• Journal of the Korean Society of Clothing and Textiles
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• v.10 no.1
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• pp.105-111
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• 1986

본 연구에서는 연신정도가 다른 완전배향사(FDY)와 부분배향사(POY)를 열처리시켜 내부구조변화를 유도한 후 염색성을 연구하였고, 염색성과의 관련성을 위해 결정화도 및 복굴절룰을 조사하였다. 열처리는 silicone oil속에서 정장상태로 실시하였으며, 시료의 염색은 Disperse Yellow 42를 이용해 무한염욕상태에서 실시하였다. 그리고, DMF를 이용해 염료를 추출시킨후 spectrophotometer 로 염료흡착량을 측정하였다. 결정화도는 밀도-결정화도 관계식으로 구하였으며, 복굴전률은 편광현미경으로 시료의 두께와 retardation을 측정한 후 계산하였다. FDY와 POY 필라멘트사의 염색성은 열처리시 감소하였으며 POY의 염색성이 FDY보다 우수했다. 결정화도는 열처리시 증가하였으며 열처리되지 않은 POY가 열처리되지 않은 FDY에 비해 낮은 값을 나타냈다. 복굴절률은 열처리시 증가하였으며 열처리되지 않은 POY가 열처리되지 않은 FDY에 비해 낮은 값을 나타냈다. 열처리후에도 POY가 FDY보다 낮은 복굴절률을 나타낸 반면 결정화도는 열처리된 POY가 열처리된 FDY와 비슷한 값을 나타냈다. 염색성은 결정화도와 배향도에 부적인 상관관계 즉 결정화도와 배향도가 증가함에 따라 염색성은 감소하는 관계를 시사했다.

• Proceedings of the Korean Society for Emotion and Sensibility Conference
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• 2001.11a
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• pp.19-24
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• 2001

본 연구에서는 국내 7개 기업에서 생산되고 있는 PET POY와 일본과 대만에서 생산되고 있는 PET POY 시료를 준비하여 이들 사의 열수축 특성을 hank 실험방법과 Toray FTA-500 계측기를 사용한 실험 data를 비교 분석하여 최근 도입되어 사용되고 있는 Toray FTA-500 열 수축률 측정계측기의 타당성을 조사하고자 한다. 본 연구를 위해 사용한 시료는 PET POY 85d/72f 그리고 120d/36f 그리고 120d/36f 2가지를 준비했으며 국내 합섬 maker 7개회사별로 각각 같은 굵기의 POY 사를 준비하였다. 그리고 국내 POY와 외국 소재로서 대만과 일본에서 생산되고 있는 소재의 열 수축률 특성치를 Toray FTA-500과 hank 방법을 비교 분석하므로서 감성의류 제조용 PET POY 사의 국내ㆍ외 소재의 차이점을 계측기계와 계측방법의 상이로 나누어 data화가 가능케 함으로서 감성의류소내 개발에 기초자료를 활용코자 한다.

• Science of Emotion and Sensibility
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• v.10 no.1
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• pp.69-77
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• 2007

This study surveys wet and dry thermal shrinkages of PET POY manufactured by domestic seven companies and foreign companies in Japan and Taiwan. These thermal shrinkages were measured by hank method (KSK 0215) and foray FTA-500 apparatus, and these measured data were analysed and discussed with measuring methods. The specimens prepared were PET POY 85d/72f and 120d/36f, furthermore, 250d/48f and 155d/50f PET POY were also prepared for comparison of wet and dry thermal shrinkages between Japan and domestic PET POY. And the wet and dry thermal shrinkages of each specimens were measured according to the each layer divided by 50,000m of the cake, and between and within thermal shrinkages were analysed and discussed with the domestic and foreign PET POY and measuring methods such as hank ant Toray methods.

• Journal of the Korean Society of Clothing and Textiles
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• v.13 no.1 s.29
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• pp.43-47
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• 1989

The microstructural changes of nylon 6 UDY, POY and FDY were compared after free-annealing through crystallinity, birefringence, and melting behavior analyses. Free-annealing was done at various temperatures $(120^{\circ}C\;,140^{\circ}C,\;160^{\circ}C,\;180^{\circ}C,\;200^{\circ}C)$ and times (15 min., 30 min., 60 min.) using vaccum oven. Crystallinity was measured by the density gradient column technique and birefringence was measured using a Nikon polarizing microscope with a quartz wedge and Senarmont compensator. Melting behavior was investigated on the basis of DSC melting corves. Crystallinites of specimens increased as the treatment temperature and time increased. Birefringence of UDY increased after annealing and increased as the treatment temperature increased. On the other hand, those of POY and FDY decreased after annealing. Especially, the changes of crystallinity and birefringence of treated POY were particularly lower than those of treated UDY and FDY. Melting peaks of untreated UDY, POY and FDY were different in the position and the shape, but little change was seen in melting peaks in spite of increasing the annealing temperature and time. UDY and FDY showed single melting peaks in all the specimens. But POY showed double melting peaks, which means the coexistences of crystals with different thermal properties.

• Journal of the Korean Society of Clothing and Textiles
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• v.17 no.1
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• pp.63-75
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• 1993

Partially oriented polyester yarn (PET POY) was treated in the unrestrained state using various solvents at different temperatures. Interactions between PET POY & solvents were estimated by the changes of microstructure, morphology and mechanical properties. The correlation between the changes of microstructure & morphology and the changes of mechanical properties was also studied. TCE, Dioxane, O-DCB, DMF, and BA were found to be active solvents, while Iso-AA and water were found to be weak solvents. PET POY was affected mainly by the solvents when treated with active solvents and affected mainly by heat when treated with weak solvents. Changes by the solvent treatment in microstructure and morphology were : an increase in crystallinity, a change in birefringence, a shrinkage in length, and a change in DSC curve. As for the changes in mechanical properties, findings in the PET POY when treated with solvents were : a decrease in stress-at-break, a change in yield stress, an increase in strain-at-break & yield strain, and a decrease in initial modulus. Changes in microstructure and morphology directly affected the mechanical properties.

• Textile Coloration and Finishing
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• v.12 no.2
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• pp.103-110
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• 2000

To examine the physical properties of POY through the microstructure control, the crystal structure such as the crystallinity, the crystallite size, the orientation, the shrinkage, the tensile properties, and the thermal stress of POY(80/48, SD) were examined at different draw ratios and annealing temperatures. From the examination following conclusions were obtained : 1. The crystallinity was more effected by the heat setting temperature than by the draw ratio. The increasing rate was greatest at the heat setting temperature range of $170~190^\circ{C}$. 2. The crystallite size perpendicular to the fiber axis was more effected by the annealing temperature at lower draw ratios. On the other hand, the crystal and amorphous orientations were more effected by the heat setting at higher draw ratios. 3. The boiling shrinkage did not change significantly, but the total shrinkage showed 13% at the draw ratio 1.9 and the heat setting temperature $170^\circ{C}$. 4. The maximum thermal stress increased with increasing the draw ratio and decreasing the heat setting temperature in the temperature range of $170~210^\circ{C}$. At the draw ratio 1.9 and the heat setting temperature $170^\circ{C}$, the maximum thermal stress found was 1.1gf/d. 5. In the heat setting temperature above $170^\circ{C}$ after the drawing, the crystallinity, the crystallite size, the orientation, and the strength increased with increasing temperature, but the shrinkage and the maximum thermal stress decreased with increasing temperature.

• Science of Emotion and Sensibility
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• v.10 no.2
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• pp.169-175
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• 2007

This study surveys the variation of the physical properties such as denier, tensile property and thermal shrinkage between seven domestic and foreign PET filaments manufactured by China and Taiwan. For this purpose, the specimens prepared were PET POY 239d/96f made in china, and PET POY 255d/48f made in Korea as a coarse filament. As a fine filament, 120d PET POY made by Taiwan, China and 6 domestic companies were prepared. The various physical properties such as yarn denier, yarn mechanical property and wet and dry thermal shrinkages were measured according to the each layer divided by 50,000m of the cake, and between and within yarn physical properties were analysed and discussed with the domestic and foreign yarns. These results provide fundamental data to the SME related to the yarn finishing and weaving for developing high added-value and high sensitive fabrics.

• Textile Coloration and Finishing
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• v.22 no.2
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• pp.140-144
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• 2010

In this study, we investigated the clean appearance and good stretch properties. Usually, clean appearance concerned with the dyeing properties of core and effect yarns. The dyeing properties between core yarn (conjugate yarn) and effect yarn were determined by the build-up and the color differences using the four different yarns of SDY FD(spindraw yarn full dull), SDY CD(spindraw yarn cation dyeable), POY FD( partially-oriented yarn full dull) and POY CD(partially-oriented yarn cation dyeable). We used the single color dye of C. I. Disperse Blue 79 and mixed colors made by C. I. Disperse Red 60, C. I. Disperse Blue 56, and C. I. Disperse Yellow 54.

• Textile Coloration and Finishing
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• v.16 no.6
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• pp.35-43
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• 2004

This study surveys the physical properties of ATY produced with FDY and POY. ATY is made with 70d Nylon FDY and 80d Nylon POY using AIKI air jet texturing machines, respectively. The processing parameters such as air pressure and yam speed are varied, and air pressure is varied ranging with 8.5bar, l0.5bar and 1l.5bar, and yarn speed is varied ranging with 400m/mim, 450m/mim, and 500m/min. The various physical properties of ATY made by POY and FDY denier, wet shrinkage, dry shrinkage, tensile properties, thermal stress and instability are measured and discussed with air pressure and yam speed. The shrinkage simulation of ATY is performed for analysing the process shrinkage on the dyeing and finishing processes.

• Textile Coloration and Finishing
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• v.16 no.3
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• pp.39-46
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• 2004

This study surveys the physical properties of DTY composite yarns manufactured by pin, disk and belt texturing systems. For this purpose, 208d/36f POY PET and 40d/12f high shrinkable PET filaments are prepared for specimens. The composite yarns are manufactured with this texturized POY and high shrinkable PET filament using the pin, disk and belt type texturing machines. While the processing conditions of the pin and disk types texturing machines were fixed, those of a belt type texturing machine were varied with over feed to compare and analyze with the yarn physical properties of pin and disk type composite yarns.