• Title/Summary/Keyword: Paper Sludge

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Kinetics of Thermal Degradation of Waste styrene compound and Paper Sludge Blend (폐 스티렌계수지와 제지슬럿지 Blend의 열분해에 관한 연구)

  • Seul, Soo-Duk;Kim, Nam-Seok;Wang, Seok-Ju;Na, Sang-Do
    • Elastomers and Composites
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    • v.30 no.2
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    • pp.105-111
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    • 1995
  • The thermal decomposition of the paper sludge with poly (acrylonitrile-butadiene-styrene) was using a thermal analysis techniques in the stream of nitrogen gas of 30ml/min at various heating rates from 4 to $20^{\circ}C/min$. The mathmatical, derivative and integral method were used to obtain values of activation energy of decomposition reaction. 1. The values of activation energy evaluated by derivative and Intergral method were consistent with each other very well. 2. The maximum value of heat of decomposition evaluated by DSC method was 10.120cal/g at weight ratio of paper sludge/ABS=20/80. 3. The thermogravimetric trace curve agreed with the theoretical equation.

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SEM Analysis Property of Non-cement Light-weight Matrix according to Type and Mixing Ratio of Alkali Activator (알칼리자극제 종류 및 혼입율에 따른 무시멘트 경량 경화체의 SEM분석 특성)

  • Shin, Jin-Hyun;Kim, Tae-Hyun;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.161-162
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    • 2017
  • As the use of cement increases with the development of modern society along with the increase of buildings, environmental pollution intensifies and researches on industrial byproducts are continuing. Research on blast furnace slag and fly ash as industrial byproducts is increasing, and research on industrial byproducts such as polysilicon sludge and paper ash used in this study is increasing. Blast furnace slag, which is one of the industrial byproducts, has been widely studied as a material used with cement. However, in this study, we fabricated lightweight matrix of polysilicon sludge and paper ash replaced based on blast furnace slag, and performed SEM analysis.

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Pre-treatment Technology of Wastewater Sludge for Enhanced Biogas Production in Anaerobic Digestion (혐기소화에서의 바이오가스 생산 증진을 위한 슬러지 전처리 기술)

  • Kim, Dong-Jin
    • Clean Technology
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    • v.19 no.4
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    • pp.355-369
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    • 2013
  • Economic feasibility is one of the most important factors in energy production from regenerative biomass. From the aspect, biogas from anaerobic digestion of wastewater sludge is regarded as the most economical because of its cheap substrate and additional income from the disposal of waste sludge. Sludge hydrolysis has been regarded as the rate limiting step of anaerobic digestion and many sludge pre-treatment technologies have been developed to accelerate anaerobic sludge digestion for enhanced biogas production. Various sludge pre-treatment technologies including biological, thermo hydrolysis, ultrasonic, and mechanical methods have been applied to full-scale systems. Sludge pre-treatment increased the efficiency of anaerobic digestion by enhancing hydrolysis, reducing residual soilds, and increasing biogas production. This paper introduces the characteristics of various sludge pre-treatment technologies and the energy balance and economic feasibility of each technology were compared to prepare a guideline for the selection of feasible pre-treatment technology. It was estimated that thermophilic digestion and thermal hydrolysis were most economical technology followed by Cell rupture$^{TM}$, OpenCEL$^{TM}$, MicroSludge$^{TM}$, and ultrasound. The cost for waste sludge disposal shares the biggest portion in the economic analysis, therefore, water content of the waste sludge was the most important factor to be controlled.

Drying Characteristics of Plating Sludge by Microwave (마이크로파 가열에 의한 도금슬러지 건조특성)

  • 문경환;손종렬;김덕찬
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.9-15
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    • 1998
  • Microwave heating and drying processes have been well established in various industrial applications. Feasibilities of successful application of microwave drying to many material have been shown on the laboratory or pilot-plant scale. The microwave drying behavior of plating sludge are considered in this paper. The plating sludge containing 70%, 80% and 90% water exposed to microwave power at 2,450 MHz, 700W. An experimental microwave drying apparatus was designed and constructed to monitor weight loss during drying. By studying the drying characteristic curve, the moisture in sludge was almost classified into two categories : free moisture and intestinal moisture. And the critical moisture contents at which the drying rate ceases to be constant were from 10.1 to 10.5%. A simple drying model is proposed which may be used to describe drying behavior of plating sludge. The constant rate and the falling rate periods in microwave drying were addressed separately. From the eqation of constant rate period the drying rate constants decreased exponentially with increasing depth. Microwave heating compared with conventional heating offered higher heating rates from 9 to 16 times. Therefore, microwave drying process can be effective in removing moisture from plating sludge.

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Effect of Coagulation and Homogenization on the Dissolved Air Flotation and Sedimentation of Bulking Sludge (응집과 균질화가 팽화슬러지의 용존공기부상과 침전에 미치는 영향)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.33 no.1 s.94
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    • pp.68-74
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    • 2007
  • The objective of this study is to examine the effect of the coagulation and homogenization in bulking sludge thickening of paper manufacturing plant using DAF(Dissolved Air Flotation) and gravitational sedimentation. The effects of parameters such as dosage of coagulant and homogenization time were examined. The results showed that DAF and sedimentation was affected aluminum sulfate and anion polymer coagulant differently. At the optimum dosage of aluminum sulfate, thickening efficiency of DAF and sedimentation process were increase 1.25 time and 2.02 time, respectively. At the optimum dosage of anion polymer coagulant, thickening efficiency of DAF process was increase 1.35 time, but thickening efficiency at sedimentation was 1.06 time. When anion polymer coagulant of 0.5 mg/l was added in DAF process, water content of sludge was decreased from 96.6% to 90.7% in dewatering process using Buchner funnel test device. After homogenization(20500 rpm, 10 min), Sauter mean diameter of sludge floc was decreased from 631 ${\mu}m$ to 427 ${\mu}m$, however increase of flotation efficiency by DAF was only 1.09 time.

Pyrolysis Characteristics of Sludge Discharged from Paper Mill Process (제지공정에서 발생하는 슬러지의 열분해 특성)

  • Ko, Jae-Churl;Kim, Seung-Ho;Park, Young-Koo;Jeon, Jea-Yeoul;Kim, Jin-Ho;Park, Joon-Seok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.1
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    • pp.80-87
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    • 2009
  • This research was conducted to evaluate pyrolysis characteristics of the sludge discharged from paper mill process with sintering temperature. The sludge was composed of 70.72% of moisture, 9.52% of volatile solids, and 19.76% of ash, respectively. The sludge contained high 66.40% of $Fe_2O_3$ and CaO(15.80%), $Al_2O_3$(9.42%), and $SO_3$(3.75%) components, and minor $SiO_2$, $Na_2O$, and $Cr_2O_3$ were also contained in it. The other components except $Fe_2O_3$ and $Cr_2O_3$ were slightly decreased with increase of sintering temperature. Specific surface area of the sludge before sintering was $130m^2/g$ and ones after sintering at $400^{\circ}C$ and $700^{\circ}C$ were $114m^2/g$ and $33m^2/g$ respectively. Specific surface area of sludge was decreased with increase of sintering temperature. From the result of TG-DTA, it was shown that weight of the sludge was decreased by moisture and organic loss until $600^{\circ}C$ and decreased by volatilization of metal components and additional combustion of carbon until $800^{\circ}C$.

The Evaluation of Scum Recyclability from Waste Sludge in Linerboard Mills (라이너지 제조공정 탈수 슬러지의 scum 재이용 가능성 평가)

  • Kang, Kwang-Ho;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.3
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    • pp.42-47
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    • 2008
  • For the purpose of reduction of production cost in the industrial papermaking process, the use of waste paper has been more and more increased as a fibrous raw material, and the closed system of white water became closed more than ever. "Scum" indicates the floated sludge by a flotation during primary wastewater treatment process in paper mills. If the scum is used as the raw material, it could reduce both the raw material and solid waste treatment cost with even small quantity. In this study, the element survey and the toxicity measurement was carried out for recycling scum. A load factor of stock preparation process in paper mills was measured by somerville screen. Physical properties of paper sheet containing the accepted scum from the stock of AOCC or KOCC were evaluated. The result of this study shows that recycling scum has potential to be used in paper making system. It also might be able to reduce the required energy used by the pressing or drainage process, the raw material cost, and solid waste treatment cost due to the recycling of scum.

Fundamental Properties of Recycled Cold Asphalt Mixtures with Recycled Sludge and Recycled Glass Aggregate (순환 슬러지 및 순환 유리골재를 사용한 순환 상온아스팔트 혼합물의 기초특성)

  • Lee, Hoo-Seok;Kang, Suk-Pyo;Kang, Hye-Ju;Lee, Min-Hi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.302-309
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    • 2020
  • This paper is a basic study for applying the dried recycled sludge of waste sludge generated in construction waste intermediate treatment facility and the crushed recycled glass aggregate of waste glass bottles that cannot be recycled to the recycled cold asphalt mixtures. This paper reviewed the characteristics of recycled cold asphalt mixtures using recycled sludge and recycled glass aggregate. As a result, as contents of recycled sludge and recycled glass aggregate increased, the Marshall stability, indirect tensile strength, and tensile strength ratio of the recycled cold asphalt mixtures decreased, but flow and void ratio of that increased.

Effects of Paper Mill Sludge in submerged Soil (제지(製紙)슬러지의 답토양(畓土壤) 시용효과(施用效果))

  • Choi, Jong Woo;Jo, Jeong Rye;Lee, Kyu Seung;Kim, Moon Kyu
    • Korean Journal of Agricultural Science
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    • v.19 no.2
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    • pp.187-193
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    • 1992
  • The effects of continuous restoration of sludge into the reclamating paddy soil and leaching test of sludge components by soil column were investigated. 1. The contents of nitrogen, phosphorus, potassium, C.E.C. and organic matter(O.M.) were increased in/on the paddy soil treated with paper mill sludge than non-treated. 2. Humic layer depth recognized by color showed the non-treated(10 cm), second year(15 cm) and third year(20 cm), respectively. 3. The effects of sludge treatment showed in the contents of O.M. such as non-treatment(0.9 %) < second year(1.39 %) < third year(1.75 %) in 10 cm depth. 4. All components in soil tested with column were increased by holding capacity of sludge, and the contamination effects of soil and ground water were not found by leaching test.

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Effects of Paper Sludge Application on the Chemical Properties of Paddy Soil and Growth of Paddy Rice;IV. Effects of Paper Sludge Application on the Seasonal Variations of Volatie Lower Fatty Acids in Paddy Soil (제지(製紙)슬러지의 시용(施用)이 논 토양(土壤)의 화학성(化學性)과 수도생육(水稻生育)에 미치는 영향(影響);IV. 슬러지시용(施用)이 토양중(土壤中) 휘발성저급지방산변화(揮發性低級脂肪酸變化)에 미치는 영향(影響))

  • Heo, Jong-Soo;Kim, Kwang-Sik;Ha, Ho-Sung
    • Korean Journal of Environmental Agriculture
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    • v.7 no.1
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    • pp.34-42
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    • 1988
  • To investigate the effects of paper sludge on seasonal variations of volatile lower fatty acids in paddy soil, paper sludge was applied to pots at the rate of either 300, 600, 900 or 1,200 kg/l0a which was either preadjusted at a C/N ratio of 30 : 1 or not adjusted. The decomposition rate of paper sludge, the evolution of $CO_2$, and the fractions of volatile lower fatty acids in the soil were determined. The results are summarized as follows: 1. Paper sludge was decomposed to $35{\sim}44%$, and its C/N ratio was $55{\sim}82$, respectively, at 120 days after treatment. 2. The evolution of $CO_2$, in the soil was proportional to the amount of paper sludge added. Significant positive correlations were observed the $CO_2$ evolution was compared with the decomposition rate of paper sludge, and volatile fatty acid contents in soil. 3. Acetic, propionic, butyric, i-butyric, valeric and i-valeric acids were identified in all the soils investigated. The content of the total volatile fatty acids in the soil increased with as the application of paper sludge increased. The formation of the acids was the highest at 25 days after treatment, and thereafter the contents of the acids decreased as time elapsed. 4. The volatile fatty acids in the soil inhibited the growth of paddy rice in early stages. The contents of acetic, propionic and i-valeric acids in the soil negatively, correlated with the uptake of N, $P_2O_5$, $K_2O$, CaO, MgO and $SiO_2$ in the paddy rice at 25 days after transplantation. In addition, the uptake of $P_2O_5$ and CaO in the paddy rice negatively correlated with the content of butyric acid in the soil. 5. The content of total volatile fatty acids positively correlated with the content of $Fe^{++}$ and $Mn^{++}$ in the soil at 25 days after transplantation. A significantly positive correlation was observed between $Fe^{++}$ and acetic acid contents in the soil.

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