• Title/Summary/Keyword: PP2A

Search Result 1,080, Processing Time 0.029 seconds

Ultrasonic degradation of polypropylene and its application for the development of PP based copolymer and nanocomposite

  • Ryu, Joung-Gul;Lee, Pil-Soo;Kim, Hyungsu;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
    • /
    • v.13 no.2
    • /
    • pp.61-65
    • /
    • 2001
  • Thermoplastic nanocomposites based on the copolymers of polypropylene (PP)-polystyrene (PS) and organically modified montmorillonite (org-MMT) were produced by using power ultrasonic wave in an intensive mixer. Owing to the unique action of the ultrasonic wave, free radicals of styrene monomers and macroradicals of PP were generated, by which copolymers of PP and PS were formed. Another important aspect of using ultrasonic wave during the mixing process was to enhance nano-scale dispersion of org-MMT by destructing the agglomerates of org-MMT in the polymer matrix. Optimum conditions for the in-situ copolymerization and melt intercalation were studied with various concentrations of styrene monomer, sonication time and different kinds of clay. It was found that a novel attempt carried out in this study yielded further improvement in the mechanical performance of the nanocomposites compared to those produced by the conventional melt mixing process.

  • PDF

Maleic Anhydride Effect on the Properties of Poly(ethrlene terephthalate)/Maleic Anhydride-Grafted PP/Poly(styrene-co-maleic anhydride) Ternary Blends (Poly(ethylene terephthalate)/Maleic anhydride-grafted PP/Poly(styrene-co-maleic anhydride) 삼상블렌드의 성질에 있어서의 무수말레인산의 효과)

  • 윤관한;이형욱;박오옥
    • Polymer(Korea)
    • /
    • v.25 no.2
    • /
    • pp.226-232
    • /
    • 2001
  • The properties of poly(ethylene terephthalate) (PET)/maleic anhydride-grafted polypropylene (MAgPP)/poly(styrene-co-maleic anhydride)(PScMA) ternary blend were investigated. The ternary blend was immiscible based on the glass transition temperatures measured by dynamic mechanical analyzer (DMA). The degradation of MAgPP during melt mixing for 30 min at 280$^{\circ}C$ did not affect the properties of the ternary blend. The interaction among the components was confirmed from the rheological properties, which was increased with the PSCMA contents. In terms of the mechanical properties, it was observed to satisfy the mixture rule for a multiple system.

  • PDF

Concentrations of Progesterone and Estradiol in Peripheral Plasma during the Estrous Cycle and after Ovariectomy in Huanghuai Goats of High or Poor Prolificacy

  • Pang, X.S.;Wang, Z.Y.;Zhu, T.G.;Yin, D.Z.;Zhang, Y.L.;Meng, L.;Wang, F.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.23 no.2
    • /
    • pp.188-196
    • /
    • 2010
  • The objective of this study was to characterize the litter sizes in Huanghuai goats with high prolificacy (HP, five or more kids born per litter on at least one occasion), and to compare their peripheral blood concentrations of progesterone and estradiol with those of goats with poor prolificacy (PP, up to three kids born per litter on any occasion). The circulating concentrations of progesterone and estradiol were measured by radioimmunoassay from daily blood samples taken during natural estrus cycles and at 1-5 days after ovariectomy. Estrus was synchronized using two doses of a prostaglandin analog. Litter size for the HP goats increased up to a parity of five and decreased thereafter. The percentage of goats with litter sizes of $\geq$4 from parities 3 to 6 ranged from 44.5% to 58.3%. Although small differences in litter size were obtained for goats of parities three, four and six relative to five, parity five does had the highest mean litter size. Progesterone concentrations began to rise earlier and were higher in the HP than in the PP goats on most days of the luteal phase, but not during the follicular phase of the cycle or after ovariectomy. There was a significant difference between the two groups (p<0.05) in the magnitude of the progesterone plateau. Mean estradiol concentrations in the HP group remained significantly higher than in the PP group (p<0.05) during the estrus cycle. There were two estradiol peaks in the HP goats during the early luteal phase, but only one in the PP group. Measurements of individual corpora lutea (CL) in vitro showed that there was a greater prevalence of small CL (<6 mm in diameter) in the HP group than in the PP group (p<0.05). After ovariectomy, the estradiol level on day 1 was significantly higher than at the nadir during the estrus cycle in both the HP (p<0.01) and PP (p<0.05) goats, while levels decreased by 12.3% and 26.2% respectively compared with the mid-luteal period in HP and PP goats (p<0.05). The overall mean estradiol concentrations in HP goats were lower than in the PP group, but no significant differences were found between groups at 1-5 days after ovariectomy.

Analysis of Program Providers(PP) in Terms of Theory of Industrial Organization in Korea (국내 프로그램공급업의 산업조직론적 분석)

  • Yeo, Hyun-Chul;Kim, Young-Soo
    • The Journal of the Korea Contents Association
    • /
    • v.10 no.5
    • /
    • pp.229-240
    • /
    • 2010
  • Most of all researchs and analyses in the field of television industry of Korea were related to Cable Television SO(System Operator), but few about PP(Program Provider) from the viewpoint of Industrial Theory in Korea. However, there wasn't a comprehensive research analysis in terms of the co-relationship of the market structure, market conduct and market performance of PP. This research analyzes co-relationship and dynamics of the market structure of PP, its market conduct and market performance in a comprehensive way in Cable TV industry. Especially this paper focuses on the analysis of 1)relationship and its influence between market structure and market conduct, 2) relationship and its influence between their market conducts and market performances and 3) relationship and its influence between market structure and market performance among 40 commercial PPs in terms of the theory of Industrial Organization in Korea. This paper is delated and reported as follows in conclusion : 1)the type of horizontal integration has an effect on the price and scale in the relationship between the structure and its conduct. 2)the price has effect on the revenue and viewing rate between the conduct and performance. And high dependency of the Cable TV license fee has an effect on viewing rate and revenue per subscribers(ARPU) between the conduct and performance. 3)The horizontal integration between the structure and performance had a positive effect on viewing rate and its product differentiation has an effect on the revenue per subscribers. Net cost of the product had a negative effect on the rate of profit.

A Study on Material Separation of Heavy Group Plastics by Triboelectrostatic Separation (마찰하전형(摩擦荷電型) 정전선별(靜電選別)에 의한 고비중(高比重) 플라스틱 혼합물(混合物)의 재질분리(材質分離)에 관한 연구(硏究))

  • Jeon, Ho-Seok;Baek, Sang-Ho;Park, Chul-Hyun;Kim, Byoung-Gon
    • Resources Recycling
    • /
    • v.16 no.2 s.76
    • /
    • pp.56-62
    • /
    • 2007
  • In this study, we carried out the research on triboelectrostatic separation for heavy group plastics (PET, PVC) recovered from wet gravity separation. From the research on charging characteristic for the choice of charging materials, it was found that PP was optimum charging material to make high charging amount with opposite polarity for PET and PVC of heavy group. Therefore, we manufactured a charger of cyclone type using PP material for separation of PET and PVC. At optimum test conditions that used PP cyclone charger developed in this study, we developed a triboelectrostatic separation technique that can separate PET plastic up to grade of 98.5% and recovery of 86.2%. We established new separation technology that could recycle the PET and PVC heavy group plastics recovered from wet gravity separation.

Value Ecosystems of Web Services : Benefits and Costs of Web as a Prosuming Service Platform (Web1.0과 프로슈밍기반 Web2.0 서비스 가치생태계 비교)

  • Kim, Do-Hoon
    • Journal of the Korean Operations Research and Management Science Society
    • /
    • v.36 no.4
    • /
    • pp.43-61
    • /
    • 2011
  • We first develop a value ecosystem framework to model the SDP(Service Delivery Process) of web services. Since the web service has been evolving from the basic web architecture (e.g., traditional world wide web) to a prosuming platform based on virtualization technologies, the proposed framework of the value ecosystem focuses on capturing the key characteristics of SDP in each type of web services. Even though they share the basic elements such as PP(Platform Provider), CA(Customization Agency) and user group, the SDP in the traditional web services (so-called Web1.0 in this paper) is quite different from the most recent one (so-called Web2.0). In our value ecosystem, users are uniformly distributed over (0, ${\Delta}$), where ${\Delta}$��represents the variety level of users' preference on the web service level. PP and CA provide a standard level of web service(s) and prosuming service package, respectively. CA in Web1.0 presents a standard customization package($s_a$) at flat rate c, whereas PP and CA collaborate and provide customization service with a usage-based scheme. We employ a multi-stage game model to analyze and compare the SDPs in Web1.0 and Web2.0. Our findings through analysis and numerical simulations are as follows. First, the user group is consecutively segmented, and the pattern of the segmentations varies across Web1.0 and Web2.0. The standardized service level s (from PP) is higher in Web1.0, whereas the amount of information created in the value ecosystem is bigger in Web2.0. This indicates the role of CA would be increasingly critical in Web2.0: in particular, for fulfilling the needs of prosuming and service customization.

Interfacial and Surface Energies Evaluation of Modified Jute and Hemp Fibers/Polypropylene (PP)-Maleic Anhydride Polypropylene Copolymers (PP-MAPP) Composites using Micromechanical Technique and Contact Angle Measurement (미세역학시험법과 접촉각 측정을 통한 변형된 Jute와 Hemp섬유 강화 Polypropylene (PP)-Maleic Anhydride Polypropylene Copolymers (PP-MAPP) 복합재료의 계면 및 표면에너지 평가)

  • Park, Joung-Man;Son, Tran Quang;Jung, Jin-Gyu;Kim, Sung-Ju;Hwang, Byung-Sun
    • Journal of Adhesion and Interface
    • /
    • v.7 no.2
    • /
    • pp.1-11
    • /
    • 2006
  • Interfacial evaluation of the untreated and treated Jute and Hemp fibers reinforced different matrix polypropylene-maleic anhydride polypropylene copolymer (PP-MAPP) composites were investigated by micromechanical technique and dynamic contact angle measurement. For the statistical tensile strength of Jute and Hemp fibers, bimodal Weibull distribution was fitted better than the unimodal distribution. The acid-base parameter on the interfacial shear strength (IFSS) of the natural fiber composites was characterized by calculating the work adhesion, $W_a$. The effect of alkaline, silane coupling agent on natural fibers were obtained with changing MAPP content in PP-MAPP matrices. Alkaline treated fibers made the surface energy to be higher due to removing the weak boundary layers and thus increasing surface area, whereas surface energy of silane treated Jute and Hemp fibers decreased due to blocked high energy sites. MAPP in the PP-MAPP matrix caused the surface energy to increase due to introduced acid-base sites. Microfailure modes of two natural fiber composites were observed clearly differently due to different tensile strength of natural fibers.

  • PDF

A Ground Penetrating Radar Detection of Buried Cavities and Pipes and Development of an Image Processing Program (지반 공동 및 매립관의 지반 투과 레이더 탐사 및 이미지 처리 프로그램 개발)

  • Lee, Hyun-Ho
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.5 no.2
    • /
    • pp.177-184
    • /
    • 2017
  • Many ground subsidence accidents have happened in Korea. The accident was caused by the subsidence and leakage of the deteriorated sewage pipe. This study aims to establish the empirical data of the ground penetration radar(GPR) detection for ground subsidence. A test bed was also manufactured for the same purpose. The GPR detection variables are embedment depth and horizontal distance of embedded cast iron pipe and expanded polystyrene(EPS). From the detection results, the EPS embedded by a depth of 1.5m was difficult for detection. The EPS closely embedded to the cast iron pipe within a 0.5m distance had a very strong cast iron pipe signal. Therefore, the detection was impossible. This study developed an image processing program, called the GPR image processing program(GPRiPP), to process the GPR detection results. Its major function is the gain function, which amplifies the wiggle wave signal. Compared to the existing programs, the GPRiPP is capable of showing a similar image processing performance.

Plasma Polymerized Styrene for Gate Insulator Application to Pentacene-capacitor (유기박막트랜지스터 응용을 위해 플라즈마 중합된 Styrene 게이트 절연박막)

  • Hwang, M.H.;Son, Y.D.;Woo, I.S.;Basana, B.;Lim, J.S.;Shin, P.K.
    • Journal of the Korean Vacuum Society
    • /
    • v.20 no.5
    • /
    • pp.327-332
    • /
    • 2011
  • Plasma polymerized styrene (ppS) thin films were prepared on ITO coated glass substrates for a MIM (metal-insulator-metal) structure with thermally evaporated Au thin film as metal contact. Also the ppS thin films were applied as organic insulator to a MIS (metal-insulatorsemiconductor) device with thermally evaporated pentacene thin film as organic semiconductor layer. After the I-V and C-V measurements with MIM and MIS structures, the ppS revealed relatively higher dielectric constant of k=3.7 than those of the conventional poly styrene and very low leakage current density of $1{\times}10^{-8}Acm^{-2}$ at electric field strength of $1MVcm^{-1}$. The MIS structure with the ppS dielectric layer showed negligible hysteresis in C-V characteristics. It would be therefore expected that the proposed ppS could be applied as a promising dielectric/insulator to organic thin film transistors, organic memory devices, and flexible organic electronic devices.

Morphological study of pulmonary arterioles in patients with ventricular septal defect associated with pulmonary hypertension (폐동맥고혈압을 동반한 심실중격결손증 환자의 폐세동맥의 형태학적 고찰)

  • 조범구
    • Journal of Chest Surgery
    • /
    • v.17 no.3
    • /
    • pp.339-345
    • /
    • 1984
  • Thirty four patients with a ventricular septal defect, aged 2 months to 24 years [median 2.33 years], had lung biopsies during open heart procedures to assess the degree of pulmonary vascular disease. The patients were divided into two groups according to their age; group 1 - under 2 years of age [15 patients], and group 2- over 2 years of age [19 patients]. The, pathologic change of the pulmonary arterioles was correlated with pre-operative hemodynamic data in 34 patients. There was no significant correlation between the severity of pulmonary vascular disease according to Heath-Edwards classification and the patients age [X2=1.8381, P=0.1751 ]. There was a significant correlation between degree of medial wall thickness and arteriolar diameter and the level of preoperative peak pulmonary artery pressure and peak systemic artery pressure [Pp/Ps]. Also, there was a good correlation between the preoperative pulmonary vascular resistance and systemic vascular resistance [Rp/Rs]. There was no significant correlation between wall thickness and Pp/Ps, and Rp/Rs below the age of 2 years. We conclude that, in patients over 2 years of age, there was a significant correlation between the medial wall thickness of the pulmonary arteriole and elevation of Pp/Ps and Rp/Rs. This is not true in patients under 2 years of age.

  • PDF