• Title/Summary/Keyword: Partial least-squares regression

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Development of non-destructive pungency measurement technique for red-pepper powder produced in different domestic origins (국내 원산지별 고춧가루의 매운맛 비파괴 측정기술 개발)

  • Mo, Changyeun;Lee, Kangjin;Lim, Jong-Guk;Kang, Sukwon;Lee, Hyun-Dong;Cho, Byoung-Kwan
    • Korean Journal of Agricultural Science
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    • v.39 no.4
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    • pp.603-612
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    • 2012
  • In this research, the feasibility of non-destructive measurement technique of pungency measurement was investigated for the red-pepper powders produced in different domestic areas in South Korea. The near-infrared absorption spectra in the range of 1100 nm~2300 nm was used to measure capsaicinoids content in red-pepper powders by using a NIR spectroscopy equipped with Acousto-optic tunable filters (AOTF). Fourth three different red-pepper powders from 14 different locations were collected and separated in three different particle size (below 0.425 mm, 0.425~0.71 mm, 0.71~1.4 mm) for the spectral measurements. The partial least square regression (PLSR) models to predict the capsaicinoids content depends on particle size were developed with the measured spectra. The determinant coefficients and standard errors of the developed models for the red-pepper powders of below 0.425 mm, 0.425~0.71 mm, and 0.71~1.4 mm were in the range of 0.859~0.887 and 12.90~12.99 mg/100 g, respectively. The PLS model with the pretreatment of Standard Normal Variate (SNV) for the red-pepper powders below 1.4 mm particle size showed the best performance with the determinant coefficient of 0.844 and the standard error of 14.63 mg/100 g.

Discrimination of Cultivars and Cultivation Origins from the Sepals of Dry Persimmon Using FT-IR Spectroscopy Combined with Multivariate Analysis (FT-IR 스펙트럼 데이터의 다변량 통계분석을 이용한 곶감의 원산지 및 품종 식별)

  • Hur, Suel Hye;Kim, Suk Weon;Min, Byung Whan
    • Korean Journal of Food Science and Technology
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    • v.47 no.1
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    • pp.20-26
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    • 2015
  • This study aimed to establish a rapid system for discriminating the cultivation origins and cultivars of dry persimmons, using metabolite fingerprinting by Fourier transform infrared (FT-IR) spectroscopy combined with multivariate analysis. Whole-cell extracts from the sepals of four Korean cultivars and two different Chinese dry persimmons were subjected to FT-IR spectroscopy. Principle component analysis (PCA) and partial least squares discriminant analysis (PLS-DA) of the FT-IR spectral data successfully discriminated six dry persimmons into two groups depending on their cultivation origins. Principal component loading values showed that the 1750-1420 and $1190-950cm^{-1}$ regions of the FT-IR spectra were significantly important for the discrimination of cultivation origins. The accuracy of prediction of the cultivation origins and cultivars by PLS regression was 100% (p<0.01) and 85.9% (p<0.05), respectively. These results clearly show that metabolic fingerprinting of FT-IR spectra can be applied for rapid discrimination of the cultivation origins and cultivars of commercial dry persimmons.

Estimation of Nitrate Nitrogen Concentration in Liquid Fertilizer Contaminated Areas using Hyperspectral Images (초분광 영상을 이용한 액비 오염지역의 질산성질소 농도 추정)

  • Lim, Eun Sung;Kim, I Seul;Han, Soo Jeong;Lim, Tai Yang;Song, Wonkyong
    • Journal of the Society of Disaster Information
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    • v.16 no.3
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    • pp.542-549
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    • 2020
  • Purpose: As nitrate nitrogen produced during fermentation of liquid fertilizer is a pollution indicator of water, in this study, four research areas where liquid fertilizer was sprayed were selected, and a model was designed to estimate the concentration of nitrate nitrogen pollution. Method: Prior to shooting on site, a spectrum library was constructed by dividing the ratio of liquid fertilizer into 5 groups: 0%, 25%, 50%, 75%, and 100%. PLSR (Partial least squares regression) method was applied to hyperspectral images acquired in the study area based on the aspect of spectrum. Result: The behavior of nitrate nitrogen was confirmed by 1st and 2nd differentiation of the spectrum of the constructed liquid fertilizer. PLSR concentration estimation modeling was implemented using images from field experiments and compared with actual concentration of nitrate nitrogen. Conclusion: When comparing the PLSR concentration estimation model with the actual concentration of nitrate nitrogen, it was measured that the detection is possible in high concentration areas where the concentration of nitrate nitrogen is 70mg/kg or more.

A New Calibration Method Based on the Recursive Linear Regression with Variables Selection

  • Park, Kwang-Su;Jun, Chi-Hyuck
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1241-1241
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    • 2001
  • We propose a new calibration method, which uses the linearization method for spectral responses and the repetitive adoptions of the linearization weight matrices to construct a frature. Weight matrices are estimated through multiple linear regression (or principal component regression or partial least squares) with forward variable selection. The proposed method is applied to three data sets. The first is FTIR spectral data set for FeO content from sinter process and the second is NIR spectra from trans-alkylation process having two constituent variables. The third is NIR spectra of crude oil with three physical property variables. To see the calibration performance, we compare the new method with the PLS. It is found that the new method gives a little better performance than the PLS and the calibration result is stable in spite of the collinearity among each selected spectral responses. Furthermore, doing the repetitive adoptions of linearization matrices in the proposed methods, uninformative variables are disregarded. That is, the new methods include the effect of variables subset selection, simultaneously.

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Psychological Factors of Increase in Apple Consumption (사과 소비의 증가에 영향을 미치는 심리적 요인 분석)

  • Huh, Moo-Yul
    • Journal of the Korean Society of Food Culture
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    • v.26 no.1
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    • pp.80-85
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    • 2011
  • This study analyzed consumer attitude, habit strength, subjective norm, a pros evaluation, and intention to consume to estimate perceptible variables that affect apple consumption. Data were collected from 207 men and women through a selfadministrated questionnaire. A partial least squares regression was conducted as one of structural equation models to estimate and test hypotheses. The results showed that attitude, habit strength, and the pros evaluation affected the intention to consume apples, and that the intention increased apple consumption. The results also showed that some marketing strategies are needed to promote apple consumption and to make consumers change their intention, to develop habits for eating apples by changing their diets, and to impress upon them that apples are good for health. This can be interpreted as meaning that it is most important to understand consumer behavior, particularly consumer psychology, which is reflected in the recent trend of marketing that concentrates on meeting the consumer's needs rather than the producer's.

EVALUATION OF NIRS FOR ASSESSING PHYSICAL AND CHEMICAL CHARACTERISTICS OF LINEN WEFT YARN

  • Sharma, Hss;Kernaghan, K.;Whiteside, L.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1091-1091
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    • 2001
  • Previous reports have shown that Near Infrared Spectroscopy (NIRS) can be used to assess physical and chemical properties of flax fibre and fabric quality. Currently, spinners assess yarn quality mainly based on strength and regularity measurements. There two key characteristics are influenced by quality of raw fibres used, especially the degree of rotting and strength. The aim of this investigation was to evaluate the use of NIRS for assessing quality of weft grade yarn available on the commercial market. In order to develop the NIR calibrations, a range of samples representing poor, medium and good quality weft yarn samples was included in the calibration and validation sample sets. The samples were analysed for physical and chemical parameters including caustic weight loss, fibre fractions, lipid, ash and minerals. A detailed protocol for assessing yarn quality has been developed to maximize the accuracy of the reflectance spectra. The development of partial least squares regression models and validation of the calibration equations using blind samples will be presented and discussed.

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Comparison of Performance of Models to Predict Hardness of Tomato using Spectroscopic Data of Reflectance and Transmittance (토마토 반사광과 투과광 스펙트럼 분석에 의한 경도 예측 성능 비교)

  • Kim, Young-Tae;Suh, Sang-Ryong
    • Journal of Biosystems Engineering
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    • v.33 no.1
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    • pp.63-68
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    • 2008
  • This study was carried out to find a useful method to predict hardness of tomato using optical spectrum data. Optical spectrum of reflectance and transmittance data were collected processed by 9 kind of preprocessing methods-normalizations of mean, maximum and range, SNV (standard normal variate), MSC (multiplicative scatter correction), the first derivative and second derivative of Savitzky-Golay and Norris-Gap. With the preprocessed and non-processed original spectrum data, prediction models of hardness of tomato were developed using analytical tools of PLS (partial least squares) and MLR (multiple linear regression) and tested for their validation. The test of validation resulted that the analytical tools of PLS and MLR output similar performances while the transmittance spectra showed much better result than the reflectance spectra.

Application of SeaWiFS data for assessment of eutrophication in the Pearl River estuary

  • Chen, Chuqun;Li, Xiaobin
    • Proceedings of the KSRS Conference
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    • v.2
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    • pp.909-912
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    • 2006
  • In this paper a method for remotely-sensed assessment of eutrophication was experimented. The water samples were collected for analysis of COD (chemical oxygen demand) and nutrients concentration, and the remote sensing reflectance data at the sampling points were synchronously measured using above-water method in two cruises, which were conducted in the Pearl River Estuary in January 2003 and January 2004 respectively. Based on the in-situ data the local algorithms for estimation of concentration of nutrients (P and N) and COD were developed by Partial Least Squares (PLS) regression. The algorithms were then applied to atmospheric-corrected SeaWiFS data and the COD and nutrients concentration in Pearl River Estuary were estimated. And then the assessment of eutrophication was carried out by comparison of the estimated nutrients and COD value with the water quality standard. The results show that the whole estuary is seriously in eutrophication.

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Non-invasive Blood Glucose Measurement by a Portable Near Infrared (NIR) System (휴대용 근적외선 분광분석기를 이용한 비침투 혈당 측정)

  • 강나루;우영아;차봉수;이현철;김효진
    • YAKHAK HOEJI
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    • v.46 no.5
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    • pp.331-336
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    • 2002
  • The purpose of this study is to develop a non-invasive blood glucose measurement method by a portable near infrared (NIR) system which was newly integrated by our lab. The portable NIR system includes a tungsten halogen lamp, a specialized reflectance fiber optic probe and a photo diode array type InGaAs detector; which was developed by a microchip technology based on the lithography. Reflectance NIR spectra of different parts of human body (finger tip, earlobe, and inner lip) were recorded by using a fiber optic probe. The spectra were collected over the spectral range 1100 ∼ 1740 nm. Partial least squares regression (PLSR) was applied for the calibration and validation for the determination of blood glucose. The calibration model from earlobe spectra presented better results, showing good correlation with a glucose oxidase method which is a mostly used standard method. This model predicted the glucose concentration for validation set with a SEP of 33 mg/dL. This study indicated the feasibility for non-invasive monitoring of blood glucose by a portable near infrared system.

Discrimination of Oil Seeds According to Geographical Origin Using Near Infrared Reflectance Spectroscopy (근적외선 분광분석법을 이용한 유량종자의 원산지 판별)

  • Kwon, Hye-Soon
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.1
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    • pp.21-24
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    • 1999
  • Sesame seed (Sesamum indicum L.) is an important seasoning in Korea and most korean consumer tend to eat the korean sesame seed as the best than other ones produced in oriental countries such as China and Japan. Near infrared reflectance spectroscopy (NIRS) was applied for discrimination according to geographical origin (Korea, China and so on) of sesame seeds. Near-infrared spectroscopy among the many kinds of techniques could provide a rapid screening, low cost solution to discriminate geographical origin of sesame seed. The objective of this study is to determine if NIR technique could be used to discriminate between the korean sesame seed and non-korean sesame seed by using the new method. Rapid, precise and nondestructive analysis method for determination of the geographic origin of sesame seeds were discriminated relative accurately according to geographical origin using PLS regression method.