• Title/Summary/Keyword: PVAm (polyvinylamine)

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Effect of PVAm Application for Fine Paper on Effectiveness of Optical Brightening Agent (PVAm 적용이 백상지의 형광증백제 발현효율에 미치는 영향)

  • Cho, Byoung-Uk;Won, Jong Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.23-29
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    • 2016
  • Effects of cationic polyvinylamine (PVAm) dry strength agent on effectiveness of optical brightening agent (OBA) during fine papermaking and the mechanism for brightness reduction of paper by PVAm was investigated by UV/Vis spectroscopy and turbidity measurement of OBA solution with PVAm. It was shown that PVAm reduced brightness of paper while opacity was not varied and tensile strength of paper was increased. Tetra-type OBA solution showed the peaks around the wavelength of 280 nm and 330 nm and the increase in the OBA concentration increased the UV absorbance in all wavelength. Addition of PVAm into the OBA solution decreased the UV absorbance at 280 nm. Turbidities of OBA and PVAm solutions were close to zero, respectively, while the turbidity value increased for the mixed solution of OBA and PVAm in various mixing ratios and the highest value was obtained when the mixing ratio of PVAm and OBA was 5:5, meaning that cationic PVAm formed complex with anionic OBA. In conclusion, cationic PVAm could form a complex with anionic OBA and that reduced UV absorbance, resulting in the reduced brightness of paper.

Effect of Dual Polymer System using Polyvinylamine for Paper Strength (Polyvinylamine을 이용한 Dual Polymer System의 지력 증강 효과)

  • Choi, Jae-Hoon;Ryu, Jeong-Yong;Kim, Bong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.46-53
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    • 2015
  • Paper strengthening system of PVAm (polyvinylamine) has been used with strong negative charge polymer for electrostatic neutralization due to strong positive charge of PVAm. Recently, because of the controversy caused by the possibility of remaining PAM monomers in white water, a search for paper strength agent that can substitute for PAM was suggested. Therefore, this study was carried out to evaluate a dry strength polymer of PVAm. Starch and CMC were used as a substitute for PAM. The dual polymer system of PVAm and anionic charge control agent such as anionic starch or CMC (carboxy methyl cellulose) were found to be very effective as strength agent compared to the chemicals based on acrylamide.

Strength Improvement of Linerboard by impregnation with PVAm (PVAm 함침에 의한 라이너지 강도 향상)

  • Kim, Hyuk-Jung;Won, Jong-Myoung;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.1
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    • pp.58-64
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    • 2012
  • As a first step to apply PVAm (polyvinylamine) on packaging paper by surface treatment, three types of linerboards were impregnated with PVAm solution. The effect of PVAm pick-up on strength properties of linerboard was investigated. The pick-up of PVAm was controlled by varying concentration of PVAm solution. It was found that dry tensile strength, tensile energy absorption, burst strength and compressive strength of linerboard were increased by applying PVAm. In addition, wet tensile strength was significantly improved with increasing PVAm pick-up. However, folding endurance was found to be decreased with increasing PVAm pick-up.

New Retention and Drainage Polymer For Carton Board and Newsprint

  • Lee, Woo-Suk;Noh, Jae-Hoon;Hughes, David
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.413-415
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    • 2006
  • In this article, we tried to find out the potential of new PVAm (Polyvinylamine) Polymer for optimizing Retention and Drainage system. From the mill experimental in Carton board mill, we could find out PVAm can reduce a significant chemical cost with preserving Drainage. Another case of Newsprint laboratory survey, we could find out the formation benefits from optimizing PAM system to PAM + PVAm dual system.

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Factors Affecting Z-direction Penetration of PVAm Solution into Paper (PVAm 용액의 종이 두께 방향 침투에 영향하는 인자들)

  • Choi, Do-Chim;Won, Jong Myoung;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.104-111
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    • 2015
  • Factors influencing penetration of PVAm solution into paper during impregnation were investigated with ultrasonic Penetration Evenness Analyzer (PEA). Paper structure was varied by changing basis weight, freeness of pulp, calendering, and filler addition, and hydrophobicity of paper was varied by adding AKD. In addition, the viscosity of PVAm solution was varied by changing the concentration of PVAm solution. Important factors influencing penetration of PVAm solution into paper were found to be the pore structure and the hydrophobicity of paper, and the viscosity of PVAm solution. Pore structure of paper could be controlled by refining degree and filler addition and hydrophobicity of paper could be controlled by internal sizing. Denser structure of paper, higher hydrophobicity and higher liquid viscosity slowed down the penetration of PVAm solution into paper.

Application of Cationic PVAm - Anionic PAM Dry Strength Aids System on a Kraft Paper Mill (양이온성 PVAm - 음이온성 PAM 건조지력증강제 시스템의 크라프트지 적용 사례)

  • Cho, Byoung-Uk;Ryu, Jeong-Yong;Son, Dong-Jin;Song, Bong-Keun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.50-57
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    • 2010
  • A mill trial was performed in a kraft paper mill in order to evaluate the possibility of utilizing dual polymer dry strength aids system consisting of cationic PVAm and anionic PAM. It was found that the cationic PVAm - anionic PAM dry strength additives can improve paper strength without significantly disturbing the stability of the kraft papermaking process when virgin UKP was used as a furnish. Tensile strength (25.3% in machine direction, 48.4% in cross machine direction), elongation of paper (31.6%, 15.6%) and tensile energy absorption (48%, 54%) were improved. Air permeability of the kraft paper was improved as well (22%). Tear strength was decreased with PVAm dry strength aids system, but it can be compensated with decreasing refining degree. In addition, the mill trial results indicate that highly air permeable kraft sack paper can be produced by the addition of PVAm dry strength agents at the stock with reduced freeness.