• Journal of the Korea Academia-Industrial cooperation Society
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• v.6 no.1
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• pp.58-63
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• 2005

PTFE (polytetrafluoroethylene) thin films were prepared from the pellets of the graphite doped PTFE via pulsed laser ablation with 1064 nm Nd:YAG laser. The graphite powder converts the absorbed photon energy into thermal energy which is transmitted to nearby PTFE. The PTFE is decomposed by thermal process. The deposited films were transparent and crystalline. SEM (scanning electron microscopy) and AFM (atomic force microscopy) analyses indicated that the film surface morphology changed to fibrous structure with increasing thickness. The fluorine to carbon ratios of the film were 1.7 and molecular axis was parallel with (100) Si-wafer substrate. These results obtained by XPS (X-ray photoelectron spectroscopy), FTIR (fourier transform infrared spectroscopy) and XRD (X-ray diffraction).

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.05a
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• pp.197-198
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• 2012

PTFE(polytetrafluoroethylene) 타겟을 RF 스퍼터링에 의하여 Si 기판과 슬라이드 글라스에 코팅하였다. PTFE의 기초 실험조건으로 타겟 건 파워, 공정시간, 압력 및 바이어스 파워를 변화시켰다. PTFE 필름의 특성은 조건별 두께를 비교하였고, 분광광도계에 의한 투과도를 측정하였다. PTFE의 발수 특성과 스퍼터링 공정 조건을 확인하고자 접촉각 측정을 실시하였다. 타겟 건의 파워 및 시간에 따라 증착속도의 차이가 있었으며, 광학적인 투과도에서도 변화가 있음을 알 수 있었다. 발수특성을 나타내는 PTFE의 스퍼터링에 의한 접촉각 측정을 통해 다양한 조건별 접촉각 특성을 확인하였다.

• Science of Emotion and Sensibility
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• v.15 no.2
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• pp.201-208
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• 2012

The objectives of this study were to investigate the psychoacoustic properties of PTFE(Poly tetra Fluoroethylene) laminated vapor permeable water repellent fabrics which are frequently used for sportswear, to examine the relationship among fabrics' basic characteristics, mechanical properties and the psychoacoustic properties, and finally to propose the predicting model to minimize the psychoacoustic fabric sound. A total of 8 specimens' frictional sound were recorded and Zwicker's psychoacoustic parameters such as loudness(Z), sharpness(Z), roughness(Z), and fluctuation strength(Z) were calculated using the Sound Quality Program. Mechanical properties of specimens were measured by KES-FB system. Loudness(Z) of specimen D-1 was the highest, which means the rustling sound of the specimen D-1 was the most noisy. Statistically significant difference among film type was observed only in loudness(Z) for fabric sound. Based on ANOVA and post-hoc test, specimens were classified into less loud PTFE film group (groupI) and loud PTFE film group (groupII). Loudness(Z) was higher when staple yarn was used compared when filament yarn was used. According to the correlation between the mechanical properties of fabrics and loudness(Z) in groupI, the shear properties, compression properties and weight showed positive correlation with loudness(Z). According to the regression equation predicting loudness(Z) of groupI, the layer variable was chosen. In groupII, variables explaining the loudness(Z) were yarn types and shear hysteresis(2HG5).

• Journal of the Korean Society of Clothing and Textiles
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• v.26 no.12
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• pp.1685-1693
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• 2002

다양한 용도로 사용되고 있는 라미네 이 팅 직물은 주로 별도로 제조된 고분자 필름 또는 막을 접착제, 열, 압력 등을 이용하여 기포(基布)와 결합시키는 방법으로 제조되어 진다. 이축연신시킨 Poly(tetrafluoroethylene) (PTFE) sheet는 매우 우수한 높은 투과성을 지니는 다공성 물질이 며, 본 연구에서는 이 막을 나일론 직물에 라미네이팅시킨 투습방수직물을 시료로 사용하여 라미네이팅 후의 역학특성 변화를 분석 하였다. 라미네이팅에 따른 투습방수직물의 물성과 역학특성의 변화에 관하여 살펴본 결과 다음과 같은 결과를 얻었다. 3-layer 라미네이팅 직물(base fabric-PTFE membrane-knitted lining)의 인열강도는 2-layer라미네이팅 직물 (base fabric-PTFE membrane)에 비해 매우 높게 나타났으며, 가공 전 직물과 비교하여 코팅직물에서 나타난 것과 같은 인열강도의 감소는 나타나지 않았다. 직물-PTFE 막 복합체 의 경우, 라미네 이 팅 이 파단강도 및 파단신도 의 증가에 기여 한 것으로 나타났으며 특히 3-layer 라미네이팅 직물의 경우, 신장률이 20%를 넘어서면서 강도가 현저히 증가하였다. 의복을 착용하였을 때 가해질 수 있을 정도의 소변형(small deformation) 하에서의 역학특성 에 있어서는 라미네이팅에 의해 전단특성이 가장 유의한 변화를 나타내었다. 전단강성(G)과 전단 히스테리시스 (2HG,2HG5)모두 증가하였고, primary hand value 중에서는 stiffness 가장 현저한 증가를 나타내었다

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1988.10a
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• pp.67-70
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• 1988

In this paper, thermally stimulated currents (TSC) of corona-charged PTFE film were studied. Corona electrets which were formed by applying high voltages ${\pm}$5∼${\pm}$8[kV], to PTFE film of 100[$\mu\textrm{m}$] thickness, were experimented to measure TSC in the temperature range from -100[$^{\circ}C$] to 200[$^{\circ}C$]. As the result, four peaks of ${\gamma}$, ${\beta}$$_2$, ${\beta}$$_1$ and ${\alpha}$ were obtained at the temperature of -40[$^{\circ}C$], 30[$^{\circ}C$], 90[$^{\circ}C$] and 170[$^{\circ}C$], respectively. Speaking of the origins of these peaks, first of all, ${\gamma}$ peak is believed to show up by virtue of CF$_2$groups. B$_2$ peak seems to turn up by detrapping of the electrons which are accelerated by the corona exposure. ${\beta}$$_1$ peak looks to be ascribed to detrapping of the dipole and the trapped electron. Finally, ${\alpha}$ peak appears to result from detrapping of the electrons which are trapped in the para-crystalline region.

• Polymer(Korea)
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• v.38 no.4
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• pp.457-463
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• 2014

In this study, the changes in the chemical structure and the physical property of fluoropolymer films (PTFE, FEP, PFA, PVDF, and ETFE) induced by $Co^{60}$ gamma ray in air, $N_2$, and vacuum environments were investigated. FTIR spectra of the irradiated fluoropolymers indicate that the oxidation proceeded by the reaction of radicals generated by irradiation with oxygen in air. The changes in the heat of fusion and the degree of crystallinity of the irradiated fluoropolymers were investigated using DSC and the results indicate that the scission and crosslinking reactions of the irradiated fluoropolymers were largely influenced by the chemical structure. It was also found that the mechanical property of the irradiated fluoropolymer films under an air atmosphere was significantly decreased.

• Membrane Journal
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• v.33 no.4
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• pp.201-210
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• 2023

Dust filter membranes play a crucial role in human life and various industries, as they contribute to several important aspects of human health, safety, and environmental protection. This study presents the development of a polysulfone@polyphenylene sulfide/polytetrafluoroethylene (PSf@PPS/ePTFE) composite dust filter membrane with excellent thermal stability and adhesion properties for high-temperature conditions. FT-IR analysis confirms successful impregnation of PSf adhesive onto PPS fabric and interaction with ePTFE support. FE-SEM images reveal improved fiber interconnection and adhesion with increased PSf concentration. PSf@PPS/ePTFE-5 exhibits the most suitable porous structure. The composite membrane demonstrates exceptional thermal stability up to 400℃. Peel resistance tests show sufficient adhesion for dust filtration, ensuring reliable performance under tough, high-temperature conditions without compromising air permeability. This membrane offers promising potential for industrial applications. Further optimizations and applications can be explored.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.113-113
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• 2010

유비쿼터스 시대를 맞이하여 현재의 전자제품은 초고주파 환경에서의 소형화된 마이크로파 소자를 요구하고 있다. 마이크로파 대역에서 세라믹 소재는 대부분의 폴리머 소재에 비해 낮은 유전손실 값을 보이고 있어 향후 확대되는 고주파화에 적합한 소재로 평가되고 있다. 하지만 세라믹 재료는 깨지기 쉬운 특성을 가지고 있어 공정 및 취급이 어려우며 높은 소결온도를 가지고 있어 융점이 낮은 재료와의 집적화에 있어서 난점을 가지고 있다. 이를 위해 본 연구실에서는 실온에서 세라믹을 비롯한 금속 및 폴리머 재료의 치밀한 코팅막의 성막 및 이종 접합이 가능한 Aerosol Deposition (AD 법)에 주목하였고 마이크로파 소자 제작 공정으로서 AD 법의 응용 가능성을 연구하였다. 마이크로파 소자의 기판으로서는 AD 법을 이용하여 유전손실이 낮고 플렉서블한 $Al_2O_3$-PTFE 혼합 기판을 제작하고 적용하였다. 금속 선로 패터닝 제작 공정으로는 도금법이 대표적이지만 고비용 및 복잡한 공정 절차, 폐화학용액으로 인한 환경문제 등의 단점을 지니고 있어 이를 대체하는 금속 선로 패터닝 공정이 절실히 요구되고 있다. 이를 위해 본 연구에서는 AD 법을 이용하여 금속 필름을 제작하고 대체 공정으로서의 가능성을 확인하였다. 하지만 AD 법을 이용한 세라믹 필름 제작에 관한 연구는 크게 활성화되어 있는 반면에 금속 필름의 제작, 특성 측정 및 개선에 관한 연구는 그에 비해 미비한 수준이다. 이를 위해 이번 연구에서는 AD 법을 이용하여 금속 필름을 성막 시에 영향을 미치는 요인을 고찰하였으며 또한 마이크로파 소자의 도체 손실에 크게 관계되는 금속 필름의 비저항 특성의 측정 및 개선에 관한 연구를 수행하였다. 이를 위해 본 연구에서는 정전장 시뮬레이션을 활용하여 AD 법으로 성막된 금속 필름의 정밀한 비저항 측정에 관한 연구방법을 마련하고 후열처리를 통한 비저항 특성을 개선시키는 연구를 진행하였다.

• Fashion & Textile Research Journal
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• v.14 no.4
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• pp.641-647
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• 2012

This study investigates the sound properties of fabric frictional sound (SPL, ${\Delta}L$, ${\Delta}f$) according to the film type of PTFE laminated vapor-permeable water-repellent fabrics in order to understand the relationship between SPL and the basic properties of fabrics such as layer, yarn type, and thickness of fiber. This study accesses their mechanical properties and determines how to control them to minimize SPL. Eight PTFE laminated water-repellent fabrics, composed of four different film types (A, B, C, D) and with two different fabrics, were used as test specimens. Frictional sounds generated at 1.21m/s were recorded by using a fabric sound generator and SPLs were analyzed through Fast Fourier Transformation (FFT). The mechanical properties of fabrics were measured by KES-FB. The SPL value was lowest at 74.4dB in film type A and highest as 85.5dB in type D. Based on ANOVA and post-hoc test, specimens were classified into less Loud Group (A, B) and Loud Group (C, D). It was shown that SPL was lower when 2 layer (instead of 3 layer), filament yarn than staple, and thin fiber than thick were used. In Group I, shearing properties (G, 2HG5), geometrical roughness (SMD), compressional properties (LC, RC) and weight (W) showed high correlation with SPL however, elongation (EM) and shear stiffness (G) did with SPL in Group II.

• Progress in Medical Physics
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• v.15 no.2
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• pp.105-111
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• 2004

The parallel plate detector with dielectric film for dosimetry was designed to measure detection characteristic of 6 MV X-ray with medical linear accelerator. PTFE film was inserted into FEP films that are made by two one-side metal coated materials for ion source. The thicknesses of PTFE dielectric film was 100 ${\mu}{\textrm}{m}$ and the thickness of FEP dielectric film was 100 ${\mu}{\textrm}{m}$, respectively. This detector was fixed by two acrylic plate for physical hardness ad geometrical consistency. The geometrical condition for measurement with parallel-plate for detector was below; SSD=100 cm and the 5 cm depth between detector and phantom surface The major parameter of detector characteristics such as zero drift current, leakage current, charge response by applied voltage, reproducibility, linearity, TMR measurement, dose rate effect were measured. The zero drift currents are 8.3 pA and leakage currents are 10 pA. The charge response of applied voltage is showing linearity in 414 voltage. The measurement deviation of reproducibility in this detector is within 1% for dose and the linearity of applied dose shows in this detector. The TMR curves in phantom between this parallel plate detector and reference detector are matched within 3% deviation from maximum dose depth to 7.5 cm depth. It is considered that this dosimetric system is satisfactory for the purpose of the constancy check of the 6 MV x-ray from medical linear accelerator.