• Title/Summary/Keyword: PPM model

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A study on Nickel Hydroxide Crystallization for Plating waste Treatment

  • Lee, Chang-Hwan;Lee, Choul-Ho
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.292-295
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    • 2001
  • A Study on the precipitation characteristics of nickel hydroxide as well as carbonate and sulfide is carried out to determine the proper treatment condition of the wastewater induced from nickel-plating industry. The nickel concentrations in the effluent could be kept lower than 5ppm when the value of pH was maintained higher than 10. The precipitation of nickel salts by alkaline addition to the nickel containing model wastewater was conducted by using proper amount of sodium hydroxide, sodium carbonate, sodium bicarbonate and sodium sulfide. In case of the sulfide treatment, the residual nickel concentration in the clear water after precipitates removed showed the lowest value. The influences of the precipitation condition upon the particle size of the crystals precipitated were also investigated. In spite of the various precipitation conditions were adopted, the particle size of the precipitated crystals showed no great differences. The sedimentation rates of the precipitated particle bed were observed and the free sedimentation period was terminated within 20 minutes. Although the hindered sedimentation as well as bed compaction progressed subsequently, the bed heights were maintained almost the same level after two hours of sedimentation.

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Temporal Dynamics of Triflumizole Residue in Tomato Leaves as Affected by Temperature and Its Effects on Cladosporium fulvum (토마토 잎에 집적된 Triflumizole 잔류량의 온도에 따른 경시적 동태와 잎곰팡이병균에 대한 약호)

  • 오연이;박은우;조일규;강창성;김성기;양장석
    • Korean Journal Plant Pathology
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    • v.12 no.3
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    • pp.307-315
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    • 1996
  • 토마토 잎에 집적된 triflumizole 잔류량 동태에 미치는 온도 영향과 Cladosporium fulvum에 대한 triflumizole의 살균효과를 구명하였다. 8주간 키운 토마토 식물체에 triflumizole을 분무 살포한 후 식물생장용 항온실에서 키우면서 4가지 온도 조건을 처리하였다. 주기적으로 토마토 잎을 채취하여 HPLC 방법을 이용하여 triflumizole의 잔류량을 조사하였다. Triflumizole 잔류량의 경시적 동태는 약제살포후 적산온도를 독립변수로 사용하는 지수적 감소 몸형으로 나타낼수 있었으며, 이는 triflumizole의 잔류성이 온도 영향을 크게 받는다는 것을 뜻한다. 경기도 농촌진흥원에 위치한 토마토 비닐하우스에서 수행한 실험에서 얻은 자료를 이용하여 평가한 결과 이 모형의 타당성이 인정되었다. Triflumizole의 약효에 대한 in vitro 실험 결과, 이 살균제는 C. fulvum의 균사 생장과 포자형성을 뚜렷이 억제하였으며, 잎곰팡이병 방제를 위해서는 토마토 잎에 집적된 triflumizole 잔류량이 최소한 10 ppm 이상이 되어야 할 것으로 추측된다. 본 연구에서 연구된 지수적 감소 모형은 토마토 잎에 집적된 triflumizole 잔류량을 추정하는데 활용될 수 있으며, 실용적인 측면에서 볼 때, 토마토 잎곰팡이병을 효과적으로 방제하는데 필요한 triflumizole의 최소 잔류량을 식물체에 유지하기 위하여 triflumizole을 살포해야 할 시기를 결정하는데 활용될 수 있다.

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Studies on the Water Purification Using Water Parsley (미나리 (Oenanthe javanica(Blume) DC)를 이용한 수질정화에 관한 연구)

  • 권성환;나규환;류재근;김종택
    • Journal of Environmental Health Sciences
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    • v.22 no.3
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    • pp.56-63
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    • 1996
  • The results of the water purification studies using water parsley (Oenanthe javanica) were obtained as follows. The removal rate of nutrient salts increased with longer plant growth periods. The results of this study use the assumption, log(T+1) = $K(C_0-C)^A$, based on Prakish's Theory. The initial concentration was calculated from experimental data. A and K are closely related to the initial concentration. It is possible to model the concentration of residual salts, as time goes by, if concentration is constant. It was observed that water parsley neutralizes acid and alkali substances promptly. The maximum suitable neutralization period is 48 hours. But water parsley withered up in strong acid and alkali solutions within a week. The removal efficiency of Cd progresses in 2 steps, which are unrelated to the initial concentration of Cd. The first part of the curve shows the concentration rapid rate of Cd removal, followed by a levelling off. The removal rate of $NO_x-N$ in the sample water tank containing 0.5 ppm Cd was between 50~80% but the removal rate was less than 20% for the higher concentration. On the other hand, increased amounts of $PO_4-P$ in the sample water tank from the third day on suspected that $PO_4-P$ was desorbed from the water parsley. The accumulation efficiency of Cd in plant was increased in proportion to the initial concentration of Cd. The accumulation phenomenon was observed in the tanks more than 50~100 times.

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Hybrid design method for air-core solenoid with axial homogeneity

  • Huang, Li;Lee, Sangjin;Choi, Sukjin
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.50-54
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    • 2016
  • In this paper, a hybrid method is proposed to design an air-core superconducting solenoid system for 6 T axial uniform magnetic field using Niobium Titanium (NbTi) superconducting wire. In order to minimize the volume of conductor, the hybrid optimization method including a linear programming and a nonlinear programming was adopted. The feasible space of solenoid is divided by several grids and the magnetic field at target point is approximated by the sum of magnetic field generated by an ideal current loop at the center of each grid. Using the linear programming, a global optimal current distribution in the feasible space can be indicated by non-zero current grids. Furthermore the clusters of the non-zero current grids also give the information of probable solenoids in the feasible space, such as the number, the shape, and so on. Applying these probable solenoids as the initial model, the final practical configuration of solenoids with integer layers can be obtained by the nonlinear programming. The design result illustrates the efficiency and the flexibility of the hybrid method. And this method can also be used for the magnet design which is required the high homogeneity within several ppm (parts per million).

Substantial Enhancement of the Response and Sensing Speed of WO3 Nanotubes Toward NO2 Gas by Au-functionalization

  • Ko, Hyunsung;Park, Sangbo;Hong, Taeseop;Park, Sunghoon;Lee, Chongmu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.369.1-369.1
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    • 2014
  • Au-functionalized $WO_3$ nanotubes were synthesized using ZnO nanowire templates. Transmission electron microscopy revealed the Au nanoparticles on the outer surface of a typical $WO_3$ nanotube ranged from 5 to 25 nm. The multiple networked Au-functionalized $WO_3$ nanotube sensors showed responses of 820-3, 924% in the $NO_2$ concentration range of 1-5 ppm at $300^{\circ}C$. These responses were approximately 5-12 fold higher than those observed for pristine $WO_3$ nanotube sensors over the same $NO_2$ concentration range. A model describing the gas sensing mechanism of Au-functionalized $WO_3$ nanotubes is discussed.

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Projected Climate Change Impact on Surface Water Temperature in Korea (기후변화에 따른 지표수의 수온 영향평가)

  • Ahn, Jong Ho;Han, Dae Ho
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.133-139
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    • 2010
  • Global human activities associated with the use of fossil fuels have aggravated climate change, increasing air temperature. Consequently, climate change has the potential to alter surface water temperature with significant impacts on biogeochemical cycling and ecosystems in natural water body. In this study, we examined temporal trends on historical records of surface water temperature, and investigated the air temperature/water temperature relationship and the potential water temperature change from an air temperature scenario developed with regional climate model. Although the temporal trends of water temperature are highly variable site-by-site, surface water temperature was highly dependent on air temperature, and has increased significantly in some sub-watersheds over the last two decades. The results presented here demonstrate that water temperature changes are expected to be slightly higher in river system than reservoir systems and more significant during winter than summer for both river and reservoir system. Projected change of surface water temperature will likely increase $1.06^{\circ}C$ for rivers and $0.95^{\circ}C$ for reservoirs during the period 2008 to 2050. Given the potential climatic changes, every $1^{\circ}C$ increase in water temperature could cause dissolved oxygen levels to fall every 0.206 ppm.

Effect of NO on Catalytic Soot Oxidation in Tight Contact with $Pt/CeO_2$ Using a Flow Reactor System ($Pt/CeO_2$ 촉매와 Tight Contact 한 상태의 Model Soot 산화에 NO가 미치는 영향에 관한 실험적 연구)

  • Lee, Dong-Il;Song, Chang-Hoon;Song, Soon-Ho;Chun, Kwang-Min
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.3
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    • pp.52-56
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    • 2011
  • Active regeneration in CDPF requires $O_2$ which regenerates soot at high temperature. However, small amount of NO can interrupt $O_2$ regeneration in CDPF. To verify this phenomena, soot oxidation experiments using a flow reactor with a $Pr/CeO_2$ catalyst are carried out to simulate Catalyzed Diesel Particulate Filter (CDPF) phenomena. Catalytic soot oxidation with and without small amount of NO is conducted under tight contact condition. As the heating rate rises, the temperature gap of maximum reaction rate is increased between with and without 50ppm NO. To accelerate the $NO_2$ de-coupling effect, CTO process is performed to eliminate interfacial contact for that time. As CTO process is extended, temperature which indicates peak reaction rate increases. From this result, it is found that small amount of NO can affect tight contact soot oxidation by removal of interfacial contact between soot and catalyst.

Evaluation of the location of the Outlets according to the Analysis of Ventilation conditions (환기상태 분석에 따른 급 배기구 위치 평가)

  • Moon, Yong-Jun;Kim, Hyouk-Soon;Kwak, Myong-Keun;Oh, Myung-Do
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1207-1212
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    • 2008
  • The purpose of this study is to evaluate the location of the outlets in the mechanical ventilation system installed in apartment. We performed the numerical analysis to estimate the ventilation effectiveness and the indoor $CO_2$ concentration considering the occupants and the condition with inlet and outlet in each room. From the numerical results, modified location of the outlets is about 10% high than designed one with respect to the ventilation effectiveness when the occupants are not considered. But designed location of inlet and outlet in living room and kitchen is better than modified one with respect to the reduction of $CO_2$ concentration in the living room and kitchen with occupants. In case of our model, Air change per hour (0.7) is not enough to sustain the acceptable criteria of $CO_2$ concentration (1000ppm) in the room with the occupants

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Macro-Kinetics of Biofiltration for Odor Control:Dimethyl Disulfide

  • Kim, Jo-Chun;Bora C. Arpacioglu;Eric R. Allen
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E3
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    • pp.165-174
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    • 2002
  • A dual -column biofilter system with two different composts was used to investigate the macro-kinetics of dim-ethyl disulfide (DMDS) degradation. The biofilter columns were filled with compost mixtures up to one meter, The gas How rate and DMDS concentration to the biofilters were varied to study their effect on the removal characteris-tics of DMDS. It was found that the biodegradation of DMDS was governed by zero-order reaction -limited macro-kinetics for inlet DMDS concentrations between 10 and 55 ppmv. The overall average zero-order kinetic coeffi-cient for DMDS removal by compost was 0.50 ($\pm$0.1) ppm/sec for both compost mixtures studied. Variations in individual kinetic coefficients were observed due to varying environmental conditions, such as pH and temperature. The kinetic coefficients determined are specific to the system discussed in this work. During high acidity conditions in the filter beds, methyl mercaptan (MM) was observed in the gas samples collected. Appearance of MM was pro-bably due to decreased microbial activity in the lower portions of the biofilter. Considering the neutral pH range required and the presence of methyl mercaptan, it is likely that the microorganisms present in the biofilters used in this research are similar to the T. thioparus (strain E6) species.

Recommended Evacuation Distance for Offsite Risk Assessment of Ammonia Release Scenarios (냉동, 냉장 시스템에서 NH3 누출 사고 시 장외영향평가를 위한 피해범위 및 대피거리 산정에 관한 연구)

  • Park, Sangwook;Jung, Seungho
    • Journal of the Korean Society of Safety
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    • v.31 no.3
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    • pp.156-161
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    • 2016
  • An accident of an ammonia tank pipeline at a storage plant resulted in one death and three injuries in 2014. Many accidents including toxic gas releases and explosions occur in the freezing and refrigerating systems using ammonia. Especially, the consequence can be substantial due to that the large amount of ammonia is usually being used in the refrigeration systems. In this study, offsite consequence analysis has been investigated when ammonia leaks outdoors from large storages. Both flammable and toxic effects are under consideration to calculate the affected area using simulation programs for consequence analysis. ERPG-2 concentration (150 ppm) has been selected to calculate the evacuation distance out of various release scenarios for their dispersions in day or night. For offsite residential, the impact area by flammability is much smaller than that by toxicity. The methodology consists of two steps as followings; 1. Calculation for discharge rates of accidental release scenarios. 2. Dispersion simulation using the discharge rate for different conditions. This proactive prediction for accidental releases of ammonia would help emergency teams act as quick as they can.