• Title/Summary/Keyword: PVC film

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Analysis of Surface Properties of PVC Thin Film according to Addition of Non-solvent to PVC-THF Solution (PVC-THF 용액에 비용매 첨가에 따른 PVC 박막의 표면 특성 분석)

  • Lee, Seung Gyu;Moon, Je Cheol;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.367-372
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    • 2022
  • The effect of the addition of a polyvinylchloride (PVC) non-solvent to a PVC-tetrahydrofuran (THF) solution on the surface properties of the PVC thin film was analyzed. The non-solvents used were composed of alcohol-based and non-alcoholic ones. Surface morphologies of PVC thin films according to the addition of the non-solvent were compared. In addition, the hydrophobic properties relying on the surface characteristics were compared. The micro-bubbles generated in the preparation of PVC-THF solution affected the surface morphology of the thin film. In order to implement the normal surface physical properties of the coating thin film at the relatively high concentration of PVC-THF solution, the selection of appropriate drying method was required. When an alcohol-based non-solvent was added, a PVC thin film having a granular porous surface was obtained and exhibited super hydrophobic properties. The volume ratio of the PVC-THF solution to the non-solvent affects the surface shape of the coating thin film. The larger the amount of non-solvent was added, the more advantageous it was to form a super hydrophobic PVC thin film.

Dry Separation of PVC Film from Plastic Film Mixture by Using Air Table

  • Song, Young-Jun;Hiroki Yotsumoto;Lee, Gye-Seung
    • Resources Recycling
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    • v.11 no.1
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    • pp.37-42
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    • 2002
  • This study was conducted in order to remove Poly vinyl chloride(PVC) from the waste plastic film mixture. The fittings of Air Table was modified to increase the separation efficiency of PVC and PE(poly ethylene). PE and PVC was successfully separated from PVC-PE film mixture with the yield of PE 90% or more and with his grade of 99% or more, using the improved Air Table. The details of the separation condition and results will be discussed in this paper. Dry separation, Waste plastic film, PVC, Air Table. The details of the separation condition and results will be discussed in this paper.

Effect of the Addition of Propanol to PVC Solution on the Structure of Thin Film and its Surface Property (프로판올 첨가에 따른 PVC 용액의 박막 형성과 표면 특성에 미치는 영향)

  • Park, Jae Nam;Shin, Young Sik;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.35-39
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    • 2015
  • Polyvinylchloride (PVC) thin films having a microporous structure could be prepared by using the solubility difference in solvents. PVC thin film with a water contact angle of $150^{\circ}$ or more was obtained from the PVC solution consisting of the mixture of tetrahydrofuran as a solvent and propanol as a non-solvent. In the drying process of dip-coated PVC film, the increase of drying temperature reduced the tendency of roughened surface, which led the decrease of surface hydrophobicity. As the addition of propanol in the solution with 1 wt% PVC increased, the uniformity of surface roughness was improved. In the case of oxygen plasma treatments, even though the surface structure of PVC thin film was not notably changed, the surface property of the film was changed from the super-hydrophobicity to hydrophilicity as a function of the plasma exposing time.

Dry separation of PVC film from waste plastic film mixture using Air Table

  • Song, Young-Jun;Hiroki Yotsumoto;Eisetsu Oi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.734-737
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    • 2001
  • A study was conducted in order to remove PVC from the waste plastic film mixture. The fittings of Air Table was modified to increase the separation efficiency of PVC. By using the improved air table, the PE and PVC was successfully separated from PVC-PE film mixture with the yield of PE 90% or more and with the content of PVC in PE 1% or less. The detail of the separation condition and result will be discussed in this paper.

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The Experimental Study of Radiant Cooling Test System under Different Covers (복사냉각 시스템에서 커버의 영향)

  • Byun, Ki-Hong;Smith, Theodore F.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.11
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    • pp.797-802
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    • 2007
  • The effects of window cover on the performance of the plate type radiant cooling test system are studied. The cover materials tested are 2mm, 1mm, 0.7mm glass, Cokin 007 filter, and PVC film. The measurements are performed during the September nights of 2005 at the rooftop of the building in Seoul. The equivalent height of the building is about a building with twelve floors. The radiant cooling performance of the black painted and aluminum film coated plate are compared under no cover condition. Also the results are compared when the system has cover over the plate. In general, the covers reduce the radiant cooling temperature differences during the nighttime. Among these covers, the PVC film cover shows the best performance. In some cases, the plate with PVC film cover shows lower temperatures than the system without cover.

Electro-optical Properties of PVC/Nematic Liquid Crytal Composite Films (PVC/Nematic 액정복합막의 전기광학특성)

  • Lee, Jong-Cheol;Kim, Byeong-Gyu
    • Korean Journal of Materials Research
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    • v.3 no.4
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    • pp.388-394
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    • 1993
  • The state of aggregation and optical contrast of poly(vinyl chlorich, )(PVC)!nematic liquid crystal(LC) composite film liave been studied for a wide range(30~70 wt% LC)of film composition. In addition. effects of temperature, frequency and voltage of the applied AV electric field on the film transmittance have heen measured for a film containing (6O wt % I, C, which showed maximum optical contrast. For this particular composition of film, tlw thn'shold voltage was smalkr than .40$V_{p-p}$ at I kHZ, $25^{\circ}C$, and the rise time and decay time were smalle, r than l0Oms at 100$V_{p-p}$, I kHz, and $25^{\circ}C$.

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Temperature Dependence of Oxygen Diffusivity in the PVC Film on Gold Electrode Using Steady-State Rotating Disk Electrode Technique and Modulated Electrohydrodynamic Impedance Technique (정상상태 회전원판전극(RDE) 방법과 유체역학적 요동에 의한 전기화학적(EHD) 임피던스방법을 이용한 금전극표면에 형성된 PVC 피막내 산소확산계수의 온도의존성에 대한 연구)

  • Yeon Jei-Won;Pyun Su-Il;Lee Woo-Jin;Choi In-Kyu
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.49-56
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    • 2000
  • In the present we.k, temperature dependence of oxygen diffusivity in the polyvinyl chloride (PVC) film $D_f$ formed on gold electrode was investigated using steady-state rotating disk electrode (RDE) technique and modulated electrohydrodynamic (EHD) impedance technique. Both the diffusion rate defined as the ratio of oxygen diffusivity in the PVC film to the film thickness $D_f/\delta_f$ and the time constant $\delta_f^2/D_f$ for oxygen diffusion through the PVC film were obtained from plot of the limiting current versus disk rotation speed and from filing the EHD impedance spectra experimentally measured to those theoretically calculated on the basis of the diffusion equation for mass transport through the non-conductive and porous film, respectively. By combining measured $D_f/\delta_f$ with $\delta_f^2/D_f$, we determined $\delta_f\;and\;D_f$ at room temperature separately. As temperature increased, it appeared that the $D_f$ value measured for the PVC film-covered gold RDE was enhanced more rapidly than that $D_s$ value in the solution measured for the PVC film-free gold RDE. This means that the pores glowing with increasing temperature act as effective diffusion paths within the film. The present in-situ steady-state and modulated EHD measurements prove to be effective for determining $\delta_f\;and\;D_f$, separately and at the same time the porosity of the PVC film at temperatures below glass temperature $T_g$ of the film.

Quality Changes in Mushrooms (Agaricus bisporus) due to Their Packaging Materials during Their Storage (포장재에 따른 양송이버섯의 저장 중 품질변화)

  • Lee, Da-Uhm;Chang, Min-Sun;Cho, Sun-Duk;Jhune, Chang-Sung;Kim, Gun-Hee
    • Food Science and Preservation
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    • v.20 no.1
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    • pp.7-13
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    • 2013
  • Mushrooms have a shorter shelf-life than most vegetables because of their very high respiration rates, sensitivity to enzymatic browning and susceptibility to microbial spoilage. This study was conducted to investigate effects of various packaging materials and precooling on the quality of mushrooms (Agaricus bisporus). Mushrooms were precooled at $4^{\circ}C$ for three hours and packaged using the following packaging materials; 1) polyethylene (PE) film bags of 0.03 mm thickness, 2) polypropylene (PP) film bags of 0.03 mm thickness, and 3) polystyrene (PS) tray+polyvinyl chloride (PVC) wrapper. The physiological changes (weight loss, gas composition, color, firmness, and sensory evaluation) associated with postharvest deterioration were monitored for 17 days at $10^{\circ}C$. The results showed that the PP film bag maintained quality of mushrooms most effectively, especially PP film bags inhibited decreasing firmness. The samples also exhibited smaller decreases in weight loss rate (0.57%) and Hunter L value (84.44) than PS tray+PVC wrapper (7.73%, 82.19) and PE film bags (0.89%, 82.96). Sensory evaluation level in all samples remained relatively constant during the first 5 days of storage. However, PE film bags and PS tray+PVC wrapper showed lower score of flavor, texture and color than PP film bags after 8 days of storage. This study suggested that PP film bag packaging effectively extends shelf-life of mushrooms during storage.