• Title/Summary/Keyword: PP&S

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Study on the rheological properties of PP-SEBS/silicate composites (PP-SEBS/실리케이트 복합체의 유변학적 특성 연구)

  • Kim, Youn-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.4
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    • pp.1988-1992
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    • 2011
  • Polypropylene (PP)-SEBS/silicate composites with PP content of 35, 40, and 45wt% were fabricated by melt compounding at $200^{\circ}C$, using lab scale Brabender mixer. The content of silicate was fixed at 5wt%. The thermal properties of the PP-SEBS/silicate composites were investigated by differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA). The melting temperature of PP-SEBS compound decreased up to $141^{\circ}C$ with SEBS content. TGA result indicates an increase in degradation temperature when the silicate was added in the PP-SEBS compound. The rheological properties of the compounds were measured by dynamic Rheometer. PP-SEBS/silicate composite indicates higher shear thinning and elastic property than PP-SEBS compound. Van Gurp-Palmen analysis was applied in order to certify an increase in elasticity.

Melt and Recrystallization Behavior of Syndiotactic Polypropylene and Isotactic Polypropylene (신디오택틱 폴리프로필렌과 아이소택틱 폴리프로필렌의 용융과 재결정화)

  • Lee, Sang-Won;Huh, Wan-Soo;Hyun, Uk;Lee, Dong-Ho;Noh, Seok-Kyun
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.521-527
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    • 2003
  • It was found that polypropylene shows rearrangement of crystal structure during the melting process. For the analysis of recrystallization behavior, the change of dynamic mechanical property, crystallinity, and crystal structure were studied by DSC, FT-IR, SAXS, and DMA. Melt-recrystallization-remelting behavior of iPP was clearly observed when iPP was cooled down kom the melt more rapidly. Elastic modulus of iPP increased during the recrystallization process but crystallinity of iPP shows constant value. Furthermore, the full width of half mean of SAXS pattern decreased about 30%, and intra-lamella ordering of iPP increased during the melt process but is was not found for sPP.

A Study on the PP/PS Blends with Nylon 6 Reactive Compatibilizers (Nylon6계 반응 상용화제에 의한 PP/PS 블렌드에 관한 연구)

  • 서성식;이기윤;김성희;김동철;이승구
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.71-79
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    • 2002
  • RPP(maleic-anhydride grafted PP)and OPS(oxazoline grafted PS) do not react to each other, and thus show immiscibility. In this study, Nylons was added to RPP/OPS blend systems, as a reactive compatibilizer for enhancing the miscibility of the blends. When Nylon6 was added to the blends of RPP and OPS, RPP/Nylon6/OPS was produced. The effects of the molar ratio of Nylon6 on the RPP-Nylon6-OPS reaction were studied. Torque test and FT-IR analysis have been carried out to investigate the reaction of RPP/Nylon6/OPS system. The reaction torgue ratio and reaction efficiency show the maximum values at 1 : 0.66 : 1 and 1 : 1 : 1 (in moles) for RPP/Nylon6/OPS. In the RPP/Nylon6/OPS blends, their mechanical properties were changed with the molar ratio of Nylon6 and showed the highest value at molar ratio of 1.5. Physical properties and compatibility of RPP/Nylon6/OPS were compared with those of PP/Nylon6/OPS. Consequently, RPP/Nylon6/OPS plays a proper role as a reactive compatibilizer to the PP/PS blend system.

Changes in Color Response of MTT formazan by Zinc Protoporphyrin (MTT formazan의 발색에 미치는 zinc protoporphyrin의 영향)

  • Park, Kyung-A;Choi, Hyun-A;Kim, Mi-Ri;Choi, Yoo-Mi;Kim, Hyun-Jung;Hong, Jung-Il
    • Korean Journal of Food Science and Technology
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    • v.43 no.6
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    • pp.754-759
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    • 2011
  • Zinc protoporphyrin (ZnPP) is produced endogenously during heme metabolism and treated in cells as a heme oxygenase inhibitor. In the present study, the effects of ZnPP on the color response of 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay, a commonly-used method for analyzing cell viability, were investigated. ZnPP induced rapid decolorizaion of MTT formazan under light; the degradation rates were 10- and 20- folds faster in the presence of 5 and $10{\mu}M$ ZnPP, respectively. Methylene blue (MB), another type of photosensitizer, also accelerated degradation of formazan under light. Butylated hyroxytoluene did not inhibit ZnPP- or MB-induced formazan degradation. The color degradation of formazan dye was signficantly delayed in the presence of N-acetylcysteine or ${\beta}$-carotene. The present results suggest that certain photosensitizing compounds may affect the color and stability of MTT formazan, which should be carefully considered when conducting the MTT assay.

Tunneling Layer의 두께 변화에 따른 유기 메모리의 특성

  • Kim, Hui-Seong;Lee, Bung-Ju;Sin, Baek-Gyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.366-366
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    • 2013
  • 건식 박막증착 공정인 플라즈마 중합법을 이용하여 유기 재료인 Styrene을 절연 박막으로 제작하였다. 플라즈마 중합된 Styrene (ppS) 절연 박막의 정밀한 공정 제어를 위해 bubbler와 circulator를 이용하여 습식 공정과 비교하여도 절연 특성이 뛰어난 pps 절연 박막을 증착하고, 이를 활용하여 gate 전극으로 ITO, insulator layer로 pps, floating gate로 Au, tunneling layer로 ppMMA와 pps, semiconductor로 Pentacene, source/drain 전극으로 Au를 사용한 비휘발성 메모리 소자를 제작하였다. ppMMA와 pps의 서로 다른 tunneling layer의 두께 변화에 따른 비휘발성 메모리 특성 변화를 연구하였다.

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Development and Properties of Rubber Sheet using Thermoplastic Elastomer (열가소성 고무를 사용한 RUBBER SHEET의 제조 및 물성)

  • Chun, Seung-Han;Han, Min-Hyeon;Mun, Il-Sik
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.122-127
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    • 2003
  • Compounding, using such thermoplastic elastomer as styrene-ethylene-butadiene-styrene (SEBS) blended with polypropylene(PP), oil, and other ingredients, was studied to develop a new material with excellent impact resistance and resilience for the replacement of environmentally toxic PVC sheet. Hardness decreased linearly with oil content in the SEBS/oil blend, and the tensile strength increased with PP content whereas elongation showed no effects over 50 phr of PP in SEBS/oil/PP blend. In the practical SEBS composition, proposed to replace the PVC sheet material, tensile and tear strength, as well as hardness, increased proportionally with PP content, while melt index decreased.

A study on the design of the boosted voltage cenerator for low power DRAM (저전력 DRAM 구현을 위한 boosted voltage generator에 관한 연구)

  • 이승훈;주종두;진상언;신홍재;곽계달
    • Proceedings of the IEEK Conference
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    • 1998.06a
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    • pp.530-533
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    • 1998
  • In this paper, a new scheme of a boosted voltage generator (BVG) is designed for low powr DRAM's. The designed BVG can supply stable $V_{pp}$ using a new circuit operting method. This method controls charge pumping capability by switching the supply voltage and ring oscillator frequency of driving circuit, so the BVG can save area and reduce the powr dissipation during $V_{pp}$ maintaining period. The charge pumping circuit of the BVG suffers no $V_{T}$ loss and is to be applicable to low-voltage DRAM's. $V_{pp}$ level detecting circuit can detect constant value of $V_{pp}$ against temperature variation. The level of $V_{pp}$ varies -0.55%~0.098% during its maintaining period. Charge pumping circuit can make $V_{pp}$ level up to 2.95V with $V_{cc}$ =1.5V. The degecting level of $V_{pp}$ level detecting circuit changes -0.34% ~ 0.01% as temperature varies from -20 to 80.deg. C. The powr dissipation during V.$_{pp}$ maintaining period is 4.1mW.W.1mW.

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Quality Changes in Mushrooms (Agaricus bisporus) due to Their Packaging Materials during Their Storage (포장재에 따른 양송이버섯의 저장 중 품질변화)

  • Lee, Da-Uhm;Chang, Min-Sun;Cho, Sun-Duk;Jhune, Chang-Sung;Kim, Gun-Hee
    • Food Science and Preservation
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    • v.20 no.1
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    • pp.7-13
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    • 2013
  • Mushrooms have a shorter shelf-life than most vegetables because of their very high respiration rates, sensitivity to enzymatic browning and susceptibility to microbial spoilage. This study was conducted to investigate effects of various packaging materials and precooling on the quality of mushrooms (Agaricus bisporus). Mushrooms were precooled at $4^{\circ}C$ for three hours and packaged using the following packaging materials; 1) polyethylene (PE) film bags of 0.03 mm thickness, 2) polypropylene (PP) film bags of 0.03 mm thickness, and 3) polystyrene (PS) tray+polyvinyl chloride (PVC) wrapper. The physiological changes (weight loss, gas composition, color, firmness, and sensory evaluation) associated with postharvest deterioration were monitored for 17 days at $10^{\circ}C$. The results showed that the PP film bag maintained quality of mushrooms most effectively, especially PP film bags inhibited decreasing firmness. The samples also exhibited smaller decreases in weight loss rate (0.57%) and Hunter L value (84.44) than PS tray+PVC wrapper (7.73%, 82.19) and PE film bags (0.89%, 82.96). Sensory evaluation level in all samples remained relatively constant during the first 5 days of storage. However, PE film bags and PS tray+PVC wrapper showed lower score of flavor, texture and color than PP film bags after 8 days of storage. This study suggested that PP film bag packaging effectively extends shelf-life of mushrooms during storage.