• Title/Summary/Keyword: PREPREG

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Study of the Curing Reaction Rate of a Glass Fiber Reinforced Bisphenol-A (BPA) Epoxy Prepreg by Differential Scanning Calorimetry (DSC) (Differential Scanning Calorimetry (DSC)를 이용한 유리섬유 Bisphenol-A(BPA)계 에폭시 프리프레그의 경화 반응 속도 연구)

  • Kwon, Hyeon-Jin;Park, Hee-Jung;Lee, Eun-Ju;Ku, Sang-Min;Kim, Seon-Hong;Lee, Kee-Yoon
    • Composites Research
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    • v.31 no.1
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    • pp.30-36
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    • 2018
  • The curing behavior of glass fiber reinforced epoxy prepregs based on Bisphenol-A (BPA) was studied by differential scanning calorimetry (DSC). The total heat of reaction(${\Delta}H_{total}=280.3J/g$) was determined based on the results of the dynamic heating scanning experiments. Isothermal experiments were carried out at $110{\sim}130^{\circ}C$, and it was observed that the maximum conversion and the maximum reaction rate were increased as temperature increased. Also Kamal equation was applied to analyze autocatalytic reaction of epoxy prepregs. The higher temperatures, the greater reaction rate constants ($k_1$, $k_2$). Theoretical values were calculated by these reaction rate constants and compared with experimental values. And it was confirmed that they were in reasonable agreement. At the beginning of the reaction, the experimental data and theoretical prediction were shown the same tendency, but at the end of reaction, the experimental data were smaller than theoretical predicted values due to reaction rates controlled by diffusion.

Fabrication and Characteristics of CFRC(Carbon Firber Reinforced Carbon Composites) Fabricated with Carbon Fiber and Coal Tar Pitch Matrix (석탄계 핏치를 결합재로한 탄소/탄소 복합재의 제조 및 특징)

  • Ju, Hyeok-Jong;Choe, Don-Muk;O, In-Seok
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.194-205
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    • 1994
  • In this research, we attempt to fabricate an excellent CFRC(Carbon Fiber Reinforced Carbon), which has good thermal and mechanical properties, with 8H/satin woven fabric prepreg, high modulus and high strength type continuous carbon fiber and raw coal tar pitch(RCTP) matrix or THF soluble fraction(THFSP) matrix which has good graphitizability. Green bodies were fabricated with hot press molding technique and CFRC samples were made after carbonization, impregnation, recarbonization and graphitization steps. For the purpose of characterization of the physical properties, SEM, polarized light microscope, TGA were observed, and tested flexural strength, modulus and ILSS. After heat treating the THFSP matrix up to $2300^{\circ}C$, the value of $C_0$/2 was 3.380$\AA$, which is analogous to the structure of natural graphite and the value of 2$\theta$ is $26.276^{\circ}$ approached to the Bragg's angle of natural graphite. As a result of TGA to test the high temperature air oxidation, the THFSP matrix, graphitized up to $2300^{\circ}C$, exhibited the best air oxidation resistance. And mechanical properties were increased up to 65~70% as fiber volume fraction increased. Because of the good orientation graphitizability, the fracture surface of THFSP matrix CFRC is very good.

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Impact Performance of 3D Orthogonal Composites by Automated Tape Placement Process (자동적층 공정에 의한 3차원 직교 섬유배열구조 복합재의 충격특성)

  • Song S-W;Lee C-H;Um M-K;Hwang B-S;Byun J-H
    • Composites Research
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    • v.18 no.3
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    • pp.38-46
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    • 2005
  • In order to characterize the outstanding performance of three-dimensional (3D) composites, the low velocity impact test has been carried out. 3D fiber structures have been achieved by using the automated tape placement (ATP) process and a stitching method. Materials for the ATP and the stitching process were carbon/epoxy prepreg tapes and Kevlar fibers, respectively. Two-dimensional composites with the same stacking sequence as 3D counterparts have also been fabricated for the comparison of damage tolerance. For the assessment of damage after the impact loading, specimens were subjected to C-Scan nondestructive inspection. Compression after impact (CAI) tests were conducted to evaluate residual compressive strength. The damage area of 3D composites was greatly reduced $(30-40\%)$ compared with that of 2D composites. Although the CAI strength did not show drastic improvement for 3D composites, the ratio of retained strength was $5-10\%$ higher than 2D samples. The effect of stitching on the impact performance was negligible above the energy level of 35 Joules.

Buckling Analysis of Composite Cylindrical Shell Using Numerical Analysis Method (수치해석적 기법을 이용한 복합재 원통 셸의 좌굴 연구)

  • Jung, Hae-Young;Cho, Jong-Rae;Bae, Won-Byung;Lee, Woo-Hyung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.1
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    • pp.51-58
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    • 2012
  • The objective of this paper is to predict the buckling pressure of a composite cylindrical shell using buckling formulas (ASME 2007, NASA SP 8007) and finite element analysis. The model in this study uses a stacking angle of [0/90]12t and USN 125 composite material. All specimens were made using a prepreg method. First, finite element analysis was conducted, and the results were verified through comparison with the hydrostatic pressure buckling experiment results. Second, the values obtained from the buckling formula and the buckling pressure values obtained from the finite element analysis were compared as the stacking angle was changed in $5^{\circ}$ increments from $20^{\circ}$ to $90^{\circ}$. The linear and nonlinear results of the finite element analysis were consistent with the results of the experiment, with a safety factor of 0.85-1. Based on the above result, the ASME 2007 formula, a simplified version of the NASA SP-8007 formula, is regarded as a buckling formula that provides a reliable safety factor.

Evaluation of Running Performance of the Composite Bogie under Different Side Beam Stiffness (사이드 빔 강성에 따른 복합소재 대차의 주행성능 평가)

  • Kim, Jung-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.86-92
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    • 2017
  • In this study, a running performance evaluation and roller rig test was conducted to evaluate the applicability of a composite bogie frame, which has the role of the primary suspension. The composite bogie frame was made of a GEP224 glass/epoxy prepreg. Vehicle dynamic analysis was carried out on the composite bogie with three different kinds of side beam thicknesses (50 mm, 80 mm, and 150 mm). From the results, the composite bogie with a side beam thickness of 80 mm satisfied all the dynamic design requirements. Although the composite bogie with the side beam thickness of 50mm also met the design requirements, its critical speed was just a 2% margin to the requirement. In contrast, the model of the side beam thickness of 150mm did not meet the ride comfort. In addition, a composite bogie frame with the side beam thickness of 80 mm was fabricated and installed on a complete bogie. Moreover, the roller rig test using the fully equipped bogie was performed to evaluate the critical speed. During the test, the lateral excitation was imposed on the wheelsets to realize the rail irregularity. There was no divergence of the lateral displacement of the wheelsets while increasing the speed. The measured critical speed was similar to the predicted result.

Glass Fiber Composite Material with Polyurethane Toughener in Unsaturated Polyester Resin (UPR) (불포화 폴리에스터 (UPR)에 폴리우레탄을 첨가하여 강인성을 부여한 유리섬유 복합소재)

  • Baek, Chang Wan;Jang, Tae Woo;Kim, Taehee;Kim, Hye Jin;Kim, Hyeon-Gook;Kim, Changyoon;Seo, Bongkuk;Lim, Choong-Sun
    • Journal of Adhesion and Interface
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    • v.22 no.2
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    • pp.63-68
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    • 2021
  • Unsaturated Polyester Resin (UPR) is in general used as a resin to prepare for composite materials with reinforcing materials such as glass fibers. UPR, a thermosetting resin, is used in industry to prepare for sheet molding compound (SMC) molding prepreg that has excellent productivity and is advantageous for mass production among various molding methods of composite materials. The fiber-reinforced composite material using UPR as a matrix material is light and has the advantage of excellent physical properties, but it is weak against impact and is fragile. Four types of polyurethane were synthesized and added to UPR resin to overcome the shortcomings.

A Study on the Fatigue Strength of the 3-D Reinforced Composite Joints (3-차원 보강 복합재 체결부의 피로강도 특성 연구)

  • Kim, Ji-Wan;An, Woo-Jin;Seo, Kyeong-Ho;Choi, Jin-Ho
    • Composites Research
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    • v.35 no.5
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    • pp.322-327
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    • 2022
  • Composite lap joints have been extensively used due to their excellent properties and the demand for light structures. However, due to the weak mechanical properties in the thickness direction, the lap joint is easily fractured. various reinforcement methods that delay fracture by dispersing stress concentration have been applied to overcome this problem, such as z-pinning and conventional stitching. The Z-pinning is reinforcement method by inserting metal or carbon pin in the thickness direction of prepreg, and the conventional stitching process is a method of reinforcing the mechanical properties in the thickness direction by intersecting the upper and lower fibers on the preform. I-fiber stitching method is a promising technology that combines the advantages of both z-pinning and the conventional stitching. In this paper, the static and fatigue strengths of the single-lap joints reinforced by the I-fiber stitching process were evaluated. The single-lap joints were fabricated by a co-curing method using an autoclave vacuum bag process and I-fiber reinforcing effects were evaluated according to adherend thickness and stitching angle. From the experiments, the thinner the composite joint specimen, the higher the I-fiber reinforcement effect, and Ifiber stitched single lap joints showed a 52% improvement in failure strength and 118% improvement in fatigue strength.

Bending Performances and Collapse Mechanisms of Light-weight Aluminum-GERP Hybrid Square Tube Beams (경량화 알루미늄-GFRP 혼성 사각관 보의 굽힘성능 및 붕괴 메커니즘)

  • Lee, Sung-Hyuk;Kim, Hyung-Jin;Chang, Young-Wook;Choi, Nak-Sam
    • Composites Research
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    • v.20 no.3
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    • pp.8-16
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    • 2007
  • Bending collapse of light-weight square tubes used for vehicle structure components is a dominant failure mode in oblique collision and rollover of vehicles. In this paper bending performances of aluminum-GFRP hybrid tube beams were evaluated in relation with bending deformation behavior and energy absorption characteristics. Aluminum/GFRP hybrid tube beams fabricated by inserting adhesive film between prepreg and metal layer were used in the bending test. Failure mechanisms of hybrid tubes under a bending load were experimentally investigated to analyze the bending performance as a function of ply orientation and composite layer thickness. Ultimate bending moments and energy absorption capacity of hybrid tube beams were obtained from the measured load-displacement corves. It was found that aluminum/GFRP hybrid tubes could be converted to rather stable collapse mode showing excellent energy absorption capacity in comparison to the pure aluminum tube beams. In particular, the hybrid tube beam with $[0^{\circ}/90^{\circ}]s$ composite layer showed a large improvement by about 78% in energy absorption capacity and by 29% in specific energy absorption.