• 대한조선학회논문집
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• 제55권6호
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• pp.514-520
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• 2018

Polyurethane foam has excellent mechanical strength and insulation performance, and has been adopted as an insulation material for $-163^{\circ}C$ liquefied natural gas carrier. In this study, Kevlar Polyurethane Foams(K-PUF) were synthesized by adding Kevlar pulp with excellent mechanical strength for the purpose of improving the performance of existing polyurethane foam. Since polyurethane foam has mechanical performance depending on the proportions of Kevlar pulp added, the mechanical strength of the K-PUF with ratios of fiber0.2wt.%, 0.4wt.%, 0.6wt.%, 0.8wt.% and 1.0wt.%) was evaluated. The compression tests were performed on the 4 different temperatures($20^{\circ}C$, $-50^{\circ}C$, $-110^{\circ}C$ and $-163^{\circ}C$) in consideration of the environmental characteristics as a cryogenic insulation used in LNG carrier. Besides, the effects of the fiber addition on polyurethane foam with closed cell structure were evaluated in a phenomenological approach through SEM analysis. All the results were compared to Neat-polyurethane foam. As a results, 0.8wt.% K-PUF showed the improved mechanical strength, and the addition of Kevlar pulp in a certain ratio improves the mechanical performance by enhancing the compression resistance.

• 한국가스학회지
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• 제8권4호
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• pp.1-7
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• 2004

본 연구에서는 멤브레인식 LNG 저장탱크의 누설 안전성을 목재와 PUF로 구성된 단열재 및 예응력 콘크리트(PC) 재질이 균일하다는 가정하에 열저항 평형온도 효과를 고려하여 유한요소법(FEM)으로 해석하였다. FEM 계산결과에 따르면, 목재와 PUF로 구성된 단열재 구조물은 누설 LNG에 의해 구조물 자체가 먼저 파손되므로 누설 안전성을 보장할 수 없다. 그러나, 내부탱크와 단열재가 동시에 파손되어도 외부탱크 PC 구조물은 강도 안전성을 확보하고 있으므로 누설 LNG를 최소 10일 정도는 안전하게 지연시킬 수 있어 멤브레인식 LNG 저장탱크 시스템의 누설 안전성은 확보될 수 있다.

• 한국환경보건학회지
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• 제38권4호
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• pp.360-368
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• 2012

Objective: This study was carried out to use pine needles as a passive air sampler (PAS) of atmospheric Polychlorinated Biphenyls (PCBs). Methods: PCB concentrations in ambient air ($C_a$, ng/$m^3$) and deposited on pine needles ($C_p$, ng/g dry) were analyzed simultaneously from June 1 to December 31. Air samples were taken using a low volume PUF active air sampler and the overall average air volume was about 900-1,000 $m^3$. Pine needles were collected at the end of August and December near the air sampler. Results: $C_a$ were higher at higher air temperature and lower chlorinated PCB congeners, but $C_p$ showed irregular distribution. The average PCB sampling rates from air to pine needles were 0.116 (0.002-0.389) $m^3$/day - g dry. Conclusions: A poor correlation was shown between $C_a$ and $C_p$. However, a good correlation was shown between the logarithm of octanol-air partitioning coefficient ($logK_{oa}$) and log ($C_p/C_a$), and the interrelation was better with longer sampling time (June to December) than shorter sampling time (June to August). The average PCB sampling rates from air to pine needles were the lowest with respect to PUF disk, XAD-2 resin and semipermeable membrane devices (SPMDs) PAS. The average ratio ($C_{a-calc}/C_{a-meas}$) of calculated ($C_{a-calc}$) and measured ($C_{a-meas}$) PCB concentration was 0.69 with a shorter sampling time and 1.24 with a longer, so $C_{a-calc}$ was close to $C_{a-meas}$. It was found that pine needles can be used as PAS of atmospheric PCBs, and are especially suitable for long-time PAS.

• 생명과학회지
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• 제19권7호
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• pp.852-858
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• 2009

호흡전자전달계의 cytochrome bc$_1$ complex 또는 cytochrome c oxidase가 기능을 하지 않는 Rhodobacter sphaeroides mutant 내에서 pyridine nucleotide[NAD(P)H와 NAD(P)$^+$]의 농도와 redox 상태는 wild type과 비교할 때 큰 변화가 없었다. 높은 산소분압 조건에서 키운 Rhodobacter sphaeroides cbb$_3$ oxidase mutant 내에서 PrrBA two-component system에 의해서 조절되는 puf 오페론의 발현은 pyridine nucleotide나 전자전달계의 ubiquinone/ubiquinol pool의 redox 상태의 변화에 의해 유도된 것이 아니다. R. sphaeroides cytochrome bc$_1$ complex mutant를 이용하여 광합성기구 합성에 대한 cbb$_3$ cytochrome c oxidase의 억제 효과는 ubiquinone/ubiquinol pool의 redox 변화에 의해 간접적으로 일어나는 것이 아님을 증명하였다.

• 한국가스학회지
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• 제24권4호
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• pp.56-61
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• 2020

수소의 액화에는 예냉 에너지, 상변화 에너지, 수소 변환열 제거 등 다량의 에너지가 요구되어진다. 본 논문의 목적은 예냉공정에 필요한 에너지로 LNG냉열로 액체질소를 제조하여 사용하는 LNG냉열 간접 이용 방식과, Cold box의 단열에 냉공기를 이용하는 새로운 에너지절약 공정을 제안하여 수소액화 수율을 향상시키고자 하였다. 분석 결과를 보면, LNG냉열 간접이용 방식은 에너지 절약과 함께 액체수소 플랜트의 안전성을 제공하는 장점을 갖는다. 새로운 Cold box 단열 방식은 외벽 철판 3mm/우레탄폼 20cm/공기 5cm/우레탄폼 20cm/설비의 구조일 때 현재 펄라이트 단열에 비교하여 열유입량이 약 35%~50%가 감소하게 된다. 또한 냉공기 보다 온도가 높은 설비는 냉각의 효과를 얻게 된다. 수소액화 플랜트의 공정에 본 결과를 적용한다면 액체 수율이 50% 내외로 크게 향상되는 효과를 제공하게 된다.

• Elastomers and Composites
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• 제46권4호
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• pp.343-351
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• 2011

유기나노점토와 인화합물을 함유한 우레탄폼 복합체를 합성하고, 폼 생성속도, 밀도, 몰포로지, 열적특성 분석을 수행하였다. 우레탄폼 복합체는 Cloisite 30B가 박리/분산된 폴리아디페이트디올과 폴리에테르-폴리올(f=4.6), PMDI(f=2.5), D-580(phenyl polyoxyalkenyl phosphate)로부터 제조하였다. 발포제로써 cyclopentane과 증류수가 우레탄폼 복합체의 특성에 미치는 영향을 D-580의 농도 0~2.9 wt%에서 측정하였다. 증류수는 cyclopentane 보다 약 30% 빠르게 폼을 형성시켰다. 증류수로 발포한 우레탄폼 복합체의 밀도는 cyclopentane으로 발포한 경우보다 32~34% 낮았다. 증류수로 발포한 우레탄폼 복합체의 cell은 타원형인 반면에, cyclopentane으로 발포한 복합체는 구형의 형상이며, D-580의 함량이 증가함에 따라 cell 직경이 $158{\mu}m$에서 $100{\mu}m$로 감소하였다. Cyclopentane 으로 발포한 우레탄폼 복합체의 $T_g$는 D-580 함량이 증가함에 따라 $77.6^{\circ}C$에서 $56.1^{\circ}C$로 낮아졌다. 증류수로 발포한 우레탄 복합체의 $T_g$는 D-580 함량이 증가함에 따라 높아졌다. Cyclopentane과 증류수로 발포한 우레탄폼 복합체는 모두 $250^{\circ}C$에서 열분해가 시작하였다. Cyclopentane로 발포한 우레탄폼 복합체는 $500^{\circ}C$ 이상에서 열분해속도가 증가하는 2차 열분해 현상이 측정되었다. D-580에 의한 열안정성의 개선 정도는 cyclopentane으로 발포한 복합체에 비하여 증류수로 발포한 우레탄 복합체에서 더 높게 측정되었다.

• 한국대기환경학회지
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• 제23권4호
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• pp.457-465
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• 2007

This study was performed to estimate the gas-particle partitioning of organochlorine pesticides (OCPs) in atmosphere, the samples were collected by PUF high volume air sampler for two years from June, 2000 to June, 2002. The gas phase fraction of ${\alpha/\gamma}-HCH$, heptachlor epoxide, ${\alpha/\gamma}-chlordane$ and trans-nonachlor was over 90%. But the gas phase fraction of ${\beta}-HCH$, p,p'-DDE, endosulfan sulfate, p,p'-DDD and p,p'-DDT was range of 20% through 80%, which means the gas phase fraction of OCPs components described above is sensitive to temperature. The correlation between the gas phase fraction and molecular weight of each OCPs component was not found in this research. The slope of regression line between gas-particle partitioning coefficient(${\log}K_p$) and subcooled liquid vapor(${\log}{P^o}_L$), gal-particle partitioning coefficient(${\log}K_p$) and octanol-air partitioning coefficient(${\log}K_{oa}$) which show -0.54 and 0.43 was not steep. So the equilibrium state between gas and particle was not reached and in this state the particulate fraction was low.

• Environmental Analysis Health and Toxicology
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• 제26권
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• pp.4.1-4.6
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• 2011

Objectives: This study was carried out to determine whether or not pine needles can be used as passive samplers of atmospheric polycyclic aromatic hydrocarbons (PAHs) using the correlation between accumulated PAH concentrations in air (Ca, ng/$m^3$) and those deposited on pine needles (Cp, ng/g dry). Methods: PAHs in ambient air was collected using low volume PUF sampler and pine needles was gathered at same place for 7 months. Results: A good correlation ($R^2$=0.8582, p<0.05) was found between Ca and Cp for PAHs with a higher gaseous state in air (AcPy, Acp, Flu, Phen, Ant, Flt, Pyr, BaA and Chry), but there was a poorer correlation ($R^2$=0.1491, p=0.5123) for the PAHs with a lower gaseous state (BbF, BkF, BaP, DahA, BghiP and Ind123). A positive correlation ($R^2$=0.8542) was revealed between the logarithm of the octanol-air partitioning coefficient ($logK_{oa}$) and Cp/Ca for the PAHs with a higher gaseous state in air, but there was a negative correlation ($R^2$=0.8131) for the PAHs with a lower gaseous state. The Ca-Cp model could not be used to estimate PAHs concentrations in air using deposited PAHs concentrations on pine needles, but the logKoa-Cp/Ca model could be used. Conclusions: It was found that pine needles can be used as passive samplers of atmospheric PAHs.

• 대한조선학회논문집
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• 제56권4호
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• pp.291-297
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• 2019

Polyurethane foam is the most efficient, high-performance insulation material, used for liquefied natural gas carrier (LNGC) insulation. Because LNGC is exposed to sloshing impact load due to ship motion of 6 degrees of freedom, polyurethane foam should be sufficient dynamic properties. The dynamic properties of these polyurethane foam depends on temperature and density. Therefore, this study investigates the dynamic response of polyurethane foam for various temperature($25^{\circ}C$, $-70^{\circ}C$, $-163^{\circ}C$) and density($90kg/m^3$, $113kg/m^3$, $134kg/m^3$, $150kg/m^3$) under drop impact test with impact energy of 20J, 50J, and 80J. For dynamic response was evaluated in terms of peak force, peak displacement, absorb energy, and the mechanical property with minimized density effects. The results show the effect of temperature and density on the polyurethane foam material for the dynamic response.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.455-458
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• 2001

Spinel $LiMn_{2-y}$$M_{y}$ $O_4$powder was prepared solid-state method by calcining the mixture of LiOH - $H_2O$, Mn $O_2$, ZnO and MgO at 80$0^{\circ}C$ for 36h. To investigate the effect of substitution with Mg, Zn cation, charge-discharge experiments and initial impedance spectroscopy performed. The structure of $LiMn_{2-y}$$M_{y}$ $O_4$crystallites was analyzed from powder X-ray diffraction data as a cubic spinel, space group Fd3m. all cathode material showed spinel phase based on cubic phase in X-ray diffraction. Ununiform which calculated by (111) face and (222) face was constant in spite of the change of y value, except PUf\ulcorner LiM $n_2$ $O_4$. The discharge capacities of the cathode for the cation subbstitUtes $LiMn_{2-y}$$M_{y}$ $O_4$/Li cell at the 1st cycle and at the 40th cycle were about 120~124 and 108~112mAh/g except LiM $n_{1.9}$Z $n_{0.1}$ $O_4$/Li cell, respectively. This cell capacity is retained by 93% after 40th cycle. AC impedance of $LiMn_{2-y}$$M_{y}$ $O_4$/Li cells revealed the similar resistance of about 65~110$\Omega$ before cycling. before cycling.g.g.