• 한국분말재료학회지
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• 제4권1호
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• pp.55-62
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• 1997

Flow and heat transfer characteristics of gas, and trajectories and cooling characteristics of droplets/particles in a gas atomizer were investigated by a numerical simulation using FLUENT code. Among several kinds of solution method, the k-$\varepsilon$ turbulent model, power-law scheme, SIMPLE algorithm is adopted in this study. Momentum and heat exchange between a continuous phase(gas) and a dispersed phase(particle) were taken into account. Particle trajectories are simulated using the Lagrangian method, and Rosin-Rammler formula is used for the particle size distribution. Streamlines, velocities and pressures of gas, and trajectories, velocities and cooling rates of particles have been investigated for the various gas inlet conditions. Small but very intensive recirculation is found just below the melt orifice, and this recirculation seems to cause the liquid metal to spread radially. Particle trajectory depends on the particle size, the location of particle formation and the turbulent motion of gas. Small particle cools down rapidly, while large diameter particles solidify slowly, and this is mainly due to the differences in thermal inertia.

• 한국응용과학기술학회지
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• 제19권2호
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• pp.131-136
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• 2002

As model waterborne acrylic coatings, mono-dispersed poly(butyl acrylate-methyl methacrylate) copolymer latexes of random copolymer and core/shell type graft copolymer were prepared by seeded multi-staged emulsion polymerization with particle size of $180{\sim}200$ nm using semi-batch type process. Sodium lauryl sulfate and potassium persulfate were used as an emulsifier and an initiator, respectively. The effect of particle texture including core/shell phase ratio, glass transition temperature and crosslinking density, and film forming temperature on the film formation and final properties of film was investigated using SEM, AFM, and UV in this study. The film formation behavior of model latex was traced simultaneously by the weight loss measurement and by the change of tensile properties and UV transmittance during the entire course of film formation. It was found that the increased glass transition temperature and higher crosslinking degree of latex resulted in the delay of the onset of coalescence of particles by interdiffusion during film forming process. This can be explained qualitatively in terms of diffusion rate of polymer chains. However, the change of weight loss during film formation was insensitive to discern each film forming stages-I, II and III.

• 한국염색가공학회지
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• 제15권4호
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• pp.57-64
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• 2003

Poly(ethylene-co-vinyl acetate)(EVA) microspheres were prepared by a thermally induced phase separation. The microsphere formation occurred by the nucleation and growth mechanism in the metastable region. The diluent used was toluene. The microsphere formation and growth was followed by the cloud point of the optical microscope measurement. The microsphere size distribution, which was obtained by SEM observation and particle size analyzer, became broader when the polymer concentration was higher, the content of vinyl acetate in EVA copolymer was higher, and the cooling rate of EVA copolymer solution was lower.

• 한국세라믹학회지
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• 제16권2호
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• pp.99-105
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• 1979

Themogravimetric analysis was used to investigate the kinetics of the $Si_3N_4$ formation from Korean rice hulls in the temperature range from $1990^{\circ}C$ to $1370^{\circ}C$. The experimental results indicated that the reaction rate controlling step in the overall process is the diffusion of CO gas from the surface of carbon particle to main body of $N_2$ gas fluid through the stagnant gas film around the carbon particle. The kinetics followed a nearly linear rate law at the initil reaction stage. The activiation energy for the formation of $Si_3N_4$ from Korean rice hulls was 43.5Kcal/mole.

• 한국연소학회지
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• 제14권2호
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• pp.10-17
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• 2009

The present study numerically investigate the effects of the Syngas chemical kinetics on the basic flame properties and the structure of the Syngas nonpremixed flames. In order to realistically represent the turbulencechemistry interaction and the spatial inhomogeneity of scalar dissipation rate, the Eulerian Particle Flamelet Model (EPFM) with multiple flamelets has been applied to simulate the combustion processes and NOx formation in the syngas turbulent nonpremixed flames. Validation cases include the Syngas turbulent nonpremixed jet and swirling flames. Based on numerical results, the detailed discussion has been made for the effects of the chemical kinetics, the flame structure, and NOx formation characteristics in the turbulent Syngas nonpremixed flames.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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• pp.289-291
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• 2012

The present study numerically investigate detailed flame structure of the Syngas diffusion flames. In order to realistically represent the turbulence-chemistry interaction and the spatial inhomogeneity of scalar dissipation rate, the Eulerian Particle Flamelet Model(EPFM) with multiple flamelets has been applied to simulate the combustion processes and NOx formation in the syngas turbulent nonpremixed flames. And level-set approach is also utilized to account for the partially premixing effect at fuel and oxidizer injector in KEPRI nonpremixed combustor. Based on numerical results, the detailed discussion has been made for the precise structure and NOx formation characteristics of the turbulent syngas nonpremixed flames.

• 한국지반공학회논문집
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• 제31권6호
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• pp.45-58
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• 2015

본 연구에서는 이론적 고찰을 통해 Kozeny-Carman식을 변형하여 전기전도도 측정을 통한 사질토의 투수계수 추정식을 제안하였다. 제안된 예측식에 대한 실험적 검증을 위해 6종류의 사질토에 대하여 4개의 전극을 설치한 정수위 투수시험을 실시하였으며, 다양한 변수들 하에 시험을 진행하였다. 시험 결과, 사질토에서 흙 입자 표면을 통한 전기전도는 미미하였으며, 간극수의 전기전도도가 투수계수와 formation facotor에 미치는 영향은 제한적이었다. 흙 입자의 유효입경이 formation factor에 미치는 영향은 미미하였으나 투수계수에는 큰 영향을 주었다. 제안된 식을 활용하여 투수계수를 예측하기 위해서는 형상계수와 Archie's m에 대한 정보가 필요하여 error norm방법을 사용해 형상계수를 구하였다. 또한, 간극률을 변화시키며 측정된 formation factor를 사용하여 Archie's m을 구하였다. formation factor를 사용하여 계산한 투수계수를 측정값과 같이 도시한 결과, 계산된 투수계수는 측정된 투수계수와 유사한 값을 보여주었다. 기존 Kozeny-Carman식과 본 연구에서 제안하는 전기전도도를 이용한 투수식 간의 정량적인 비교를 위해, 정규화된 투수계수를 사용하여 형상계수, Archie's m, 간극률에 따른 정규화된 투수계수의 변화를 비교한 결과, 형상계수와 Archie's m의 변화에 따른 정규화된 투수계수의 변화 폭에 비해, 간극률의 변화에 따른 정규화된 투수계수는 매우 큰 폭으로 변하였다. 따라서 본 연구에서 제안하는 전기전도도를 이용한 투수계수 예측식이 기존 Kozeny-Carman식보다 더 높은 신뢰도를 보일 것으로 판단된다.

• 공업화학
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• 제9권3호
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• pp.364-371
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• 1998

이론적인 입자 응집모델이 CWM 응집물에서 인접한 석탄입자들 사이의 응집력을 예측하기 위해서 전개되었다. 유연탄은 약 $400^{\circ}C$ 또는 그 이상 가열될 때 석탄 입자들은 플라스틱성 거동으로의 전이 현상이 관찰될 수 있다. 석탄 입자들의 응집과정에서의 응집력은 입자들의 플라스틱성의 지속기간에 비례하는 것으로 알려져 있다. 본 연구에서는 가열단계에서 CWM 연료의 응집물 형성에 미치는 영향을 입자 응집모델에 의하여 고찰하였다. 실험에 사용한 전산모사 프로그램은 RKG(Runge-Kutta-Gill) 방법을 이용하여 포트란으로 작성을 하였다. 입자 응집 모델에 의한 CWM 연료의 입자 응집과정에서의 응집력은 입자 가열속도에 반비례하며, 입자크기에 비례하는 것으로 나타났다.

• Asian Journal of Atmospheric Environment
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• 제11권4호
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• pp.300-312
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• 2017

To improve the understanding of secondary organic aerosol (SOA) formation from the photo-oxidation of anthropogenic and biogenic precursors at the regional background station on Baengnyeong Island, Korea, gas phase and aerosol chemistries were investigated using the Proton Transfer Reaction Time of Flight Mass Spectrometer (PTR-ToF-MS) and the Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS), respectively. HR-ToF-AMS measured fine particles ($PM_1$; diameter of particle matter less than $1{\mu}m$) at a 6-minute time resolution from February to November 2012, while PTR-ToF-MS was deployed during an intensive period from September 21 to 29, 2012. The one-minute time-resolution and high mass resolution (up to $4000m{\Delta}m^{-1}$) data from the PTR-ToF-MS provided the basis for calculations of the concentrations of anthropogenic and biogenic volatile organic compounds (BVOCs) including oxygenated VOCs (OVOCs). The dominant BVOCs from the site are isoprene (0.23 ppb), dimethyl sulphide (DMS, 0.20 ppb), and monoterpenes (0.38 ppb). Toluene (0.45 ppb) and benzene (0.32 ppb) accounted for the majority of anthropogenic VOCs (AVOCs). OVOCs including acetone (3.98 ppb), acetaldehyde (2.67 ppb), acetic acid (1.68 ppb), and formic acid (2.24 ppb) were measured. The OVOCs comprise approximately 75% of total measured VOCs, suggesting the occurrence of strong oxidation processes and/or long-range transported at the site. A strong photochemical aging and oxidation of the atmospheric pollutants were also observed in aerosol measured by HR-ToF-AMS, whereby a high $f_{44}:f_{43}$ value is shown for organic aerosols (OAs); however, relatively low $f_{44}:f_{43}$ values were observed when high concentrations of BVOCs and AVOCs were available, providing evidence of the formation of SOA from VOC precursors at the site. Overall, the results of this study revealed several different SOA formation mechanisms, and new particle formation and particle growth events were identified using the powerful tools scanning mobility particle sizer (SMPS), PTR-ToF-MS, and HR-ToF-AMS.

• 천문학회보
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• 제44권2호
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• pp.68.3-68.3
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• 2019

We present the preliminary results on the formation of star clusters by cloud-cloud collision. For this purpose, we perform sub-parsec scale, radiation-hydrodynamic simulations of giant molecular clouds using a sink particle algorithm. The simulations include photo-ionization, direct radiation pressure, and non-thermal radiation pressure from infrared and Lyman alpha photons. We confirm that radiation feedback from massive stars suppresses accretion onto sink particles. We examine the collision-induced star formation and discuss the possibility on the formation of a globular cluster.