• Title/Summary/Keyword: POLYMER

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fundamental Properties of Water-Permeable Polymer-Modified Concrete (투수성 폴리머 시멘트 콘크리트의 기공적 성질)

  • 이윤수;주명기
    • Journal of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.402-408
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    • 2002
  • The permeable polymer-modified concrete has a lot of internal voids, which has more excellent performance in permeability and durability than asphalt and cement concrete. Therefore, the purpose of this study is to ascertain the strength properties of water-permeable polymer concretes with SBR latex and redispersible polymer powder. The water-permeable polymer concretes using SBR latex and redispersible polymer powder with water-binder ratio of 29 %, polymer-cement ratios of 0, 5, 10, 15 and 20 % are prepared, and tested for compressive strength, splitting tensile strength, flexural strength, water permeablility. From the test results, improvements in the strength properties of the water-permeable polymer concretes due to the addition of the SBR latex and redispersible polymer powder are discussed.

Characterization of Mechanical Property Change in Polymer Aerogels Depending on the Ligand Structure of Acrylate Monomer

  • Lee, Kyu-Yeon;Jung, Hae-Noo-Ree;Mahadik, D.B.;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.3
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    • pp.15-20
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    • 2016
  • In an effort to overcome the weakness of aerogel, polymer aerogels have been prepared by copolymerizing the different types of monomers through sol-gel process. Polymerizing the successive phase of a high internal phase emulsion, which has interconnected porous structure, porous polymer aerogel can be manufactured. In this paper, we use the styrene/divinylbenzene chain as a basic monomer structure, and additionally use 2-ethylhexyl methacrylate (2-EHMA) or 2-ethylhexyl acrylate (2-EHA) as monomers for distinguishing the visible mechanical properties of synthesized polymer aerogel. We can observe the different tendency of polymer aerogels by kinds of monomer or ratio. Flexibility and microstructure can be changed by the types of monomer. EHA polymer aerogel shows high flexibility and thin microstructure, and EHMA polymer aerogel shows high hardness and thick microstructure. EHA/EHMA polymer aerogel shows the intermediate nature between them. By utilizing the mechanical properties of three types of polymer aerogels to adequate situation or environment, polymer aerogels could be used as drug agent, ion exchange resin, oil filter and insulator, and so on.

Effects of Temperature on Tribological Properties of Polymer Material (온도 조건에 따른 폴리머 소재의 트라이볼로지 특성 연구)

  • Chi-Yoon An;Dae-Eun Kim
    • Tribology and Lubricants
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    • v.39 no.6
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    • pp.262-267
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    • 2023
  • Research to replace metal mechanical elements with polymer materials has recently accelerated. However, polymers exhibit less favorable mechanical properties than metal materials, and are often easily worn-out owing to frictional heat when their mechanical elements contact while in relative motion. Therefore, research on the polymer tribological properties is required to employ polymer materials in mechanical elements operating under harsh conditions. In this study, we examine the effect of mechanical part operating temperatures on the material friction and wear characteristics of polymer materials. We conduct ball-on-disk friction tests under dry conditions at various temperatures, using a metal ball with high hardness and a polymer as the counter surface. Each test is repeated at least three times to ensure the reliability of the test results. Before the friction test, we analyze the surface hardness and roughness of each polymer specimen; after the friction test, we use a three-dimensional confocal microscope to compare and analyze the polymer specimen wear characteristics. Based on this study, we systematically elucidate the polymer material tribological characteristics. This information should be useful for selecting and utilizing polymer materials at various temperatures.

Bend Resistance of Polymer Cement Slurry Coated Reinforcing Bars

  • Kim, Wan-Ki;Chang, Sung-Ju;Kim, Hyun-Ki;Soh, Yang-Seob
    • KCI Concrete Journal
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    • v.13 no.2
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    • pp.42-48
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    • 2001
  • The bend resistance of coated reinforcing bar is greatly influenced by both the adhesion strength between bar and coating materials, and the followed transformation of coating material as bars bend. Especially, tearing state or partial microscopic cracks are predicted on the inside and outside of bending angle, because tensile strength and elongation of polymer film are very different according to types of polymer dispersions in bar coating, and these damaged parts are rapidly corroded by penetration of corrosive factors. In this study, polymer cement slurry coated reinforcing bars with various polymer dispersions are prepared by following combined conditions, polymer-cement ratio of 50% and 100%, coating thickness of 250$\mu$m and 450$\mu$m, coating number, curing age of 3, 7, 14 and 28days. Then the specimens are tested for working life and bend resistance at bending angles $90^{\circ}$, $135^{\circ}$and $180^{\circ}$ to observe the microscopic damage effect as the bars bend. Also, epoxy-coated reinforcing bars for control experiment were used with 250$\mu$m of coating thickness. The tensile strength for polymer films is performed. From the test results, the working life of the polymer cement slurry is within 90 seconds. Among four types of polymer dispersion, polymer cement slurry coated reinforcing bar using St/BA-1 emulsion has the excellent bend resistance, which is remarkably improved than that of epoxy-coated reinforcing bar. And the bend resistance is more related to elongation than tensile strength of polymer film. Polymer cement slurry with a polymer-cement ratio of 100%, a coating thickness of $450\mu$m and one coating using St/BA emulsion is selected as a most suitable coating material for coated reinforcing bar.

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Tensile Strength and Tensile Adhesive Strengths of Polymer-Modified Mortar with Methyl Methacrylate-Based Latexes (MMA계 라텍스를 혼입한 폴리머 시멘트 모르타르의 인장강도 및 부착강도)

  • Hyung, Won-Gil;Lee, Chan-Tae;Park, Sung-Moo
    • Polymer(Korea)
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    • v.34 no.3
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    • pp.247-252
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    • 2010
  • This paper investigates the effects of the monomer ratios on the typical properties of polymer-modified mortars that contain methyl methacrylate-based latexes. Basic data are also obtained to develop appropriate latexes for cement modifiers. Polymer-modified mortars that contain methyl methacrylate latexes copolymerized with butyl acrylate or ethyl acrylate are prepared for different polymer-cement ratios. They are then tested to obtain the tensile and tensile adhesive strengthes of polymer-modified mortar with methyl methacrylate-based latexes. From the test results, the tensile strength of MB7 polymer-modified mortar was higher than normal cement mortar by a maximum of 94% with a 20% polymer-cement ratio, which was almost twice higher than normal. The tensile adhesive strength of the MB polymer-modified mortar was higher for higher MMA monomer contents and polymer-cement ratios, and increased up to four times than that of normal cement mortar. The basic properties of the polymer-modified mortars are more affected by the polymer-cement ratio than by the monomer ratio, and are improved over unmodified mortar.

Effect of Manufacturing Method and Acidifier on the Dissolution Rate of Carvedilol from Solid Dispersion Formulations

  • Lim, Dong-Kyun;Bae, Jeong-Woo;Song, Byung-Joo;Jo, Han-Su;Kim, Hyoung-Eun;Lee, Dong-Won;Khang, Gil-Son
    • Journal of Pharmaceutical Investigation
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    • v.41 no.6
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    • pp.363-369
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    • 2011
  • In this study, we demonstrated the release behavior of carvedilol with the content of polyvinylpyrrolidone K-30 (PVP K-30) and the effect of citric acid and fumaric acid as acidifiers on the release behavior of drug. In addition, it tries to inquire into the release behavior difference of the carvedilol according to the manufacturing method. The release behavior of the tablets was compared with Dilatrand$^{(R)}$ in the simulated gastric fluid (pH1.2). Differential scanning calorimeter (DSC), X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FT-IR) were characterized for the physicochemical properties of the tablets. In case of mixing the carvedilol and PVP K-30, in case the ratio of the carvedilol and PVP K-30 was 1:5, the release behavior was the highest among. As well as the dissolution rate of tablets manufactured by lyophilization and rotary evaporator was higher than physical mixture. The dissolution rate of containing acidifiers was more improved. But, rather the excessive amount of the acidifier addition reduced the dissolution rate.

X-ray Scattering Studies on the Structure of Porcine Pepsin in Various pH Solutions

  • Jin, Kyeong-Sik;Jin, Sang-Woo;Yoon, Jin-Hwan;Heo, Kyu-Young;Kim, Jae-Han;Kim, Hee-Soo;Ree, Moon-Hor
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.348-348
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    • 2006
  • In the present study, porcine pepsin in various pH conditions was investigated by small-angle X-ray scattering (SAXS) in order to detailed information on the structure and its variations with pH conditions. These analyses identified the structure of pepsin, and compared with that obtained by single crystallography. Moreover, this study found the structure' variations with changing pH conditions. All the results will be discussed with considering the conformational characteristics of pepsin in solution and further correlate to the biological and spectroscopic characteristics reported previously.

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Mix Design of Polymer Grouting Mortar for Prepacked Concrete Using Polymer Dispersions (폴리머 디스퍼션을 이용한 프리팩트 콘크리트용 주입 모르타르의 배합에 관한 연구)

  • Jo, Young-Kug;Kim, Wan-Ki
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.5
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    • pp.85-91
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    • 2008
  • Prepacked concrete has recently been used in the special constructions fields such as underwater concrete work, heavy-weight concrete work, underground structure work, partial repair works for damaged reinforced concrete structures. and polymer-modified mortars have been employed as grouting mortars for the prepacked concrete. The purpose of this study is to recommend the optimum mix design of polymer-modified grouting mortars for prepacked concrete. Polymer-modified mortars using SBR and EVA emulsions as admixture of grouting mortars for prepacked concrete are prepared with various mix proportions such as sand-binder ratio, fly ash replacement ratio, polymer-binder ratio. and tested for flowability, viscosity of grouting mortars, bleeding ratio, expansion ratio, flexural and compressive strengths of grouting mortars and compressive and tensile strengths of prepacked concretes. From the test results, it is apparent that polymer-modified mortars can be produced as grouting mortars when proper mix design is chosen. We can design the mix proportions of high strength mortars for prepacked concrete according to the control of mix design factors such as type of polymer, polymer-binder ratio, sand-binder ratio and fly ash replacement ratio. Water-binder ratio of plain mortars for a constant flowability value are in the ranges of 43% to 50%. SBR-modified mortar has a little water-binder ratios compared to those of plain mortar, however, EVA-modified mortar needs a high water-binder ratio due to a high viscosity of polymer dispersion. The expansion and bleeding ratios of grouting mortars are also controlled in the proper value ranges. Polymer-modified grouting mortars have good flexural. compressive and tensile strengths, are not affected with various properties with increasing fly ash replacement to cement and binder-sand ratio. In this study, SBR-modified grouting mortar with a polymer-binder ratio of 10% or less, a fly ash replacement of 10% to cement and a sand-binder ratio of 1.5 is recommended as a grouting mortar for prepacked concrete.

Effect of Silk in Silk/PLGA Hybrid Films on Attachment and Proliferation of Human Aortic Endothelial Cells (실크/PLGA 하이브리드 필름에서 실크가 인간 대동맥 내피세포의 부착과 증식에 미치는 효과)

  • Lee, Jihye;Lee, Sojin;Kim, Seulji;Kim, Kyounghee;Kim, Younglae;Song, Jeongeun;Lee, Dongwon;Khang, Gilson
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.127-134
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    • 2013
  • The vascular endothelial cells are the inner layers of blood vessels. It regulates the function of blood vessels and proliferation of vascular smooth muscle cells. Poly(lactide-co-glycolic acid) (PLGA) is a biodegradable synthetic polymer with a well-controlled degradation rate and an acceptable mechanical strength. It can be easily fabricated into many shapes. Silk consists of 18 amino acids. It found important for attaching cells cultured in vitro, and maintaining cell functions. In this study, we fabricated silk/PLGA biomaterial hybrid films of 0, 10, 20, 40 and 80 wt% silk. We performed MTT, SEM, ELISA, and immunocytochemistry analyses. We confirmed the adhesion and the proliferation of HAECs on silk/PLGA according to the content of silk, and 40 wt% silk/PLGA hybrid films have superior adhesion and proliferation properties. These results demonstrate that silk/PLGA hybrid films provide suitable surfaces for HAECs, and there is the effect of silk on cell growth and proliferation.