• Transactions of the Korean hydrogen and new energy society
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• v.20 no.5
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• pp.424-431
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• 2009

Treatment for water repellency on the carbon supports of GDL which composed a part of MEA has been suggested as a solution to prevent flooding. PTFE is a fluoropolymer that has hydrophobic property and a PTFE emulsion was selected as waterproof agent in this investigation. Carbon paper was coated by PTFE emulsion with different particle size of 5~500 nm and 3~$5\;{\mu}m$ as various concentration. PTFE coated carbon paper has difference in weight variation changed proportionally at PTFE concentration and coating times. Then gas permeability of the coated carbon paper with emulsion of 3~$5\;{\mu}m$ PTFE was changed vastly. Characteristics of carbon paper coated with different PTFE emulsion were analyzed by FE-SEM, FT-IR spcetroscopy and were evaluated by weight variations, gas permeability and water contact angle.

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1333-1336
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• 2014

Expanded polytetrafluoroethylene (ePTFE) grafts have been used as vascular access for many patients suffering from end stage renal disease. However, the vascular graft can cause significant clinical problems such as stenosis or thrombosis. For this reason, many studies have been performed to make drug eluting graft, but initial burst is major problem in almost drug eluting systems. Therefore we used biodegradable polymer to reduce initial burst and make sustained drug delivery. The ePTFE grafts were dipped into a paclitaxel-dissolved solution and then PLGA-dissolved solution was passed through the lumen of ePTFE. We analyzed whether the dose of paclitaxel is enough and the loading amount of PLGA on ePTFE graft increases according to the coating solution's concentration. Scanning electron microscope (SEM) images of various concentration of PLGA showed that the porous surface of graft was more packed with PLGA by tetrahydrofuran solution dissolved PLGA. In addition, in vitro release profiles of Ptx-PLGA graft demonstrated that early burst was gradually decreased as increasing the concentration of PLGA. These results suggest that PLGA coating of Ptx loaded graft can retard drug release, it is useful tool to control drug release of medical devices.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.4
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• pp.323-330
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• 2009

Efficiency of a fuel cell is determined by the generated water. If water is not removed sufficiently, water will be accumulated at GDL, which causes flooding. Therefore, water control is regarded as a crucial factor to sustain fuel ell performance. In this study, PTFE coating on the surface of carbon paper was carried out to establish optimum process for hydrophobic treatment of GDL. Carbon paper was immersed at different concentrations of nano-sized PTFE coating solution. Their characteristics were analyzed systematically by FE-SEM, water contact angle, cyclic voltamogam, XRD and FT-IR. The quantitative correlation between the amount of coated-PTFE on a carbon paper and concentration of coating solution was carefully investigated. It is suggested that the amount of PTFE-coating on a carbon paper can be managed by means of controling concentration of coating solution.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.7
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• pp.391-402
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• 2017

Particulate matter becomes an important issue in the environmental society recently so that it is necessary to evaluate that the commercial application of baghouse systems for effective control of fine particulates is viable. A laboratory-scale baghouse experimental apparatus with filter bags made of PTFE felt or PTFE felt coated with PTFE membrane is used to investigate the filtration performances of fine particulates. Experiments by changing filtration velocity, inlet dust concentration, and average dust particle size show that the dust collection efficiency becomes higher at lower filtration velocity, higher inlet dust concentration and larger average dust particle size. The total pressure drop through the filter media and dust layer becomes higher at higher filtration velocity and higher inlet dust concentration. The dust collection efficiency is higher and the pressure drop is lower at a baghouse with filter bags coated with PTFE membrane than that without membrane coating. From the result that the dust collection efficiency of $PM_{2.5}$ in a reasonable filtration velocity range during off-line pulsing at a baghouse with PTFE felt bag filters coated with PTFE membrane is as high as 99.99%, it is confirmed that the use of baghouse is an effective measure to control the fine particulates.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.4
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• pp.313-320
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• 2010

Carbon cloth was impregnated into PTFE emulsion. PTFE is a fluoropolymer used as a coating material in various fields due to its hydrophobicity and excellent mechanical properties. In this study, PTFE emulsion was prepared different particle size of 5~500 nm and $3{\sim}5{\mu}m$. FE-SEM and FT-IR spectroscopy were used microscopic observation and investigation of chemical structure change after PTFE coating. Mass variations, gas permeability and water contact angles were analyzed to determine a GDL performance of PTFE coated carbon cloth. PTFE coated carbon cloth show different mass increase according as PTFE concentration and the number of coating times. Water contact angle of PTFE coated carbon cloth was not effected by size of PTFE particle and the number of coating time; meanwhile, gas permeability was rapidly changed at carbon cloth coated by emulsion with size of $3{\sim}5{\mu}m$ PTFE particle.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.24 no.1
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• pp.64-69
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• 2011

Super-hydrophobic properties have been achieved on the rf-sputtered polytetrafluoroethylene(PTFE) films deposited on etched aluminum surfaces. The microstructural evolution created after etching has been investigated by FESEM. The water contact angle over $160^{\circ}$ can be achieved on the rf-sputtered ultra-tihn PTFE film less than 10 nm coated on aluminum surface etched with 7 wt.%, 12.5 wt.%, and 15 wt.% HCl concentration for 12 min. XPS analysis have revealed the presence of a large quantity of $-CF_3$ and $-CF_2$ groups in the rf-sputtered PTFE films that effectively can reduce the surface energy of etched aluminum. The presence of patterned morphology along with the low surface energy at the rf-sputtered PTFE coating makes the aluminum surface with high super-hydrophobic property.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.52 no.9
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• pp.395-399
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• 2003

In this paper, physical phenomena which are related to the high temperature and high pressure arc plasma generated during the fault current interruption by SF6 gas circuit breakers are reviewed. In particular, in order to analyze nozzle ablation induced by the heats transferred to the surface of the poly-tetrafluoroethylene(PTFE) nozzle through arc radiation, a governing equation for the calculation of PTFE concentration is added to the governing equations for SF6 arc Plasma analysis. The proposed method is applied to the steady state analysis of $SF_6$ arc plasma generated by direct current taking account of the nozzle ablation and the results are presented.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.2
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• pp.66-71
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• 2011

This study analyzed the mechanical characteristics and evaluated their subsequent performance for two types of seals which reinforced characteristics with lower friction and anti-wear functions among the foremost important features in the automotive engine seals; one with the addition of glass fiber to PTFE(Polytetrafluoro ethylene); the other with the addition of self-lubricant molybdenumin addition to the glass fiber. Based on the configuration design of seal installed to the front part in the automotive engine, this study carried out interpretations on the stress and reaction for those two types of oil seals to compare the maximum stress and contact load generated from the seal steel, rubber and PTFE lip. This study also verified the stress concentration and anti-wear performance through the coefficient of friction, torque and durability test by producing two types of PTFE seals actually.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.05b
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• pp.7-10
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• 2004

This paper presents the electrical properties of PTFE nozzle for a electrical apparatus. In the arcing environment in a electrical apparatus, radiation is considered to be the major energy transport mechanism from the arc to the wall. The fraction of the radiation power is emitted out of the arc and reaches the nozzle wall, causing ablation at the surface and in the depth of the wall. The energy concentration in the material leads to the depolymerization and eventually leads to the generation of decomposed gas as well as some isolated carbon particles. Adding some fillers into PTFE is expected to be efficient for improving the endurability against radiation. In this experiment, three kinds of fillers that have endurance in the high temperature environment were added into PTFE. Light reflectance of fillers was investigated. Dielectric constan and dissipation factor of PTFE composites were investigated. Dielectric constant and dissipation factor of the PTFE composites increased with increasing contents of the fillers.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.11a
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• pp.204-207
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• 2003

This paper presents the electrical properties of PTFE (polytetrafluoroethylene) nozzle for circuit breaker. PTFE has been used widely as a nozzle material for circuit breaker. In the arcing environment in a circuit breaker, radiation is considered to be the major energy transport mechanism from the arc to the wall. The fraction of the radiation power is emitted out of the arc and reaches the nozzle wall, causing ablation at the surface and in the depth of the wall. The energy concentration in the material lead to the depolymerization and eventually lead to the generation of decomposed gas as well as some isolated carbon particles. The generation of the decomposed gas in the depth of the material causes inner explosion. The surface of nozzle becomes uneven. The flow of gas is not uniform due to the unevenness of the surface. Adding some fillers into PTFE is expected to be efficient for improving the endurability against radiation. In this experiment, three kinds of fillers that have endurance in the high temperature environment were added into PTFE. Dielectric constant, dissipation factor, electrical resistivity and dielectric strength of PTFE composites were investigated.