• 제목/요약/키워드: Partial least-squares regression

검색결과 188건 처리시간 0.031초

MEAT SPECIATION USING A HIERARCHICAL APPROACH AND LOGISTIC REGRESSION

  • Arnalds, Thosteinn;Fearn, Tom;Downey, Gerard
    • 한국근적외분광분석학회:학술대회논문집
    • /
    • 한국근적외분광분석학회 2001년도 NIR-2001
    • /
    • pp.1152-1152
    • /
    • 2001
  • Food adulteration is a serious consumer fraud and a matter of concern to food processors and regulatory agencies. A range of analytical methods have been investigated to facilitate the detection of adulterated or mis-labelled foods & food ingredients but most of these require sophisticated equipment, highly-qualified staff and are time-consuming. Regulatory authorities and the food industry require a screening technique which will facilitate fast and relatively inexpensive monitoring of food products with a high level of accuracy. Near infrared spectroscopy has been investigated for its potential in a number of authenticity issues including meat speciation (McElhinney, Downey & Fearn (1999) JNIRS, 7(3), 145 154; Downey, McElhinney & Fearn (2000). Appl. Spectrosc. 54(6), 894-899). This report describes further analysis of these spectral sets using a hierarchical approach and binary decisions solved using logistic regression. The sample set comprised 230 homogenized meat samples i. e. chicken (55), turkey (54), pork (55), beef (32) and lamb (34) purchased locally as whole cuts of meat over a 10-12 week period. NIR reflectance spectra were recorded over the wavelength range 400-2498nm at 2nm intervals on a NIR Systems 6500 scanning monochromator. The problem was defined as a series of binary decisions i. e. is the meat red or white\ulcorner is the red meat beef or lamb\ulcorner, is the white meat pork or poultry\ulcorner etc. Each of these decisions was made using an individual binary logistic model based on scores derived from principal component or partial least squares (PLS1 and PLS2) analysis. The results obtained were equal to or better than previous reports using factorial discriminant analysis, K-nearest neighbours and PLS2 regression. This new approach using a combination of exploratory and logistic analyses also appears to have advantages of transparency and the use of inherent structure in the spectral data. Additionally, it allows for the use of different data transforms and multivariate regression techniques at each decision step.

  • PDF

장기미집행 도시공원 및 녹지 보상재원 마련을 위한 지방채 발행과 보상우선지역 선정 - 서울특별시를 대상으로 - (Issuing Municipal Bonds to Pay Compensation for Lands and Selecting Compensation Priority Areas for Urban Parks and Greenbelts unexecuted in the Long-Term - With a Focus on Seoul City -)

  • 김유리
    • 한국조경학회지
    • /
    • 제45권3호
    • /
    • pp.92-106
    • /
    • 2017
  • 이 연구에서는 장기미집행 도시공원 및 녹지 토지보상 재원마련을 위한 지방채 발행의 타당성을 검토하였고, 지방채를 발행하여 지가 상승이 높은 지역을 우선보상할 것을 제안하였다. 이를 위해 장기미집행 도시공원 및 녹지 32개소를 대상으로 상관분석과 부분최소제곱(Partial Least Square: PLS) 회귀분석을 실시함으로써 '7년간 개별공시지가 상승가'에 영향을 미치는 요인을 규명하였다. PLS 회귀분석의 투영시 변수 중요도 값은 '기준년도 개별공시지가(1.919)', '해당 자치구 누적상승률(1.176)' 순으로 높았다. 본 연구의 시사점은 다음과 같다. 지난 12년간 서울의 평균개별공시지가 누적상승률이 지방채 누적이자율보다 더 높다는 것은 지방채 발행으로 지급해야 하는 이자보다 개별공시지가가 더 많이 올랐다는 것을 의미한다. 더구나 실보상가는 개별공시지가의 3배 정도 되므로, 실제로는 지급이자액보다 훨씬 더 많은 지가 상승이 이루어졌을 것이다. 이는 지방채를 발행하여 지가상승이 높은 지역과 같은 보상우선대상지를 선매수하는 것이 예산집행에 있어서 경제성과 효율성을 높일 수 있음을 보여준다. 또한 예산집행의 경제적 효율성을 위하여, 지가 상승이 높을 것으로 예상되는 '개별공시지가가 높은 곳', '지가 상승이 높은 자치구에 속한 곳'을 우선보상 기준항목으로 선정하는 것이 필요함을 보여준다. 앞으로, 장기미집행 도시공원 및 녹지 토지보상을 위해서 지방채를 발행할 경우, 지방채 상환재원 마련방안에 대한 다양한 연구도 함께 진행되어야 할 것이다.

Near Infrared Diffuse Reflectance Spectroscopy to Measure Pulmonary Edema

  • Larry Leonardi;David H.Burns;Luis Openheimer;Rene P.Michel
    • Near Infrared Analysis
    • /
    • 제2권1호
    • /
    • pp.43-53
    • /
    • 2001
  • A non-invasive spectroscopic method is presented for the measurement of pulmonary edema. Both early diagnosis and quantitative edema estimates were investigated. The spectroscopic determination of pulmonary edema involved the acquisition of diffuse reflectance spectra in the near-infrared (NIR) region with change in water concentration - water is the main constituent of edema fluid. Pulmonary edema was induced into the excised perfused lungs of seven animals by elevating the hydrostatic pressure. Estimates of edema were ascertained from a partial least squares regression of the measured spectral response. Actual edema was determined from the change (increase) in total lung weight. Estimates in relative lung weight increases due to in vitro edema were made with the near infrared spectra. The results revealed that fluid accumulation produced spectral changes in the O-H and C-H absorptions as well as scattering changes in the spectra. Histology of the lung was used to verify the presence or absence of interstitial and alveolar edema. Results demonstrated that near infrared spectroscopy might provide a new tool for clinical assessment of pulmonary edema.

Major Characteristics Affecting the Sensory Quality of Rice Marketed in Korea

  • Jang, Eun-Hee;Kim, Qui-Woung;Kim, Hoon;Kim, Dong-Chul;Lee, Se-Eun;Kim, Sang-Sook
    • Food Science and Biotechnology
    • /
    • 제17권1호
    • /
    • pp.66-71
    • /
    • 2008
  • A total of 284 milled rice (MR) marketed in Korea were analyzed for grading characteristics (head rice, broken kernels, chalky kernels, and damaged kernels%), color characteristics (L-, a-, b-values, and whiteness), protein content (%), and the cooked rice (CR) sensory quality to investigate the key characteristics affecting the overall sensory quality of rice marketed in Korea. Relatively high correlation with the overall sensory quality of the CR was found in color characteristics such b-value of the CR (r=-0.779) and MR (r=-0.545), the a-value of the CR (r=0.513), and the whiteness (r=0.298) of the MR, compared to protein (r=-0.150), and the moisture (r=0.158) contents of the MR and the percentage of head rice (r=0.195). Partial least squares (PLS) regression of the CR b-value with various characteristics of the MR showed that CR b-value was increased with MR b-value effectively, followed by protein content, damaged kernels, chalky kernels, and colored kernels of MR while it was decreased with whiteness and moisture content for the MR.

Near Infrared Reflectance Spectroscopy(NIRS)에 의한 음식물 쓰레기 퇴비 분석에 관한 연구 (Analysis on Food Waste Compost by Near Infrared Reflectance Spectroscopy(NIRS))

  • 이효원;길동용
    • 한국유기농업학회지
    • /
    • 제13권3호
    • /
    • pp.281-289
    • /
    • 2005
  • In order to find out an alternative way of analysis of food waste compost, the Near Infrared Reflectance Spectroscopy(NIRS) was used for the compost assessment because the technics has been known as non-detructive, cost-effective and rapid method. One hundred thirty six compost samples were collected from Incheon food waste compost factory at Namdong Indurial Complex. The samples were analyzed for nitrogen, organic matter (OM), ash, P, and K using Kjedahl, ignition method, and acid extraction with spectrophotometer, respectively. The samples were scanned using FOSS NIRSystem of Model 6500 scanning mono-chromator with wavelength from $400\~2,400nm$ at 2nm interval. Modified partial Least Squares(MPLS) was applied to develop the most reliable calibration model between NIR spectra and sample components such as nitrogen, ash, OM, P, and K. The regression was validated using validation set(n=30). Multiple correlation coefficient($R^2$) and standard error of prediction(SEP) for nitrogen, ash, organic matter, OM/N ratio, P and K were 0.87, 0.06, 0.72, 1.07, 0.68, 1.05, 0.89, 0.31, 0.77, 0.06, and 0.64, 0.07, respectively. The results of this experiment indicates that NIRS is reliable analytical method to assess some components of feed waste compost, also suggests that feasibility of NIRS can be Justified in case of various sample collection around the year.

  • PDF

Factors Influencing Use of Social Commerce: An Empirical Study from Indonesia

  • RAHMAN, Arief;FAUZIA, Refika Nurliani;PAMUNGKAS, Sigit
    • The Journal of Asian Finance, Economics and Business
    • /
    • 제7권12호
    • /
    • pp.711-720
    • /
    • 2020
  • This research aims to analyze the factors affecting the acceptance of social commerce, including performance expectancy, effort expectancy, social support, facilitating conditions, hedonic motivation, habitability, price saving orientation, and privacy concerns using the Unified Theory of Acceptance and Use of Technology (UTAUT2). UTAUT2 has been examined and modified in various contexts. The research model studies the acceptance and use of technology in the context of customers. This study adopts a quantitative method using the partial least squares regression (PLS) approach involving 244 respondents. The respondents are users of social commerce in Indonesia. The result of this research indicates that social influence, facilitating conditions, hedonic motivation, habit, price value orientation, and privacy concerns have a significant effect on behavioral intention. On the other hand, performance expectancy and effort expectancy does not affect behavioral intention. Furthermore, price value has a significant effect on social commerce user behavior. Lastly, facilitating conditions and habits does not affect social commerce user behavior. This research contributes to the development of theory by examining an additional variable, which is privacy concern. This study is significant since social media and social commerce have grown exponentially nowadays. Implications of the results for the development of the theory (UTAUT2) and practice are discussed in the article.

PLS 기법에 의한 (X,Y) 자료의 시각화 (Visualizing (X,Y) Data by Partial Least Squares Method)

  • 허명회;이용구;이성근
    • 응용통계연구
    • /
    • 제20권2호
    • /
    • pp.345-355
    • /
    • 2007
  • PLS 회귀는 q-변량의 Y 변수에 대한 회귀에서 p-변량의 X 변수가 다중공선성의 문제를 갖는 경우에도 적용 가능한 방법이다. 특히 X 변수의 수 p가 관측개체 수 n보다 큰 경우에 적용 가능하여 계량화학(chemometrics) 분야에서 근적외선 분광기(near-infrared spectroscopy) 자료에 대한 표준적 분석 방법으로 활용되고 있다. 이 연구에서 우리는 PLS회귀의 방법론을 정리하고 이를 활용한 p개의 X 변수들과 q개의 Y 변수들의 동시 시각화를 위한 두 가지의 수량화 방법을 제안한다.

ANALYTICAL APPLICATIONS OF NEW PORTABLE NEAR INFRARED (NIR) SPECTROMETER SYSTEM

  • Ahn, Jhii-Weon;Kang, Na-Roo;Lim, Hung-Rang;Lee, Jung-Hun;Woo, Young-Ah;Kim, Hyo-Jin
    • 한국근적외분광분석학회:학술대회논문집
    • /
    • 한국근적외분광분석학회 2001년도 NIR-2001
    • /
    • pp.1122-1122
    • /
    • 2001
  • A compact and handhold near infrared (NIR) system using microspectrometer was developed. This system was suitable not only in the laboratory, but also in the field or in the process. This system was first applied for classification of geographical origin of herbal medicine such as ginseng and sesame. To identify the origin of ginseng on site, the portable NIR system is more suitable for real field application. For this study, using the compact NIR system, soft independent modeling of class analogies (SIMCA) with 1100-1750 nm NIR spectra was utilized for classification of geographical origin (Korea and China) of both ginseng and sesame. The accuracy of results is more than 90%. Quantitative analysis for petroleum such as toluene, benzene, tri-methyl benzene, and ethyl benzene was performed with partial least squares (PLS) regression with NIR 1100-1750 nm spectra. This study showed that the NIR method and gas chromatography (GC), which is a standard method, have good correlations. Furthermore, the ash content of Cornu Cervi Parvum was analyzed and the accuracy was confirmed by the developed compact NIR system.

  • PDF

Studies on pharmaceutical assay method using Near Infrared Spectroscopy (NIRS) (II)

  • Kang, Shin-Jung;Yun, Mi-Ok;Lee, Su-Jung;Choi, Hyun-Chul;Kim, Ho-Jeong;Kim, Ji-Yeon
    • 한국근적외분광분석학회:학술대회논문집
    • /
    • 한국근적외분광분석학회 2001년도 NIR-2001
    • /
    • pp.4113-4113
    • /
    • 2001
  • This study developed effective assay method of pharmaceutical quality control was developed by near-infrared spectroscopy (NIRS). The calibration equation model of assay was developed by 2nd deriviative PLS(Partial Least Squares) regression method with NIRS over the wavelength range from 1100 to 1400nm using diazepam tablets (2mg, 5mg). Although diazepam tablets are made by 5-different manufacture, they have similar formulation. When the correlation was compared with values by NIRS and HPLC, the R-2s and standard error of calibration (SEC) for 2mg were 0.9300 and 0.98%, the R-2s and SEC for 5mg were 0.9165 and 0.63%. The validation of the calibration equation model yield that the R-2s and standard error of prediction (SEP) for 2mg were 0.9611 and 0.995%, the R-2s and SEP for 5mg were 0.9114 and 0.842%. The method was validated on assay method for diazepam tablets by the calibration equation.

  • PDF

DEVELOPMENT OF PORTABLE NEAR INFRARED SYSTEM FOR HUMAN SKIN MOISTURE

  • Woo, Young-Ah;Ahn, Jhii-Weon;Kim, Hyo-Jin
    • 한국근적외분광분석학회:학술대회논문집
    • /
    • 한국근적외분광분석학회 2001년도 NIR-2001
    • /
    • pp.3115-3115
    • /
    • 2001
  • In this study, portable near infrared (NIR) system was newly integrated with a photodiode array detector, which has no moving parts and this system has been successfully applied for evaluation of human skin moisture. The good correlation between NIR absorbance and absolute water content of separated hairless mouse skin was, in vitro, showed depending on the water content (7.42-84.94%) using this portable NIR system. Partial least squares (PLS) regression was used for the calibration with the 1100-1650 nm wavelength range. For the practical use for the evaluation of human skin based on moisture, PLS model for human skin moisture was, in vivo, developed using the portable NIR system based on the relative water content values of stratum corneum from the conventional capacitance method. The PLS model showed a good correlation. This study indicated that the portable NIR system could be a powerful tool for human skin moisture, which may be much more stable to environmental conditions such as temperature and humidity, compared to conventional methods. Furthermore, in order to confirm the performance of newly integrated portable NIR system, scanning type conventional NIR spectrometer was used in the same experiments and the results were compared.

  • PDF