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The Preparation and Electrochemical Properties of Homogeneous Anion-exchange Composite Membranes Containing Acrylonitrile-butadiene Rubber (Acrylonitrile-butadiene rubber를 포함한 균질계 음이온교환 복합막의 제조 및 전기화학적 특성)

  • Song, Pu Reum;Mun, Hye Jin;Hong, Sung Kwon;Kim, Jeoung Hoon;Chang, Bong Jun
    • Membrane Journal
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    • v.24 no.6
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    • pp.463-471
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    • 2014
  • While poly(styrene)-based anion exchange membranes have the advantage like easy and simple manufacturing process, they also possess the disadvantage of poor durability due to their brittleness. Acrylonitrile-butadiene rubber was used here as an additive to make the membranes have improved flexibility and durability. For the preparation of the anion exchange membranes, a PP mesh substrate was immersed into monomer solutions with vinylbenzyl chloride, styrene, divinylbenzene and benzoyl peroxide, then thermally polymerized & crosslinked. The prepared membranes were subsequently post-aminated using trimethylamine to result in $-N+(CH_3)_3$ group-containing composite membranes. Various contents of vinylbenzyl chloride and acrylonitrile-butadiene rubber were investigated to optimize the membrane properties and the prepared membranes were evaluated in terms of water content, ion exchange capacity and electric resistance. It was found that the optimized composite membranes showed higher IEC and lower electric resistance than a commercial anion exchange membrane(AMX) and have excellent flexibility and durability.

Cultural and Physiological Conditions for T-2 Toxin Production by Fusarium sp. (Fusarium 균주의 배양 조건 및 생리적 조건에 따른 T-2 toxin의 생성 조건)

  • 홍성희;양규환
    • Korean Journal of Microbiology
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    • v.36 no.2
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    • pp.91-96
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    • 2000
  • The cultural and physiological conditions for the T-2 toxin [4,15-diacetoxy-8-(3-mety1butyloxy)-12,13- epoxy-trichothec-9-en-3-01, $C_{24}H_{30}O_9$] production by Fusarium spp. were studied. Thin layer chromatography (TLC) assay and the microbiological assay uslng Rhodotomla rubra were used to quantitate tbe T- 2 toxin. Among the four strains of Fusarium spp., F tn'cinctum NRRL 3299 was best for T-2 toxin production. In solid culture, white com grit medium was best for T-2 toxm production. Temperature played a critical role in the production of T-2 toxin. T-2 toxin production was favored by long duration of low-temperature incubation. The growth and toxin production were relatively high on galactose, fructose, glucose, and sucrose media, when each was used as a sole carbon source, and relatively low on sorbitol, glycerol, and lactose media. For nitrogen sources, $NH_4^(+) and NO_3^{-}were used well as a sole nitrogen source, but $NO_2^-$ was not used. Initial pH and speed of shaker also affected the production of T-2 toxin. From temperature shifting experiment, it is clear that T-2 toxin metabolic pathway is regulated by temperature-dependent enzyme depression or enzyme induction system.

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하계 경기만의 수질오염과 생산력에 관한 연구 1

  • 이민재;홍순우;하영칠
    • Korean Journal of Microbiology
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    • v.10 no.3
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    • pp.97-104
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    • 1972
  • The extent of water pollution was investigated at 4 stations in Kyonggi Bay during the summer seasons in 1970 and 1971. The concentrations of dissolved oxygen, total hardness, ammonia, nitrate, nitrite, phosphate, chemical oxygen demand, salinity, biochemical oxygen demand, coliform bacteria and facel coli were examined together with the measurement of pH and transparency. The relationship between the extent of pollution and the distance from the Inchon Bay also was examined. The concentrations of biochemical oxygen demand, chemical oxygen demand, ammonia, nitrate, nitrite, phosphate, coliform bacteria nad fecal coli were all highest at station 1, and lowest at station 4. Values were somewhat higher at low tide level in general. On the contrary, dissolved oxygen concentration was highest at station 4 and lowest at station 1. The highest and lowest values of biochemical oxygen demand were 10.88 ppm at station 1 and 0.27 ppm at station 4. The chemical oxygen demand concentrations at station 1 and 4 were 1.90 ppm and 0.63 ppm. Ammonia concnetration at station 1 was 0.43 pp, and was nearly 5 times as much as that at station 4. The values were $2.45{\times}10^{-4}$ ppm at station 1, and $6{\times}10^{-4}$ ppm at station 4. Nitrite concnetration at station 1 was $3{\times}10^{-4}$ppm and was the highest, while the lowest was $9.45{\times}10^{-5}$ ppm at station 4. Phosphate value at station 1 too was the highest and was about 4 times as much as that at station 4. Coliform bacteria were most abundant at station 1, and were counted to be 1.$1.7{\times}10^{-5}$cells/ml. At station 4, the number greatly reduced to 8 * 10$^{2}$ cells/ml. The number of fecal coli at station 1 was $2{\times}10^{-4}$ cells/ml. But at station 4, no fecal coli was detected at high tide level. At low tide level, 3 cells/ml were counted at station 4. In all of these, the highest data were obtained at low tide level, while most of the lowest value, at high tide level. Generally, values at statio 1 were 3-5 times as much as those at station 4. Concentration of dissolved oxygen at station 1 was 0.366 mg-atoms/1 and was the lowest. The highest value was 0.420 mg-atoms/1 and was recorded at station 4. The highest at station 4, which certainly were believed to be the result of the dilution by the fresh water of the Han river flowing into the Inchon Bay. As we can see from the data above, the extent of pollution was highest at station 1, the nearest from Inchon harbor, and lowest at station 4, where is the farthest, Station 1 and 2 were proved to be much polluted, but station 3 and 4, not.

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PIV Measurements of Wake behind a KRISO 3600TEU Container Ship Model (PIV를 이용한 KRISO 3600TEU 컨테이너선모형선의 반류 측정 및 해석)

  • Sang-Joon Lee;Min-Seok Koh;Choung-Mook Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.39 no.3
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    • pp.48-56
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    • 2002
  • The flow characteristics around KRISO 3600TEU container ship model have been experimentally investigated in a circulating water channel. The instantaneous velocity vectors were measured using 2-frame PIV measurement system. The mean velocity fields and turbulent statistics including turbulent kinetic energy and vorticity were obtained by ensemble-averaging 400 instantaneous velocity fields. The free stream velocity was fixed at 0.6m/s and the corresponding Reynolds number was $9{\times}10^5$. The test sections were divided into two regions, three transverse sections of the wake region(Station -0.5767, -1, -3) and five longitudinal sections of the wake((Z/(B/2)=0, 0.1, 0.2, 0.4, 0.6). In the wake region, large-scale longitudinal vortices of nearly same strength are symmetric with respect to the wake centerline and a relatively weak secondary vortex is formed near the waterline. With going downstream, the strength of longitudinal vortex is decreased and the wake region expands.

An Evaluation of Broadcaster Licensing Policy in Korea since 1990 (1990년 이후 방송사업자 인허가정책에 대한 평가)

  • Jung, In-Sook
    • Korean journal of communication and information
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    • v.18
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    • pp.199-229
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    • 2002
  • This study analyzed the trends of broadcaster licensing policy during 1990-2001 in Korea. It is to seek the answers about how the examination standards and procedures applied to broadcaster licensing has been changed for the last decade. For the purpose this study inquired six cases such as private broadcasting licence (1990 October), cable TV program provider licences(1993 July), cable TV system operator licences(1994 January), private local broadcaster licences(1994 July), satellite broadcaster licence(2000 December) and cable TV home shopping channel licences(2001 March). It examined the degree of specification and measurement of the standards based upon the government white paper; average points per item, average points per quantitative item, and average points per qualitative item etc. The government hadn't opened the standards and procedures how it licensed broadcasters until 1990 and the uncertain attitude brought distrust on the government broadcasting policy. The first white paper about broadcaster licensing was made in 1994 after cable TV broadcaster licensing was finished. The results indicated that Korean broadcasting licensing policy rapidly developed in the dimension of transparency from 'a secret room policy' to 'a sunshine policy' for the last decade. But it still needs improvement in the dimension of fairness of examination. Now one of the main distrust is the ratio that the one of qualitative examination standards are much more than the qualitative one.

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Development of Forms for Cold Weather Concrete by Combination of Insulation (단열재 조합에 의한 한중콘크리트용 거푸집 개발)

  • Han, Cheon-Goo;Oh, Seon-Kyo;Sin, Dong-An;Kim, Kyoung-Min
    • Journal of the Korea Concrete Institute
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    • v.15 no.3
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    • pp.392-399
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    • 2003
  • This paper discusses the validities of insulating curing of cold weather concreting at early stage by applying insulation forms. Tests were carried out using modified insulating form combining existing insulating form and various other insulations in order to develop improved insulation form. Temperature history of concrete using various insulating forms and insulation was measured to determine most effective combination of insulting form. According to results, as for the wall form, under the curing temperature of $-10^{\circ}C$, the temperature of concrete using Euro form drops sharply before 24 hours and lasts below $0^{\circ}C$ for 7 hours. The temperature of concrete using the form combining Polypropylene panel, styrofoam and plywood panel keep above $0^{\circ}C$. And, it is confirmed that the form mentioned above has a favorable effects on enhancing strength development of concrete and the cost to make the forms shows more reasonable than that of existing forms. However, as for the combination methods of insulation form for slab, which is composed of insulating form at the bottom of slab and various surface curing materials at the top of slab, in case of exposed condition at the top of slab, temperature history of concrete goes below $0^{\circ}C$ after 10 hours. In case of the combination of vinyl sheet and curing blanket, it drops below $0^{\circ}C$ after 42 hours. However, in case of the combination of vinyl, styrofoam and curing blanket, it does not go below $0^{\circ}C$ until 55 hours. Accordingly, compared to the case of exposure and the combination of vinyl and curing blanket, it indicates that the combination mentioned above has more effective insulating performance.

Evaluation on Spalling Properties of Ultra High Strength Concrete with Melting and Vaporization of Fiber (유기섬유의 용융 및 기화에 따른 초고강도 콘크리트의 폭렬 특성 평가)

  • Kim, Gyu-Yong;Choe, Gyeong-Cheol;Lee, Joo-Ha;Lee, Seung-Hoon;Lee, Tae-Gyu
    • Journal of the Korea Concrete Institute
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    • v.24 no.2
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    • pp.173-183
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    • 2012
  • Recently, experimental studies to prevent explosive spalling based on spalling mechanism and addition of Polypropylene fiber in high strength concrete (HSC) are performed actively. However, with respect to ultra high strength concrete (UHSC), its compact internal structure is more difficult release vapor pressure at rapid rising temperature compared to HSC. Therefore, in this study, an experiment was conducted to evaluate spalling properties of UHSC using ${\Box}$ $100mm{\times}100{\times}H200mm$ rectangular specimen according to ISO-834 standard fire curve. With respect melting point of fiber, three fiber types of Polyethylene, Polypropylene, and Nylon fibers with melting temperature of $110^{\circ}C$, $165^{\circ}C$, and $225^{\circ}C$, respectively, were considered. Mixed fiber of 0.15% and 0.25% of concrete volume was used to consider spalling properties based on water vapor pressure release. Then, TGDTA test on fiber and FEM analysis were performed. The results showed that it is difficult to prevent initial spalling without loss of fiber mass even if fiber melting temperature is low. Also, in preventing thermal spalling, fiber that melts to rapidly create porosity within 10 minutes of fire is more effective than that of low melting temperature property of fiber.

Analysis of Input/Output Transfer Characteristic to Transmit Modulated Signals through a Dynamic Frequency Divider (동적 주파수 분할기의 변조신호 전송 조건을 위한 입출력 전달 특성 분석과 설계에 대한 연구)

  • Ryu, Sungheon;Park, Youngcheol
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.27 no.2
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    • pp.170-175
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    • 2016
  • In order to transmit baseband signals through frequency dividing devices, we studied the transfer function of the device in the term of the baseband signal distortion. From the analysis, it is shown that the magnitude of the envelope signal is related to the mixer gain and the insertion loss of the low pass filter whilst the phase is the additional function with the 1/2 of the phase delay. For the purpose of the verification of the study, we designed a dynamic frequency divider at 1,400 MHz. The operating frequency range of the device is closely related to the conversion gain of mixers and the amplitude of input signal, and becomes wide as the conversion gain of mixers increases. The designed frequency divider operates between 0.9 GHz and 3.2 GHz, for -14.5 dBm input power. The circuit shows 20 mW power dissipation at $V_{DD}=2.5V$, and the simulation result shows that an amplitude modulated signal at 1,400 MHz with the modulation index of 0.9 was successfully downconverted to 700 MHz.

Removal of PVC from Mixed Plastic Waste by Combination of Air Classification and Centrifugal Process (풍력(風力) 및 습식비중(濕式比重) 선별(選別)에 의한 혼합(混合)폐플라스틱 종말품(終末品)으로부터 PVC 제거(除去)에 관한 연구(硏究))

  • Choi, Woo-Zin;Yoo, Jae-Myung
    • Resources Recycling
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    • v.16 no.5
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    • pp.71-76
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    • 2007
  • The mixed plastic waste generated from households after hand-picking and/or mechanical sorting processes amounts to 1,750,000 ton in 2006, and most of these waste are finally end up with landfill and/or incineration due to the lacks of separation technologies and economical reasons. The mixed plastic wastes can not be used as raw materials for chemical and/or thermal recycling processes because of their high content of PVC(upto 4.0 wt.%). In the present research, gravity separation system has been developed to remove PVC from the mixed plastic waste and to recover the PO-type plastics. This system mainly consists of air classification, magnetic separation, one-step crushing, feeding system at fixed rate and wet-type gravity separation system. The gravity system based on centrifugal separation has been developed at capacity of 0.5 ton/h and it consists of mixing, precleaning, separation, dewatering, recovery system and wastewater treatment system, etc. The main objective of this process is to achieve high separation efficiency of polyolefins with less than 0.3 wt.% PVC content and less than 10% moisture content in the final products. In addition, a crushing unit of with 8 rotor system is also developed to improve the crushing efficiency of soft-type plastics. The system with a capacity of 1.0 ton/h is developed and operational results are presented.

Monitoring of pH and dissolved oxygen in microorganism fermentation processes using a 24-well microplate (24-웰 마이크로 플레이트를 이용한 미생물 발효공정에서 pH 및 용존산소의 모니터링)

  • Kim, Sun-Yong;Kim, Chun-Kwang;Sohn, Ok-Jae;Rhee, Jong-Il
    • KSBB Journal
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    • v.24 no.2
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    • pp.207-211
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    • 2009
  • In this study, the sensing membranes for detection of pH and dissolved oxygen(DO) were prepared by immobilizing 6-aminofluorescein or ruthenium complex onto the sol-gel matrixes of GPTMS, MTMS, and TEOS and then recoated with the mixture of hydrophobic sol-gel and graphite for light insulation. The pH and DO sensing membranes recoated with the light insulation layer showed a higher sensitivity than those without light insulation layer. The sensing membranes were immobilized on the wells of 24-well microplate and used to monitor the fluorescence intensity for pH and DO in E.coli JM109 and P.pastoris X-33 fermentation processes. The change of the fluorescence intensity in the DO sensing membrane agreed with the growth patterns of microorganisms, that the membranes are valuable to monitor the DO in fermentation processes. In the case of pH monitoring, the fluorescence intensity has showed good correlation to the off-line pH data, that the pH membranes are valuable to monitor pH values in fermentations.