• Title/Summary/Keyword: PVD

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Electrochemical Properties of PVdF Gel Polymer Electrolyte with Plasticizer for Lithium/sulfur Battery (리튬 유황 전지용 PVdF 겔 고분자 전해질의 가소제에 따른 전기화학적 특성 평가)

  • Ryu, Ho-Suk;Kim, Jong-Seon;Kim, Dong-Ju;Kim, Dong-Yeon;Kim, Ic-Pyo;Ahn, Hyo-Jun;Kim, Ki-Won;Ahn, Jou-Hyeon;Lee, Gun-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.10 no.3
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    • pp.213-218
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    • 2007
  • In order to find out proper PVdF gel polymer electrolyte for Li/S battery, we investigated PVdF gel polymer electrolytes with various glyme type plasticizer such as polyglyme, tetraglyme, triglyme. The organic solvents as triglyme, tetraglyme, polyglyme (Mn = 250, 500) has different chain length of ethylene oxide(EO) in solvent of glyme system. ionic conductivity decreased as increasing chain length of EO in plasticizers. Ionic conductivity of PVdF gel electrolyte with tetraglyme, triglyme, polyglyme (Mn = 250, 500) at room temperature was $5{\times}10^{-4},\;3{\times}10^{-4},\;6{\times}10^{-5},\;3{\times}10^{-5}\;S/cm$, respectively. Li/S cell with PVdF gel polymer electrolyte using tetraglyme plasticizer had low interfacial resistance and the highest initial discharge capacity of 1232 mAh/g of active sulfur, which was about 70% utilization of theoretical value.

High Capacity Steganographic Method (고용량 스테가노그래픽 방법 연구)

  • Kim, Ki-Jong;Jung, Ki-Hyun;Yoo, Kee-Young
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.9 no.5
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    • pp.155-161
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    • 2009
  • This paper proposes a high capacity data hiding method using modulus function of pixel-value differencing (PVD) and least significant bit (LSB) replacement method. Many novel data hiding methods based on LSB and PVD methods were presented to enlarge hiding capacity and provide an imperceptible quality. A small difference value for two consecutive pixels is belonged to a smooth area and a large difference one is located on an edge area. In our proposed method, the secret data are hidden on the smooth area by the LSB substitution method and PVD method on the edge area. From the experimental results, the proposed method sustains a higher capacity and still a good quality compared with other LSB and modified PVD methods.

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Preparation and Characterization of Microporous PVdF Membrane for Li-ion Rechargeable Battery (이차전지용 미세다공성 PVdF 분리막의 제조와 물성)

  • Nam, Sang-Yong;Yu, Dae-Hyun;Jeong, Mi-Ae;Rhim, Ji-Won;Byun, Hong-Sik;Jeong, Chul-Ho;Lee, Young-Moo;Seo, Myung-Su
    • Membrane Journal
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    • v.17 no.3
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    • pp.233-243
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    • 2007
  • In this study, a separate. which is a microporous membrane based on poly(vinylidene fluoride)(PVdF) was prepared by phase inversion method. Being prepared by dissolving the PVdF in the N,N'-dimethylformamide(DMF) with mechanical stirring, the homogenous casting solution was cast onto a clean glass plate. Pore size and porosity of the membranes were controlled by changing preparation condition. The highest porosity of the membrane was 78.6%. The mechanical property of the membrane was determined by using an universal testing machine(UTM). The morphology of the membrane was investigated by scanning electron microscopy(SEM). The cross-section of the membrane shows sponge-like small micro-pores.

Preparation of EMI Shielding Sheet by PVD Method and Its Characteristic of EMI Shielding Efficiency (PVD법을 이용한 전자파 차폐용 시트 제조 및 차폐효율 특성)

  • Chae, Seong-Jeong;Hong, Byung-Pyo;Lee, Byoung-Soo;Byun, Hong-Sik
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.527-531
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    • 2010
  • The optimized sheet for EMI shielding was prepared by metal power with Fe series. Then various metal powders were deposited on the sheet by PVD method. Moreover, the PVdF nanofiber membrane was used to compare the characteristic of EMI shielding efficiency of various metal powders. The electrical property was measured by the 4-point probe method. The result from EDS confirmed that the metal powder existed on the sheet. EMI shielding efficiency was analysed by EMI shielding measurement apparatus. The lowest electrical resistance, $641.95{\Omega}{wcdot}cm$, was obtained with $1000\;{\AA}$ deposition of Cu on the sheet. It was revealed that the EMI shielding efficiency increased with increase of the metal deposition thickness. The sheet deposited by Cu with $1000\;{\AA}$ showed the highest EMI shielding efficiency, 32.5 dB.

Preparation and Characterization of PVdF-HFP Microporous Membranes for Li-ion Rechargeable Battery (Poly(vinylidene fluoride-hexafluoropropylene)를 이용한 이차전지용 미세다공성 분리막의 제조와 물성)

  • Nam, Sang-Yong;Yu, Dae-Hyun;Jeong, Mi-Ae;Rhim, Ji-Won;Byun, Hong-Sik;Yoo, Hyun-Oh;Kim, Jong-Man;Seo, Myung-Su
    • Membrane Journal
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    • v.17 no.4
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    • pp.359-368
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    • 2007
  • The copolymer membranes, poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) were prepared by phase inversion method using as an additive with N,N-dimethylformamid as a solvent. The pores are generated during the solvent and non-solvent exchange process in the coagulation bath filled with non-solvent (distilled water). The highest porosity of the membrane was 60%. The surface and cross-section of the membranes was observed with a scanning electron microscopy (SEM). The mechanical property of the membrane was determined by using an universal testing machine (UTM). Tensile strength of measured membranes is presented the maximum 6.57 MPa at 30 wt% of PVdF-HFP.

Preparation and Characterization of Chemical Gel Based on [Epoxy/PEG/PVdF-HFP] Blend for Lithium Polymer Battery Applications ([Epoxy/PEG/PVdF-HFP] 복합체를 이용한 리튬고분자전지용 화학겔의 제조 및 분석)

  • Kim, Joo-Sung;Seo, Jeong-In;Bae, Jin-Young
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.544-550
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    • 2009
  • In this study, we have designed [Epoxy/PEG] polymer gel electrolyte systems by thermal curing the mixtures of epoxy, PEG, imidazole catalyst, and a plasticizer of 1:1 ethylene carbonate and propylene carbonate in the presence of $LiPF_6$ salt. In order to enhance the poor mechanical property of the Corresponding [Epoxy/PEG] gel electrolyte PVdF-HFP was incorporated into the system. The ionic conductivities of the polymer gel electrolytes were related to the amount of PVdF-HFP in blends as well as the amount of liquid electrolyte. The optimized gel system showed room-temperature conductivities of $2.56\times10^{-3}S/cm$.

A Study to Provide Real-Time Freeway Precipitation Information Using C-ITS Based PVD (C-ITS 기반 PVD를 활용한 실시간 고속도로 강수정보 수집에 관한 연구)

  • Kim, Ho seon;Kim, Seoung bum
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.20 no.6
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    • pp.133-146
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    • 2021
  • Providing weather information on roads today means that the road weather conditions near weather observation points are presented to road managers and road users. These weather observation points are managed by the Korea Meteorological Administration. However, it is difficult to provide accurate weather information due to physical limitations such as the presence of precipitation collection points, distance to weather information provision roads, and the presence of mountains. Therefore, this study intends to perform a comparative analysis by time zone and administrative dong provided by the Meteorological Administration using the wiper information among the information contained in the PVD(Probe Vehicle Data) collected from the highway C-ITS project. As a result of the analysis it was possible to detect rainfall even in the event of local rainfall and rainfall over a long period of time and the higher the cumulative precipitation per hour, the higher the probability of coincidence. This study is meaningful because it used PVD to solve the limitations of the existing road weather information provision method and suggested utilization plan for PVD.

Laboratory Test and Field Study of Soft Ground Improvement Effect by Using Various PVDs (실내실험과 현장실험을 통한 다양한 PVD의 연약지반개량효과)

  • Shin, Eun-Chul;Nazarova, Zhanara
    • Journal of the Korean Geosynthetics Society
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    • v.7 no.2
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    • pp.15-21
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    • 2008
  • The advantages of prefabricated vertical drains over conventional sand drains include their relatively low costs, less disturbance to the soil mass, the easinees of installation, and their flexibility which ensures the integrity of the drains during installation. This study tested the change of discharge capacities with respect to the hydraulic gradients for each lateral pressure. From the test results, as increases the overburden pressure, the clay soil is being consolidated, and also lateral pressure to the PVD specimen is increased. Therefore, the discharge capacity is decreased. The size of opening space in the core of PVDs is proportionally related to the discharge capacity. The numerical analysis was performed with utilizing computer simulation with considering field conditions. The results of numerical analysis are compared well with the field measurements.

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Stochastic cost optimization of ground improvement with prefabricated vertical drains and surcharge preloading

  • Kim, Hyeong-Joo;Lee, Kwang-Hyung;Jamin, Jay C.;Mission, Jose Leo C.
    • Geomechanics and Engineering
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    • v.7 no.5
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    • pp.525-537
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    • 2014
  • The typical design of ground improvement with prefabricated vertical drains (PVD) and surcharge preloading involves a series of deterministic analyses using averaged or mean soil properties for the various combination of the PVD spacing and surcharge preloading height that would meet the criteria for minimum consolidation time and required degree of consolidation. The optimum design combination is then selected in which the total cost of ground improvement is a minimum. Considering the variability and uncertainties of the soil consolidation parameters, as well as considering the effects of soil disturbance (smear zone) and drain resistance in the analysis, this study presents a stochastic cost optimization of ground improvement with PVD and surcharge preloading. Direct Monte Carlo (MC) simulation and importance sampling (IS) technique is used in the stochastic analysis by limiting the sampled random soil parameters within the range from a minimum to maximum value while considering their statistical distribution. The method has been verified in a case study of PVD improved ground with preloading, in which average results of the stochastic analysis showed a good agreement with field monitoring data.