• 제목/요약/키워드: POPs

검색결과 151건 처리시간 0.025초

Bioaccumulation of polycyclic aromatic hydrocarbons in Manila clam (Ruditapes philippinarum) exposed to crude oil-contaminated sediments

  • Lee, Chang-Hoon;Lee, Ji-Hye;Sung, Chan-Gyoung;Moon, Seong-Dae;Kang, Sin-Kil;Lee, Jong-Hyeon;Yim, Un Hyuk;Shim, Won Joon;Ha, Sung Yong
    • 한국패류학회지
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    • 제30권4호
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    • pp.371-381
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    • 2014
  • The bioaccumulation of 16 United States Environmental Protection Agency (USEPA) priority polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs in the Manila clam, Ruditapes philippinarum exposed to sediments artificially contaminated by Iranian Heavy Crude Oil was measured and the biota-sediment accumulation factor (BSAF) was estimated through laboratory experiments. The proportion of 16 PAHs accumulated in the tissue of R. philippinarum was only from 3 to 7% of total PAHs. Among 16 PAHs, the concentration of naphthalene was highest in the tissue. Alkylated PAHs were highly accumulated more than 93% of total PAHs. The C3 dibenzothiophene was most highly accumulated. The relative composition of alkylated naphthalenes in the tissue of R. philippinarum was lower than in the sediments. In contrast, those of alkylated compounds of fluorenes, phenanthrenes, dibenzothiophenes were higher in the tissue than the sediments. The BSAF for sum of 16 PAHs was 0.11 to 0.13 g carbon/g lipid and that for alkylated PAHs was 0.05 to 0.06 g carbon/g lipid. Naphthalene showed the highest BSAF value. Alkylated PAHs with the same parent compound, BSAF tended to increase with the number of alkylated branch increased, except for alkylated chrysenes. BSAF of total PAHs lies between that of field-based values, and are also similar to those of other persistent organic pollutants (PCBs, DDTs, HCHs). This study provides the BSAF values of individual alkylated PAHs accumulated in R. philippinarum for the first time and will be used as a basis for further understanding the bioaccumulation of organic contaminants in the marine benthic organisms.

안산지역 대기 중 다이옥신 및 dl-PCBs의 오염특성 조사 (Concentration and Gas-particle Partition of PCDDs/Fs and dl-PCBs in the Ambient Air of Ansan Area)

  • 허종원;김동기;송일석;이강웅
    • 한국대기환경학회지
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    • 제26권5호
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    • pp.517-532
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    • 2010
  • After establishment of Banwol industrial complex in 1987, Ansan city becomes the largest industrial sector development in Gyeonggi-do, Korea. As the population and industrial activity grow over this region, toxic air pollutants, particularly POPs (Persistent Organic Pollutants) from various emission sources have been major public concerns. Air samples for POPs monitoring were collected at the industrial sites ($A_2$), residential sites ($B_1$, $B_2$), commercial site (C), and rural/remote site (D) of the area of Ansan during 2008 with a prolonged industrial sampling site $A_1$ from 2001 to 2008. All samples were analysed for 2,3,7,8 substituted-polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) and dioxin like polychlorinatd diphenyls (dl-PCBs). In site $A_1$, a steady decline of their concentrations from 2003 to 2008 was observed due to the reinforced emission guideline from waste incinerators. The average concentration of the PCDD/Fs and dl-PCBs ranged between 0.118 pg-TEQ/$m^3$ (rural/remote site D) and 0.532 pg-TEQ/$m^3$ (industrial area $A_2$). These level were generally consistent with previous studies in Gyeonggi-do, while higher than other places. Most of PCDD/Fs congener were partitioned into particle phase, whereas dl-PCBs were partitioned into gas phase. The logarithm of gas-particle partition coefficient $K_P$ of dl-PCBs and PCDD/Fs were well correlated with sub-cooled liquid vapor pressure $P_L$. The slope $m_T$ of log $K_P$ versus log $P_L$ for PCDD/Fs (-1.22) and dl-PCBs (-1.02) in industrial area ($A_2$) were high compared to other residential/commercial area. It suggests that this area was likely influenced by the direct emission source of PCDD/Fs and dl-PCBs. To simulate the partition of PCDD/Fs and dl-PCBs between gas and particle phase, Junge-Pankow model ($P_L$-base) and $K_{oa}$ model were applied. It was found that J-P model was more suitable than the $K_{oa}$ model in this study.

K-POP의 세계시장 진출 성공요인 분석: VRIO 모형을 중심으로 (Exploring the Success Factors of K-POP Globalization: Utilizing the VRIO Model)

  • 신동석;남성집;남명현
    • 유통과학연구
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    • 제13권2호
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    • pp.55-62
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    • 2015
  • Purpose - This study aims to investigate the success factors pertaining to K-POPs from an analysis of the internal business environment. Much research has investigated Korean Moves or how to popularize them. The research mainly focused on aspects of Korean Moves. However, few studies have attempted to examine Korean Moves or K-POPs from a managerial viewpoint. The current research tries to investigate the success factors of K-POP from strategic perspectives, specifically utilizing internal resource based view perspectives. It differentiates itself by looking at the competitiveness of K-POP from the internal resources. Research design, data, and methodology - In the entertainment industry, where creativity is heavily stressed, competitiveness is often regarded within the organization as a form of intangible asset, knowledge, or technology that is often related with the organization's personnel. Some research has tried to reveal the competitiveness of K-POP using Porter's competitiveness of nations framework. Others utilize the adapted model of Porter's structure. However, these models only look at the outside environment, and not inside a firm's resource, knowledge, or capabilities. This research utilizes the VRIO model to examine the internal resources and capabilities of K-POP producers. The model measures whether a firm's internal resources and capabilities are valuable, rare, difficult to imitate by competitors, or organizable. The research covered businesses whose yearly revenue exceeds $10 Million in music planning and recording in South Korea. There were only thirteen such companies (one percent of the total population). Of these, companies for whom 20 percent or more of the sales revenue comes from the abroad are targeted. Only seven are selected and these participated in the research. In order to find a firm's internal resources, we conducted qualitative research methodology. Their business names and persons who participated in this research are not revealed due to case sensitive issues. Instead, we use unrelated initials for their names and their statements. Results - From the in-depth interview with top-tier K-POP producers and managers, the current research tried to identify resources and capabilities that helped to strengthen their competitiveness. These resources and capabilities are sought from the scope of the VRIO model, which looks at the internal resources and capabilities from the scope of value, rarity, imitability, and organization. Interviews with the top tier producers and managers reveal the internal success factors of K-POPs. We conclude that these resources and capabilities are from internally accumulated producing know-how, unique managing (training) system, and outstanding all-round entertainment capabilities of the performers. Conclusions - These results indicate that the core resources and capabilities of K-POP are robust. It will take a significant amount of time and money to imitate for followers, because these resources and capabilities are the result of time investment and are embedded into producers' and performers' know-how. Taking Luo (2000)'s argument, K-POP is in the second stage of the globalization process, which is configuring and allocation resource capabilities to a global scope.

불가리아 한류의 의미와 발전방향 (The Meaning of Hallyu and Its Sustainability in Bulgaria)

  • 송정은;남기범
    • 한국콘텐츠학회논문지
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    • 제16권6호
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    • pp.19-39
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    • 2016
  • 동유럽 지역의 한류는 2000년대 후반부터 확산되고 있으며 한국의 인지도와 친숙도 형성에 기여하고 있다. 동유럽권의 한류는 루마니아와 헝가리를 중심으로 확산되었으며, 불가리아에도 한국 드라마와 케이팝이 유입되었다. 한국과 불가리아는 수교 25주년을 맞이했지만, 아직 양국의 대중은 상대국에 대한 인지도가 낮다. 본 연구는 한국과 불가리아의 관계를 바탕으로, 불가리아 한류의 의미와 한류를 매개로 양국 간에 문화적 관계형성의 방향을 논의할 것을 목적으로 한다. 이를 위해, 본 연구는 불가리아의 수도 소피아에 거주하는 20대와 30대의 남녀 24명을 대상으로 초점집단토론을 실시하여 한국에 대한 인지도와 한류의 의미 및 영향력을 살펴보았다. 불가리아의 한류는 한국대사관, 한국어교육기관, 한류 팬이 각자의 영역에서 각기 다른 대상에게 한국의 문화를 알리면서 확산되고 있지만, 대중들에게 한류는 낯선 현상이다. 경제적, 문화적으로도 한류의 영향력은 낮다. 불가리아의 한류가 한국 드라마나 케이팝의 선호를 넘어 현지의 다양한 문화적 스타일의 하나로 지속되기 위해서는, 한류 콘텐츠 제작자들의 불가리아의 사회문화적 특성에 대한 이해와 현지에서 한국문화를 다방면으로 경험할 수 있는 환경이 우선적으로 마련되어야 한다. 이를 바탕으로 한류의 특징인 혼종성과 현지 문화적 코드를 반영한 한국 드라마, 영화, 케이팝을 제작하여 한류를 확산시킬 수 있다.

Persistent Organic Pollution and Arsenic Contamination in Asia Pacific Water: Case Study of Emerging Environmental Problems in Vietnam

  • Pham, Viet.H.
    • 한국습지학회지
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    • 제9권1호
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    • pp.79-89
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    • 2007
  • This paper provides a comprehensive overview of the present status of several environmental problems caused by emerging toxic substances such as persistent organic pollutants (POPs), endocrine disrupting chemicals (EDCs), and arsenic in various environmental media in Vietnam. Monitoring data reported during the 1990s demonstrated elevated contamination of DDTs in most of these compartments in Vietnam. Studies in frame of the Asia-Pacific Mussel Watch Program revealed that fish, mussels and resident birds from Vietnam contained higher concentrations of DDTs as compared to other countries in region, suggesting the role of Vietnamese environment as a significant emission source of DDT in the Southeast Asian region. The estimated dietary intakes of PCBs and DDTs for Vietnamese were relatively high among Asian developing countries, suggesting potential risk for humans posed by thesechemicals. Widespread contamination of some endocrine active compounds such as alkylphenols and phthalates was observed at various sites along the coasts of northern and middle Vietnam. The presence of significant source of bisphenol-A along Red River estuary was revealed with the concentrations comparable to those reported for developed nations. A case study on seasonal variation of alkylphenols and phthalates in surface water of river delta and estuary of north and middle Vietnam indicated the differences in distribution of these compounds between dry and rainy seasons. Higher concentrations of alkylphenols and phthalates were found in dry season in estuary; while the contrasting pattern was observed in the river delta, showing elevated residues in rainy season. This result suggests the different behavior of alkylphenols and phthalates in river delta and coastal environment. From ecotoxicological perspectives, concentrations of bis-phenol A and di(2-ethylhexyl)phthalates [DEHP] in surface water from some locations in Vietnam exceeded the guideline values for Ecotoxicological Effects and the Environmental Risk Limit, respectively, suggesting potential for toxic implications on aquatic wildlife. Widespread and elevated arsenic contamination was discovered inour recent surveys in groundwater in a large area of suburban areas of Hanoi city, the capital of Vietnam. The most recent investigation in 4 villages showed about more than 50 % of groundwater samples contained As concentrations exceeding 50 g/L (the WHO and Vietnamese standard). In particular, in Son Dong villages, 58 % of samples analyzed contained As concentrations higher than 200 g/L. Good correlations were found in As concentrations in water and hair and urine of peoples in corresponding families, suggesting the chronic exposure to As by people living in As-contaminated ground water areas. In Son Dong village, As levels in hair (mean: 1.7 mg/kg dry wt) and urine (g/g creatinine) exceeding the reference values recommended by WHO, suggesting potential for human risk posed by long term accumulation of As in human body. Future studies should be focused on the time trends of POPs and EDCs in biota in Vietnam in order to predict future trend of contamination and to reveal new clues for understanding possible toxic impacts on aquatic organisms. The issues of arsenic contamination in groundwater and their chronic toxic implications on human health should be systematically investigated in the future.

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이란산 원유의 증발에 따른 풍화율 및 화학적 성상 변화 (Effects of Evaporation on the Weathering Rate and Chemical Composition of Iranian Heavy Crude Oil)

  • 김범;김기범;심원준;임운혁
    • 한국해양환경ㆍ에너지학회지
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    • 제15권3호
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    • pp.238-246
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    • 2012
  • 해양으로 유출된 유류는 다양한 풍화과정을 통해 환경에서 제거되며, 증발이 유출사고 초기에 가장 우세한 풍화과정이다. 본 연구에서는 허베이스피리트호 사고유 중 이란산 원유를 대상으로 실험실에서 표준화된 증발실험을 실시하여 시간에 따른 물리화학적 변화를 관찰하였다. 증발과정에 영향을 미치는 유막두께, 풍속 등의 변수를 제어하여 48시간까지 노출한 결과 $29.3{\pm}0.4%$의 재현성 있는 결과를 산출하였다(n=40, p<0.001). 미국해양대기청의 풍화모델인 ADIOS2를 이용하여 환경조건에서 증발을 시뮬레이션한 결과 29%의 증발율을 구할 수 있었으며, 본 실험과 일치하는 결과를 확인하였다. 증발율에 따른 원유의 조성변화를 분석한 결과 저분자량의 알칸과 PAHs가 제거되었으나, 바이오마커 화합물은 증발에 의한 영향을 받지 않는 보전적인 특성을 나타냈다. 바이오마커 중 $17{\alpha}(H)$, $21{\beta}(H)$-hopane을 이용한 풍화율 계산값은 48시간 최종 값이 24.4%로 물리적인 증발에 따른 양적변화와 유사한 결과를 보였다. 호판을 이용한 풍화율 계산값 비교결과 사고 초기 현장 표착유(1단계 풍화 28.9%)와 메소코즘 풍화 실험 5일차(26.5%)까지는 풍화과정이 주로 증발에 의한 것으로 확인되었다.

소나무잎에 침착된 PAHs 특성 (Characteristics of PAHs Absorbed on Pine Needles)

  • 천만영
    • Environmental Analysis Health and Toxicology
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    • 제23권3호
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    • pp.213-220
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    • 2008
  • The characteristics of PAHs accumulated on pine needles which were used as passive samplers of atmospheric POPs were studied. Atmospheric PAHs were accumulated on pine needles. The absorbed rate of PAHs was higher in gaseous state than in particulate and is not constant. The accumulation rate did not change too much among different classes of pine trees. Therefore young pine needles is better as a passive sampler of atmospheric PAHs for short monitoring period.

국내 잔류성유기오염물질(Persistent Organic Pollutants) 배출목록 개발 - 부산물 PCBs, HCB, PAHs를 중심으로 - (Development of National Emission Inventories for Persistent Organic Pollutants (Unintentionally Formed PCBs, HCB and PAHs))

  • 조규탁;이동수;이지윤;김경미;이지은
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 추계학술대회 논문집
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    • pp.221-222
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    • 2003
  • 잔류성유기오염물질(Persistent Organic Pollutants, 이하 POPs)은 환경에 노출되면 장기간 잔류하면서 인체 및 생태계에 악영향을 끼치며 또한 장거리 이동하는 특징으로 인하여 전지구적인 규제ㆍ관리의 필요성이 제기되고 있다. 이러한 필요에 부응하여 UNEP를 중심으로 국제적인 관리를 위한 논의가 이루어져 2001년 5월 스톡홀름협약(Stockholm convention for Persistent Organic Pollutants)이 당사국회의에서 채택되었고, 우리나라는 외교적 서명을 함으로써 협약가입의사를 분명히 하였다. (중략)

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대기 중 미량독성 유해물질의 특성과 현황 (Characteristics and Status of Toxic Trace Substances in Ambient Air)

  • 김영성;김영주;임은정
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2002년도 춘계학술대회 논문집
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    • pp.133-134
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    • 2002
  • 미량독성 유해물질은 크게 중금속 성분과 잔류성 유기오염물질 (POPs, persistent organic pollutants)로 나눌 수 있다. 아직은 우리 사회의 관심이 직접 주변에서 확인할 수 있는 국내 배출에 머물고 있으나 미량독성 유해물질로 분류되는 많은 물질들이 분해가 어렵고 대기 중 체류시간이 길어 장거리 이동의 가능성이 매우 크다. 실제 오염물질 배출이 거의 없는 북극의 북극곰, 물개, 물고기에서도 미량독성 유해물질 검출이 보고되고 있는데, 다른 지역에서 배출된 독성물질들이 침적과 휘발을 반복하며 이동하는 가운데 기온이 낮은 극지방에 축적됨으로써 나타난 현상이다. (중략)

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Aerosol Mass Spectrometer (AMS)-Based Real-Time Physicochemical Characterization of Atmospheric Aerosols

  • Kim, Donghwi
    • Mass Spectrometry Letters
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    • 제13권2호
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    • pp.27-34
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    • 2022
  • Atmospheric aerosols have become a major environmental concern because of their adverse effects on human health, air quality, and climate change. Over the last few decades, several mass spectrometry (MS)-based techniques have been developed and applied in the field of atmospheric aerosol research. Particularly, real-time measurement of ambient aerosols using an aerosol mass spectrometer (AMS) has become one of the most powerful tools for aerosol chemistry. This review provides a brief description of AMS and its applications for understanding the physicochemical properties of atmospheric aerosols, as well as its sources and evolution processes.