• Title/Summary/Keyword: PVC

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Effect of Acrylonitrile Content on the Glass Transition Temperature and Melt Index of PVC/SAN Blends

  • Liu Wang;Kim Hwan-Chul;Pak Pyong-Ki;Kim Jong-Chun
    • Fibers and Polymers
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    • v.7 no.1
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    • pp.36-41
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    • 2006
  • PVC and SAN are often mixed to compensate for the disadvantages of each polymer. Miscibility and thermal stability of PVC/SAN blend were investigated in this study by blending SAN polymer having 20, 24, 28, 32 % of acrylonitrile contents. Two polymers were mixed using a melt blending method with a single screw extruder. DSC thermogram was used to evaluate miscibility of the two polymers. SAN having 24 % of acrylonitrile showed the best miscibility with PVC. In order to evaluate degradation behavior, blended polymer was heat treated in DSC furnace and glass transition temperature was measured consecutively. Glass transition temperature increased continuously with annealing time due to degradation and cross-linking of polymer chains. Melt index of blended polymer was always higher than that of PVC.

Dry separation of PVC film from waste plastic film mixture using Air Table

  • Song, Young-Jun;Hiroki Yotsumoto;Eisetsu Oi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.734-737
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    • 2001
  • A study was conducted in order to remove PVC from the waste plastic film mixture. The fittings of Air Table was modified to increase the separation efficiency of PVC. By using the improved air table, the PE and PVC was successfully separated from PVC-PE film mixture with the yield of PE 90% or more and with the content of PVC in PE 1% or less. The detail of the separation condition and result will be discussed in this paper.

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Poly-${\varepsilon}$-caprolactone(PCL) / Polyvinyl chloride(PVC) 블렌드의 기계적 성질 및 생분해성

  • Seo, Hae-Jeong;Ha, Gi-Ryong;Gang, Seon-Cheol
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.379-380
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    • 2002
  • Biodegradable polymers have been regarded as a good alternative to solve the plastic waste problems caused by nondegradable synthetic polymers such as polyethylene and polystyrene. In the soil environment, plastics are mainly being used as a mulching film for agricultural purposes. In this research, the miscibility, tensile properties and biodegradation effect of poly-${\varepsilon}$-caprolactone(PCL) with polyvinyl chloride(PVC) have been studied. After 8 weeks of biodegradation, PCL/PVC(9/91) blend surface showed newly formed many holes. Consequently, the antiplasticization phenomenon and biodegradation were observed in the PCL/PVC blends. It was confirmed that a test for general biodegradation condition can be applied to plastic biodegradation in soil.

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Characteristics of Enzyme Sensors using Carboxylated PVC for Immobilizing Penicillinase (Carboxylated PVC에 페니실리나제를 고정한 효소 센서의 특성)

  • Kim, Ki-Myo;Kim, Young-Hak;Lee, Eun-Yup;Hur, Moon-Hye;Ahn, Moon-Kyu
    • YAKHAK HOEJI
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    • v.40 no.1
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    • pp.72-77
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    • 1996
  • Penicillin sensor was manufactured by immobillizing penicillinase with glutaraldehyde on the $H^+$-selective membrane based on PVC-COOH-TDDA. This membrane was not inter fered by $K^+$ ion in Pc-G potassium salt. When enzyme was immobilized with glutaraldehyde, the PVC-COOH matrix was more effective than PVC matrix. Calibration curve calculated from Nernst equation was not linear. But potential was relative to concentration of Pc-G. And maximal potentiometric velocity was also relative to concentration of Pc-G. Therefore, it may be applied to Michaelis-Menten equation. The penicillin sensor was useful for determination of Pc-G at concentration of 0.1~10mM level.

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A Study on Property Change with Mixing Ratio in NBR/PVC Composites

  • Li, Xiang Xu;Jeong, Hyung Seok;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.48-51
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    • 2018
  • 10, 20, 30, and 40% of polyvinyl chloride (PVC) were added to nitrile butadiene rubber (NBR) to modify the latter. The NBR/PVC composites containing pure NBR were synthesized to investigate properties, such as crosslinking density, hardness, tensile strength, abrasion resistance, heat resistance, solvent resistance, and filler dispersion. The experimental result revealed a decrease in crosslinking density and heat resistance with increase in the PVC content. In contrast, addition of PVC to NBR resulted in enhancement of hardness, tensile strength, solvent resistance, and filler dispersion.

Improvement of the electrochemical properties of low temperature synthesized carbon for anode materials in lithium-ion batteries (리튬이온전지의 음극 재료로서 저온합성탄소의 전기화학적 특성의 향상)

  • 이헌영;장석원;신건철;이성만;이종기;이승주;백홍구
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.1
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    • pp.55-61
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    • 2000
  • The electrochemical properties of hard carbon anodes in lithium ion batteries were improved by carbon coating using polyvinyl chloride (PVC). The reduction in irreversible capacity occured and the reversible capacity increased. It is suggested that the PVC carbon coating modifies the surface of hard carbon and reduces the surface reaction with species from air. The degree of the graphitization of PVC carbon was controlled by an addition of Ni, and the effect of the amount of Ni addition on the electrochemical properties was discussed.

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A study on the Corona Electrification Phenomena for Polyvinyl chloride (PVC) (폴리염화비닐(PVC)의 코로나 대전현상에 관한 연구)

  • 박구범;황명환;조기선;이덕출;임헌찬
    • Journal of the Korean Society of Safety
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    • v.7 no.2
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    • pp.57-62
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    • 1992
  • In this thesis, the electrification phenomenon was studied by measurement of charging current and discharging current in polymers when the carriers generated by corona discharge were supplied to the surface of polymers. Corona charging current of PVC, polar and noncrystalline polymer, was larger than that of nonpolar and amorphous polymers. Corona charging current on the specimen of naked upper surface (CIM) was larger than charging current on the specimen of electrode made. Carrier injection differed from interfacial phase of polymer surFace. The transfer phenomenon vaned with chemical structure of polymer and then the polar effect of PVC was remarkable because of large electron affinity of Cl. In the characteristics of discharging current of PVC, the abnormal current was observed. It was supposed that this phenomena presented the trap of injected carriers in PVC and that static electricity phenomenon was generated by trap.

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Assessment of Premature Ventricular Contraction Arrhythmia by K-means Clustering Algorithm

  • Kim, Kyeong-Seop
    • Journal of the Korea Society of Computer and Information
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    • v.22 no.5
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    • pp.65-72
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    • 2017
  • Premature Ventricular Contraction(PVC) arrhythmia is most common abnormal-heart rhythm that may increase mortal risk of a cardiac patient. Thus, it is very important issue to identify the specular portraits of PVC pattern especially from the patient. In this paper, we propose a new method to extract the characteristics of PVC pattern by applying K-means machine learning algorithm on Heart Rate Variability depicted in Poinecare plot. For the quantitative analysis to distinguish the trend of cluster patterns between normal sinus rhythm and PVC beat, the Euclidean distance measure was sought between the clusters. Experimental simulations on MIT-BIH arrhythmia database draw the fact that the distance measure on the cluster is valid for differentiating the pattern-traits of PVC beats. Therefore, we proposed a method that can offer the simple remedy to identify the attributes of PVC beats in terms of K-means clusters especially in the long-period Electrocardiogram(ECG).

Comparison of PVC Detecting Methods with ECG Using Descending Slope Tracing Waves and Form Factor (하강 기울기 추적파와 Form Factor를 이용한 심전도 조기심실수축의 검출 방법의 비교)

  • Ju, Jangkyu;Lee, Ki Young
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.1 no.3
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    • pp.21-26
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    • 2008
  • In this paper, we extracted descending slope tracing waves (DSTW) and form factors (FF), and compared the detecting results of premature ventricular contraction (PVC) which were derived from DSTW and FF in order to find an efficient method. The 2nd. derivatives and DSTW were employed to extract correct R-waves from ECG. To evaluate extracting methods, ECGs including PVCs from MIT/BIH database were used.

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Determination of Nitrate in Chromium Plating Solution with Nitrate-Selective Electrodes

  • 강유라;이원;허황;차근식;남학현
    • Bulletin of the Korean Chemical Society
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    • v.16 no.3
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    • pp.221-226
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    • 1995
  • A method for determining nitrate in post treatment chromium plating solutions with PVC-based nitrate-selective electrodes is described. PVC-based nitrate-selective membranes which contain TDMANO3 ion-exchanger in PVC/NPOE, PVC/DOA or PVC/DBP matrices, and a commercially available Corning electrode (No. 476134) have been compared in respect of their detection limits, response slopes, selectivities at various pHs, and dynamic response to the hydrochromate ion in basic condition. The PVC/DBP/TDMANO3 membrane electrode was chosen as the ISE detector for the determination of nitrate in the presence of hydrochromate interference. The amount of nitrate in real post treatment chromium plating solution could be determined successfully with this electrode in both static and flow-injection measurements when the sample was properly diluted with an alkaline buffer.