnace Slag According to Unit Binder Content (단위결합재량에 따른 고로슬래그 기반 육성용 인공토양골재의 특성평가)

  • Mun, Ju-Hyun;Sim, Jae-Il;Yun, In-Gu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.5
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    • pp.85-92
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    • 2016
  • The eight mixes and artificial soil aggregates were prepared for evaluating the practical application of lightweight foamed concrete as soil aggregates. The main parameter was unit binder content ranged between from 100 to $800kg/m^3$. In lightweight foamed concrete, flow, slurry and dried density, and compressive strength at different ages were measured. In Artificial soil aggregates crushed from lightweight foamed concrete, particle size distribution, pH, coefficient of permeability, cation exchange capacity(CEC), and ratio of carbon to nitrogen(ratio of C/N), were measured. The test results showed that flow, slurry and dried density, and compressive strength at different ages of lightweight foamed concrete increased with the increasing of unit binder content. Compressive strength at age of 28, of lightweight foamed concrete with unit binder of more than $500kg/m^3$, was more than 4 MPa. The ammonium phosphate immersion time of more than age of 3, was effective to decrease pH of artificial soil aggregates. In addition, artificial soil aggregates was evaluated as high class in terms of cation exchange capacity(CEC), while satisfied with value of ratio of carbon to nitrogen(ratio of C/N) recommended by landscape specification.

FRACTAL DIMENSION OF SIMULATED SEDIMENTS (모의류사의 쪽거리 차원)

  • 김형수;윤용남
    • Water for future
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    • v.27 no.3
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    • pp.115-121
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    • 1994
  • Cohesie sediment movement in estuarine systems is strongly affected by the phenomena of aggregation and flocculation. Aggregation is the process where primary particles are clustered together in tightly-packed formations; flocculation is the process where aggregates and single particles are bonded together to form large particle groups of very low specific density. The size, shape and strength of the flocculants control the rate of deposition and the processes of pollutant exchange between suspended sediments and ambient water. In estuarine waters, suspended sediments above the lutocline form the mobile suspension zone while below the lutocline they form the stationary suspension zone. Suspended particles in the mobile zone are generally in a dispersed state and the controlling forces are the Brownian motion and the turbulent flow fluctuations. In the stationary suspension zone, the driving force is the gravity. This paper discusses the settling and particle flocculation characteristics under quiescient flow conditions. Particles are entering the study domain randomly. Particles in the mobile suspension zone are simulated by using the Smoluchowski's model. Flocs created in the mobil suspension zone are moving into the stationary suspension zone where viscosity and drag effects are important. Utilizing the concepts of the maximum Feret's diameter and the Minkowski's sausage logic, the fractal dimension of the flocs within the stationary suspension is estimated and then compared with results obtained by other studies.

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Large Eddy Simulation for a 2-D hydrofoil using VIC(Vortex-In-Cell) method (VIC 방법을 사용한 2차원 날개의 LES 해석)

  • Kim, M.S.;Kim, Y.C.;Suh, J.C.
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.407-413
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    • 2011
  • VIC (Vortex-In-Cell) method for viscous incompressible flow is presented to simulate the wake behind a modified NACA16 foil. With uniform rectangular grid, the velocity in field is calculated using streamfunction from vorticity field by solving the Poisson equation in which FFT(Fast Fourier Transform) is combined with 2nd order finite difference scheme. Here, LES(Large Eddy Simulation) with Smagorinsky model is applied for turbulence calculation. Effective viscosity is formulated using magnitude of strain tensor(or vorticity). Then the turbulent diffusion as well as viscous diffusion becomes particle strength exchange(PSE) with averaged eddy viscosity. The well-established panel method is combined to obtain the irrotational velocity and to apply the no-penetration boundary condition on the body panel. And wall diffusion is used for no-slip condition numerical results of turbulent stresses are compared with experimental results (Bourgoyne, 2003). Before comparing process, LES(Large Eddy Simulation) SGS(Subgrid scale) stress is transformed Reynolds averaged stress (Winckelmans, 2001).

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Improvement in Mechanical Strength of α-Alumina Hollow Fiber Membrane by Introducing Nanosize γ-Alumina Particle as Sintering Agent (소결조제로 나노크기 γ-알루미나 입자의 도입에 따른 α-알루미나 중공사 분리막의 기계적 강도 향상)

  • Kim, Yong-Bin;Kim, Min-Zy;Arepalli, Devipriyanka;Cho, Churl-Hee
    • Membrane Journal
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    • v.32 no.2
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    • pp.150-162
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    • 2022
  • In the field of water treatment and pharmaceutical bio an alumina hollow fiber membrane used for mixture separation. However, due to the lack of strengths it is very brittle to handle and apply. Therefore, it is necessary to study and improve the bending strength of the membrane to 100 MPa or more. In this study, as the mixing ratio of the nano-particles increased to 0, 1, 3, and 5 wt%, the viscosity of the fluid mixture increased. The pore structure of the hollow membrane produced by interrupting the diffusion exchange rate of the solvent and non-solvent during the spinning process suppresses the formation of the finger-like structure and gradually increases the ratio of the sponge-like structure to improve the membrane mechanical strength to more than 100 MPa. As a result, an interparticle space was ensured to improve the porosity of the sponge-like structure with high permeability, and it showed excellent N2 permeability of about 100000 GPU and high water permeability of 3000 L/m2 h. Therefore, it can be concluded, that the addition of γ-Al2O3 nanoparticles as sintering aid is an important method to enhance the mechanical strength of the α-alumina hollow fiber membrane to maintain high permeability.

Competitive Adsorption of Multi-species of Heavy Metals onto Sandy Clay Loam and Clay Soils (사질식양토와 식토에서 중금속 이온의 다중 경쟁 흡착)

  • Chung, Doug Y.;Noh, Hyun-Hee
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.5
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    • pp.238-246
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    • 2005
  • We conducted this investigation to observe competitive adsorption phenomena among the heavy metals onto the available sorption sites of soil particle surfaces in sandy clay loam and clay soil collected from Nonsan city, Chungnam and Yoosung, Daejeon in Korea, respectively. Polluted and contaminated soils can often contain more than one heavy metal species, resulting in competition for available sorption sites among heavy metals in soils due to complex competitive ion exchange and specific sorption mechanism. And the adsorption characteristics of the heavy metals were reported that the selectivity for the sorption sites was closely related with electropotential and electro negativity carried by the heavy metals. The heavy metals were treated as single, binary and ternary systems as bulk solution phase. Adsorption in multi-element system was different from single-element system as Cr, Pb and Cd. The adsorption isotherms showed the adsorption was increased with increasing equilibrium concentrations. For binary and ternary systems, the amount of adsorption at the same equilibrium concentration was influenced by the concentration of individual ionic species and valence carried by the respective heavy metal. Also we found that the adsorption isotherms of Cd and Pb selected in this experiment were closely related with electronegativity and ionic potential regardless number of heavy metals in solution, while the adsorption of Cr carried higher valance and lower electro negativity than Cd and Pb was higher than those of Cd and Pb, indicating that adsorption of Cr was influenced by ionic potential than by electronegativity. Therefore adsorption in multi-element system could be influenced by electronegativity and ionic potential and valance for the same valance metals and different valance, respectively. But it still needs further investigation with respect to ionic strength and activity in multi-element system to verify sorption characteristics and reaction processes of Cr, especially for ternary system in soils.