• 제목/요약/키워드: POT method

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Synthesis and Characterization of Zn(1-x)NixAl2O4 Spinels as a New Heterogeneous Catalyst of Biginelli's Reaction

  • Akika, Fatima-Zohra;Kihal, Nadjib;Habila, Tahir;Avramova, Ivalina;Suzer, Sefik;Pirotte, Bernard;Khelili, Smail
    • Bulletin of the Korean Chemical Society
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    • 제34권5호
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    • pp.1445-1453
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    • 2013
  • $Zn_{(1-x)}Ni_xAl_2O_4$ (x = 0.0-1.0) spinels were prepared at $800^{\circ}C$ by co-precipitation method and characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. The specific surface area was determined by BET. SEM image showed nano sized spherical particles. XPS confirmed the valence states of the metals, showing moderate Lewis character for the surface of materials. The powders were successfully used as new heterogeneous catalysts of Biginelli's reaction, a one-pot three-component reaction, leading to some dihydropyrimidinones (DHPMs). These new catalysts that produced good yields of DHPMs, were easily recovered by simple filtration and subsequently reused with persistent activity, and they are non-toxic and environmentally friendly. The optimum amount of catalyst is 20% by weight of benzaldehyde derivatives, while the doping amount has been found optimal for x = 0.1.

Minimizing Zinc Consumption In Hot-Dip Galvanizing Lines

  • Bright, Mark;Ellis, Suzanne
    • Corrosion Science and Technology
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    • 제10권2호
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    • pp.43-46
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    • 2011
  • Zinc consumption in a continuous galvanizing line is one of the highest operating cost items in the facility and minimizing zinc waste is a key economic objective for any operation. One of the primary sources of excessive loss of zinc is through the formation of top dross and skimmings in the coating pot. It has been reported that the top skimmings, manually removed from the bath, typically consist of more than 80% metallic zinc with the remainder being entrained dross particles ($Fe_2Al_5$) along with some oxides. Depending on the drossing practices and bath management, the composition of the removed top skimmings may contain up to 2 wt% aluminum and 1 wt% iron. On-going research efforts have been aimed at in-house recovery of the metallic zinc from the discarded top skimmings prior to selling to zinc recycling brokers. However, attempting to recover the zinc entrapped in the skimmings is difficult due to the complex nature of the intermetallic dross particles and the quality and volume of the recycled zinc is highly susceptible to fluctuations in processing parameters. As such, an efficient method to extract metallic zinc from top skimmings has been optimized through the use of a specialized thermo-mechanical process enabling a continuous galvanizing facility to conserve zinc usage on-site. Also, through this work, it has been identified that filtration of discrete dross particles has been proven effective at maintaining the cleanliness of the zinc. Future efforts may progress towards expanded utilization of filters in continuous galvanizing.

Cobalt ferrite nanotubes and porous nanorods for dye removal

  • Girgis, E.;Adel, D.;Tharwat, C.;Attallah, O.;Rao, K.V.
    • Advances in nano research
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    • 제3권2호
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    • pp.111-121
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    • 2015
  • $CoFe_2O_4$ nanotubes and porous nanorods were prepared via a simple one-pot template-free hydrothermal method and were used as an adsorbent for the removal of dye contaminants from water. The properties of the synthesized nanotubes and porous nanorods were characterized by electron diffraction, transmission electron microscopy and x-ray powder diffraction. The Adsorption characteristics of the $CoFe_2O_4$ were examined using polar red dye and the factors affecting adsorption, such as, initial dye concentration, pH and contact time were evaluated. The overall trend followed an increase of the sorption capacity reaching a maximum of 95% dye removal at low pHs of 2-4. An enhancement in the removal efficiency was also noticed upon increasing the contact time between dye molecules and $CoFe_2O_4$ nanoparticles. The final results indicated that the $CoFe_2O_4$ nanotubes and porous nanorods can be considered as an efficient low cost and recyclable adsorbent for dye removal with efficiency 94% for Cobalt ferrite nanotubes and for Cobalt ferrite porous nanorods equals 95%.

대전지역 급식학교 초등학생들의 음식 기호도 (Food Preference of Elementary School Children Under Meal Service in Taejon)

  • 구난숙;박종임
    • 대한지역사회영양학회지
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    • 제3권3호
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    • pp.440-453
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    • 1998
  • This study was done to provide basic information for nutrition education and meal planning by analyzing children's food preference. For this purpose, 938 children from eleven elementary schools under meal service were randomly selected in Taejon. The survey was conducted by questionnaires, and data were analyzed by SAS program. Children prefered ssalbap to japkogbap and liked kimbap the best among one dish foods. But their most favorite foods were chajangmyun in noodles, miyeokkuk in soups, and chamchichigae in pot stew. Sixth graders like kimchichigae more than third graders. In the case of chims, children like duejigalbichim, sogalbichim, and dalgyalchim. In the jorim, they prefered duejigogi jangjorim, mechurial jangjorim to any other jorims. The preference of bockum, namul, jangachi, and jotgal is generally low. Children's preference is high in fruit, drink, fried food, one dish food and is low in jangachi, namul, bockum. These results suggest that the preference of foods should be fully taken into consideration in school meal service so that they can eat foods with pleasure. Foods, which are low in preference due to the cooking method, should be prepared with new cooking methods developed specifically for children. 'Even though the preference of food is low to the children, the nutritious foods should be utilized in the school menu. Then, the importance of food intake must be taught to them through nutrition education.

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타날문단경호(打捺文短頸壺)의 연구(硏究) (The Paddling and Round Pots)

  • 이성주
    • 헤리티지:역사와 과학
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    • 제33권
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    • pp.4-35
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    • 2000
  • The paddling technique is a Kind of secondary treatments in the process of ceramic forming, which appeared in the Chinese Neolithic Age pottery making. In the case of Korean prehistoric pottery making, it was first introduced together with the kiln firing method from Tongpei region(東北地方) of China in Yan(燕) dynasty occupation period. Korean archaeologists have recognized the adoption of the new technologies as a drastic innovation of ceramic production. And most of them have thought that the diffusion of new techniques, accompanied by the migration of the northern ethnic groups, had been immediately followed by the innovative changes in pottery procdution. However, rejecting the arguments from the simple diffusionist viewpoint, I have first tried to describe the innovation processes in the ceramic production systems as a spatio-temporal process. The paddling technique by the cord-wound paddle, which was first introduced among the various paddles, was associated with the new sort of pottery, round pots fired in low temperature of reducing atmosphere condition. The cord-marked round pots first tried by the indigenous potters in the southern part of Korean were characterized by the relatively low leveled techniques in forming and firing, compared to those of north-east China. The techniques of the round pots were hardly improved in the domestic production system until the appearance of the fully-specialized one. The specialized production system of the round pot, which appeared first in the mid-western region of Korea, showed the diversified paddling techniques and made the noticeable improvements in forming and firing processes.

단기 태·폭풍 기인 잠제 배후의 Piling-up 현상 평가 (Assessment of Water Piling-up behind a Submerged Breakwater during Storm Events)

  • 손동휘;유제선;김무종
    • 한국연안방재학회지
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    • 제5권4호
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    • pp.203-210
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    • 2018
  • It is generally known that submerged breakwaters can reduce the incoming wave energy without disturbing the beach scenery. However, a submerged breakwater is also able to cause a setup of the sea level in the protected area which is also called as water piling-up. Since the piling-up can result in longshore currents, sediment transports, and unexpected beach erosion, understanding about the piling-up process is required prior to designing the nearshore structures. In this study, the water piling-up behind a submerged breakwater is assessed in the time of storm events. For the study area, Anmok beach in Gyeonso-dong, Gangwon-do is selected. 1-year, 5-year, 10-year, and 50-year return-values were derived from Peaks-Over-Threshold(POT) method and those are applied as offshore boundary conditions for the numerical simulation. The numerical results of the piling-up were assessed with regard to the wave steepness and the height of the submerged breakwater. With increase of both significant wave height and the height of the submerged breakwater, the piling-up parameter is also increased which can lead to erosion of dry beach behind the structure.

고층 스카이브리지의 변위 허용치 산정에 대한 연구 (Study on Evaluating Displacement Tolerance of Sky-bridge in Tall Buildings)

  • 김윤곤
    • 대한건축학회논문집:구조계
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    • 제36권4호
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    • pp.135-142
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    • 2020
  • The new method for evaluating the displacement tolerance of sky-bridges with pin-roller type supports was proposed considering both return period of phase difference between connected buildings and geometrical characteristics of skybridge. Because displacement tolerance is relative value, which is most affected by the phase difference of the connected buildings, the dynamic response of these building with time history analysis should be evaluated. However, the initial phase could not be specified, so the result of displacement tolerance would be varied with respect to initial value. Thus, the tolerance can be reasonably evaluated SRSS calculation with design displacements based on statistical approach and of each building. In addition, the geometrical characteristics of sky-bridge should be considered because the transverse displacement of sky-bridge span causes the shear deformation of the bridge and longitudinal displacement tolerance cannot release the shear deformation. Therefore, the some pin-end support in sky-bridge should have longitudinal displacement tolerance to accommodate the shear deformation. By resolving this shear deformation, it is possible not only to accommodate transverse displacement, but also to avoid the complicated joint details such as both pot bearing and guided supports with shear key.

모조 태풍 합성 재분석 바람장을 이용한 북서태평양 극치 해상풍 추정 (Estimation of Extreme Wind Speeds in the Western North Pacific Using Reanalysis Data Synthesized with Empirical Typhoon Vortex Model)

  • 김혜인;문일주
    • Ocean and Polar Research
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    • 제43권1호
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    • pp.1-14
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    • 2021
  • In this study, extreme wind speeds in the Western North Pacific (WNP) were estimated using reanalysis wind fields synthesized with an empirical typhoon vortex model. Reanalysis wind data used is the Fifth-generation European Centre for Medium-Range Weather Forecasts (ECMWF) reanalysis (ERA5) data, which was deemed to be the most suitable for extreme value analysis in this study. The empirical typhoon vortex model used has the advantage of being able to realistically reproduce the asymmetric winds of a typhoon by using the gale/storm-forced wind radii information in the 4 quadrants of a typhoon. Using a total of 39 years of the synthesized reanalysis wind fields in the WNP, extreme value analysis is applied to the General Pareto Distribution (GPD) model based on the Peak-Over-Threshold (POT) method, which can be used effectively in case of insufficient data. The results showed that the extreme analysis using the synthesized wind data significantly improved the tendency to underestimate the extreme wind speeds compared to using only reanalysis wind data. Considering the difficulty of obtaining long-term observational wind data at sea, the result of the synthesized wind field and extreme value analysis developed in this study can be used as basic data for the design of offshore structures.

북한산림복구용 용기묘 식재기 개발 (Development of Pottery Planting Equipment for the Restoration of North Korean Forest)

  • 최종오
    • 한국환경복원기술학회지
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    • 제26권1호
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    • pp.61-68
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    • 2023
  • In North Korea, the production of courage tombs continues, and it is known that the activity rate is higher than that of old tombs. However, pot seedling are planted using hoes and shovels used for planting old tombs with exposed roots and low activity rates. This is believed to result in excessive force when stepping on the container grave with a hoe in the planting process, resulting in the collapse of the container grave or the waste of labor due to the creation of unnecessary planting holes. Therefore, when planting courage graves at North Korean afforestation sites, it is necessary to improve the work of making planting holes using general hoes in a way that improves labor productivity in a more efficient manner. As part of inter-Korean technical cooperation to improve the North Korean afforestation method, this study was conducted with the aim of developing efficient container seedlings and using them for North Korean forest restoration projects. It is believed that developing planting equipment exclusively for container graves for forest restoration in North Korea in South Korea and providing equipment and production technology to North Korea can contribute to the development of forest restoration technology in North Korea. If the Yonggeomyo Development Planting Equipment is provided to North Korea, it will be a realistic inter-Korean forest cooperation project to avoid international sanctions by recognizing the excellence of the development products by directly using its own materials through technical cooperation.

A Simple and Rapid Method for Functional Analysis of Plant Growth-promoting Rhizobacteria Using the Development of Cucumber Adventitious Root System

  • Bae, Yeoung-Seuk;Park, Kyung-Seok;Lee, Young-Gee;Choi, Ok-Hee
    • The Plant Pathology Journal
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    • 제23권3호
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    • pp.223-225
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    • 2007
  • Many plant growth-promoting rhizobacteria (PGPRs) have been known for beneficial effects on plants including biological control of soilborne pathogens, induced systemic resistance to plant pathogens, phytohormone production, and improvement of nutrient and water uptake of plants. We developed a simple and rapid method for screening potential PGPR, especially phytohormone producing rhizobacteria, or for analyzing their functions in plant growth using cucumber seedling cuttings. Surface-sterilized cucumber seeds were grown in a plastic pot containing steamed vermiculite. After 7 days of cultivation, the upper part 2 cm in length of cucumber seedling, was cut and used as cucumber cuttings. The base of cutting stem was then dipped in a microcentrifuge tube containing 1.5ml of a bacterial suspension and incubated at $25^{\circ}C$ with a fluorescent light for 10 days. Number and length of developed adventitious roots from cucumber cuttings were examined. The seedling cuttings showed various responses to the isolates tested. Some isolates resulted in withering at the day of examination or in reduced number of roots developed. Several isolates stimulated initial development of adventitious roots showing more adventitious root hair number than that of untreated cuttings, while some isolate had more adventitious root hair number and longer adventitious roots than that of untreated control. Similar results were obtained from the trial with rose cuttings. Our results suggest that this bioassay method may provide a useful way for differentiating PGPR's functions involved in the development of root system.