• International Journal of Concrete Structures and Materials
• /
• 제10권1호
• /
• pp.113-124
• /
• 2016

This paper presents the effect of silica fume and nano silica, used individually and in combination with the set accelerator and/or hydrated lime, on the properties of class F high volume ultra fine fly ash (HV-UFFA) cement composites, replacing 80 % of cement (OPC). Compressive strength test along with thermogravimetric analysis, X-ray diffraction and scanning electron microscopy were undertaken to study the effect of various elements on the physico-chemical behaviour of the blended composites. The results show that silica fume when used in combination with the set accelerator and hydrated lime in HV-UFFA cement mortar, improves its 7 and 28 day strength by 273 and 413 %, respectively, compared to the binary blended cement fly ash mortar. On the contrary, when nano silica is used in combination with set accelerator and hydrated lime in HV-UFFA cement mortar, the disjoining pressure in conjunction with the self-desiccation effect induces high early age micro cracking, resulting in hindering the development of compressive strength. However, when nano silica is used without the additives, it improves the 7 and 28 day strengths of HV-UFFA cement mortar by 918 and 567 %, respectively and the compressive strengths are comparable to that of OPC.

• 콘크리트학회지
• /
• 제9권3호
• /
• pp.189-197
• /
• 1997

본 연구에서는 보통의 일반콘크리트와 플라이애쉬를 혼입한 강섬유보강 콘크리트의 해수에 대한 저항성을 고찰하기 위하여 수행되었다. 콘크리트 배합 인자를 물.시멘트비, 강섬유혼입률, 플라이애쉬 혼입률별로 각각 제조하였으며, 표준수(수도물)와 인공으로 제조한 해수에 장기간 침지한 경우와 건조와 습윤의 반복작용에 의한 촉진시험으로 시험을 수행하여 콘크리트의 성능저하에 미치는 영향을 비교.고찰하였다. 시험방법은 소정의 재령에 각각의 배합조건별로 압축강도와 재령 1일을 기준으로 길이변화와 동탄성계수를 측정하여 성능저하정도를 비교분석하였다. 그 결과 강섬유와 플라이애쉬의 적정량의 혼입은 콘크리트의 내해수성을 현저히 개선시키는 효과를 나타내었다.

• 한국건축시공학회지
• /
• 제12권2호
• /
• pp.194-202
• /
• 2012

This paper predicts the cementing efficiency of fly-ash(FA) based on mortar test considering binder-water ratio and FA replacement ratio as experimental variables. The cementing efficiency prediction model proposed by statistical analysis enables us to estimate the value according to the binder-water ratio and FA replacement ratio of matrix. When FA replacement ratio is the same, the lower the binder-water ratio, the higher the estimated cementing efficiency. There are significant differences in the values according to binder-water ratio at FA replacement ratios of 15% or less, but there are almost no differences when FA replacement ratio is more than 15%. As the binder-water ratio increases, the variations in the values according to FA replacement ratio are great at FA replacement ratios of 15% or less. As the FA replacement ratios increase, the values increase for FA replacement ratios of 15% or less, but decrease for more than 15%. The values range from -0.71 to 1.24 at binder-water ratio of 1.67-2.86 and FA replacement ratio of 0-70%. The RMSE of the 28-day compressive strength predicted by modified water-cement ratio is 2.2 MPa. The values can be trusted, as there is good agreement between predicted strength and experimental strength.

• 한국세라믹학회지
• /
• 제51권2호
• /
• pp.64-71
• /
• 2014

Accelerated carbonation is a technique that can be used as a CCS technology for $CO_2$ sequestration of approximately 5~20% in a stable solid through the precipitation of carbonate. An alkaline inorganic waste material such as ash, slag, and cement paste are generated from incinerators, accelerated carbonation offers the advantage of lower transport and processing costs at the same generation location of waste and $CO_2$. In this study, we evaluated an amount of $CO_2$ sequestration in various types of inorganic alkaline waste processed by means of accelerated carbonation. A quantitative evaluation of $CO_2$ real sequestration based on a TG/DTA analysis, the maximum 118.88 $g/kg_{-waste}$ of $CO_2$ in paper sludge fly ash, the maximum 134.46 $g/kg_{-waste}$ of $CO_2$ in municipal solid waste incinerator bottom ash, the maximum 9.72 $g/kg_{-waste}$ of $CO_2$ in industrial solid waste incinerator fly ash, and the maximum $18.19g/kg_{-waste}$ of $CO_2$ in waste cement paste.

• Advances in concrete construction
• /
• 제5권4호
• /
• pp.313-330
• /
• 2017

Geopolymer is a sustainable concrete, replaces traditional cement concrete using alternative sustainable construction materials as binders and alkaline solution as alkaline activator. This paper presents the strength characteristics of geopolymer concrete (GPC) developed with fly ash and GGBS as binders, combined Sodium silicate ($Na_2SiO_3$) and Sodium Hydroxide (NaOH) solution as alkaline activators. The parameters considered in this research work are proportions of fly ash and GGBS (70-30 and 50-50), curing conditions (Outdoor curing and oven curing at $600^{\circ}C$ for 24 hours), two grades of concrete (GPC20 and GPC50). The mechanical properties such as compressive strength, split tensile strength and flexural strength along with durability characteristics were determined. For studying the durability characteristics of geopolymer concrete 5% $H_2SO_4$ solutions was used and the specimens were immersed up to an exposure period of 56 days. The main parameters considered in this study were Acid Mass Loss Factor (AMLF), Acid Strength Loss Factor (ASLF) and products of degradation. The results conclude that GPC with sufficient strength can be developed even under Outdoor curing using fly ash and GGBS combination i.e., without the need for any heat curing.

• Computers and Concrete
• /
• 제19권2호
• /
• pp.217-226
• /
• 2017

This paper summarizes the results of experimental research, and artificial intelligence methods focused on determination of compressive strength of lightweight cement mortar with silica fume and fly ash after sulfate attack. The artificial neural network and the support vector machine were selected as artificial intelligence methods. Lightweight cement mortar mixtures containing silica fume and fly ash were prepared in this study. After specimens were cured in $20{\pm}2^{\circ}C$ waters for 28 days, the specimens were cured in different sulfate concentrations (0%, 1% $MgSO_4^{-2}$, 2% $MgSO_4^{-2}$, and 4% $MgSO_4^{-2}$ for 28, 60, 90, 120, 150, 180, 210 and 365 days. At the end of these curing periods, the compressive strengths of lightweight cement mortars were tested. The input variables for the artificial neural network and the support vector machine were selected as the amount of cement, the amount of fly ash, the amount of silica fumes, the amount of aggregates, the sulfate percentage, and the curing time. The compressive strength of the lightweight cement mortar was the output variable. The model results were compared with the experimental results. The best prediction results were obtained from the artificial neural network model with the Powell-Beale conjugate gradient backpropagation training algorithm.

• 한국농공학회지
• /
• 제44권2호
• /
• pp.107-116
• /
• 2002

The amount used of aggregates for concrete is increasing rapidly since the mid-1980s in Korea. The natural gravels from river are already displaced with crushed stone, and use of crushed sand as a substitute of natural river sands, also, is getting increased day by day. This paper is presented fur analysis on mechanical properties of high strength concrete using fly ash and crushed sand. The material functions in mixing design of concretes are various water-cement ratios(w/c) such as 0.25, 0.40, 0.55 and different replacement ratio of crushed sand to natural sands such as 0%, 20%, 40%, 60%. As a results, it has been shown that compressive strengths of concretes with W/C lower than 0.40 and 0.25 are higher than 400 kgf/$\textrm{cm}^2$ and 600 kgf/$\textrm{cm}^2$ respectively. It is also concluded that the results of rapid chloride permeability tests of concrete are evaluated to negligible. The conclusions of this study is that it is possible to use fly ash and crushed sand fur high strength concrete.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2019년도 추계 학술논문 발표대회
• /
• pp.21-22
• /
• 2019

In order to prevent global warming according to fossil fuel use, countries around the world are making efforts through the Kyoto Protocol and the Paris Climate Change Convention. In addition, in order to prepare for high oil prices, researches such as the development of various renewable energy are being conducted. At present, the domestic production rate of energy sources in Korea is low at 18.1%, and power plants using forest biomass are being constructed to meet the domestic situation where 63% of the land is a forest. In 2015, the global production of wood pellets, a raw material for wood-based biomass power generation, was 28 million tons, up 7.7% from 2014, and has increased tenfold over the last decade. This is a result of increased demand for biomass. Korea is also increasing every year. However, biomass fly ash, an industrial by-product generated by biomass energy generation, is now being disposed of entirely, and there is little research to utilize it. Therefore, this paper will use biomass fly ash, an industrial by-product, which is currently being discarded due to a lack of separate treatment methods, as an admixture concept to contribute to solving environmental problems, developing new admixtures, improving quality, and seeking recycling plans.

• Advances in concrete construction
• /
• 제5권6호
• /
• pp.671-683
• /
• 2017

Commonly used concrete in general, consists of cement, fine aggregate, coarse aggregate and water. Natural river sand is the most commonly used material as fine aggregate in concrete. One of the important requirements of concrete is that it should be durable under certain conditions of exposure. The durability of concrete is defined as its ability to resist weathering action, chemical attack or any other process of deterioration. Durable concrete will retain its original form, quality and serviceability when exposed to its environment. Deterioration can occur in various forms such as alkali aggregate expansion, freeze-thaw expansion, salt scaling by de-icing salts, shrinkage, attack on the reinforcement due to carbonation, sulphate attack on exposure to ground water, sea water attack and corrosion caused by salts. Addition of admixtures may control these effects. In this paper, an attempt has been made to replace part of fine aggregate by tailing material and part of cement by fly ash to improve the durability of concrete. The various durability tests performed were chemical attack tests such as sulphate attack, chloride attack and acid attack test and water absorption test. The concrete blend with 35% Tailing Material (TM) in place of river sand and 20% Fly Ash (FA) in place of OPC, has exhibited higher durability characteristics.

• Advances in concrete construction
• /
• 제11권1호
• /
• pp.73-80
• /
• 2021

Rice Husk Ash (RHA) geopolymer paste activated by sodium aluminate were characterized by X-ray diffractogram (XRD), scanning electron microscope (SEM), energy dispersion X-Ray analysis (EDAX)and fourier transform infrared spectroscopy (FTIR). Five series of RHA geopolymer specimens were prepared by varying the Si/Al ratio as 1.5, 2.0, 2.5, 3.0 and 3.5. The paper focuses on the correlation of microstructure with hardened state parameters like bulk density, apparent porosity, sorptivity, water absorption and compressive strength. XRD analysis peaks indicates quartz, cristobalite and gibbsite for raw RHA and new peaks corresponding to Zeolite A in geopolymer specimens. In general, SEM micrographs show interconnected pores and loosely packed geopolymer matrix except for specimens made with Si/Al of 2.0 which exhibited comparatively better matrix. Incorporation of Al from sodium aluminate were confirmed with the stretching and bending vibration of Si-O-Si and O-Si-O observations from the FTIR analysis of geopolymer specimen. The dense microstructure of SA2.0 correlate into better performance in terms of 28 days maximum compressive strength of 16.96 MPa and minimum for porosity, absorption and sorptivity among the specimens. However, due to the higher water demand to make the paste workable, the value of porosity, absorption and sorptivity were reportedly higher as compared with other geopolymer systems. Correlation regression equations were proposed to validate the interrelation between physical parameters and mechanical strength. RHA geopolymer shows comparatively lower compressive strength as compared to Fly ash geopolymer.