• 설비공학논문집
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• 제14권4호
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• pp.285-292
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• 2002

The vapor pressure and miscibility measurement apparatus was developed and used to obtain data for refrigerant/oil mixture. The vapor pressure and miscibility data for R-404A/32 ISO VG polyol ester (POE) oil mixture and R-404A/46 ISO VG polyol ester oil mixture are obtained over the temperature range from -20 to $60^{\circ}$ with at $10^{\circ}$ intervals and the oil concentration range from 0 to 70 wt%. Using the experimental data, an empirical model was developed to predict the temperature vapor pressure-concentration relations for R-404A/46 ISO VG polyol ester oil mixtures at equilibrium. In the R-404A/32 ISO VG polyol ester oil mixture, the average root-mean-square deviation between measured data and calculated results from the empirical model is 1.24% and in the R-404A/46 ISO VG polyol ester oil mixture, that is 1.37%. Miscibility for R-404A/32 ISO VG polyol ester oil mixture was observed all over the experimental conditions. Immiscibility for R-404A/So1est 46 oil mixture was observed at the low oil concentrations (20~30 wt%) over the high experimental temperature range (50~$60^{\circ}$).

• 설비공학논문집
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• 제19권10호
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• pp.718-725
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• 2007

In the general vapor-compression refrigeration system, refrigeration lubricant circulates in refrigeration system with refrigerant. Knowledge of the amount of circulating lubricant is very important to exactly calculate capacity of the refrigeration system. An experimental study was conducted to estimate the oil concentration of a flowing $CO_2/Oil$ mixtures. POE and PAG oil are considered as test lubricants in this study. Performance tests were conducted under simulated liquid conditions for $CO_2/POE$ oil mixture in oil concentration of 0 to 10 weight-percent and $CO_2/PAG$ oil mixture in oil concentration of 0 to 6 weight-percent in the temperature ranges of $-5^{\circ}C\;to\;15^{\circ}C$. The results obtained indicate specific gravity of $CO_2/Oil$ mixture is increased as oil concentration is increased and as temperature of mixture is decreased. Oil concentration correlation of $CO_2/POE$ oil mixture and $CO_2/PAG$ oil mixture is suggested, based on the measurement of specific gravity and temperature. This correlation enable to predict the oil concentration without extraction of the mixture and can be applied for $CO_2/POE$ mixtures and $CO_2/PAG$ mixtures.

• 대한기계학회논문집B
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• 제38권3호
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• pp.255-262
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• 2014

판형열교환기의 증발과정에서 오일에 위한 영향을 알아보기 위해 마이크로 기어 펌프를 이용한 냉매-R134a 순환 성능실험 장치를 구성하여, 증발열전달 실험을 수행하였다. POE 오일을 펌프를 이용하여 냉매 질량 유량에 비례하도록 0~5%를 첨가하여, 오일순환량에 따른 열전달계수 변화를 측정하였다. 오일순환율이 증가할수록 R134a 증발 열전달계수는 감소하며, 압력손실은 증가한다. 질량유량 80 g/s, 증발 온도 $30^{\circ}C$ 일 때, 오일 순환율 2%조건에서 무오일 대비 약 10%의 열전달계수가 감소하였고, 압력손실은 약 10% 증가하였다.

• 설비공학논문집
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• 제8권4호
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• pp.473-483
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• 1996

To protect the ozone layer, R22 will be replaced with HFCs. R407C is a leading candidate as alternative refrigerant for air conditioner due to its similar thermodynamic characteristics with R22. In replacing R22 with R407C, the compatibility with lubricating oil is of major concern. Polyol ester (POE) oil among the synthetic oils is considered to be the best lubricant for use with R407C because of good electrical properties and miscibility. However, lubricating ability of mixture of R407C/POE oil is lower than that of R22/mineral oil due to the production of acid by hydrolysis which causes corrosive wear. Therefore, to minimize water content, it is needed to develop a molecular sieve desiccant which is compatible with R407C and ester oil. This paper discusses (1) the change of properties of POE oil when current molecular seive is used, (2) the effects of POE oils and additives on durability of compressor. Through compressor life test and bench wear test, it was found that inadequate use of POE oils and additives may promote the deteriation of molecular sieve, resulting in decrease of durability of compressor.

• 대한화장품학회지
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• 제22권2호
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• pp.20-40
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• 1996

The oil in water type ME of 4 component system was composed with POE monoalkyl ether and POE sorbitan monoalkyl ester as surfactant, saturated hydrocarbon, side chain structure and aromatic structure as oil, and glycerine as cosurfactant using high pressure homogenizer. The objective of this study was to examine the role of surfactant and oil structure on droplet size and stability. The experimental results showed that the droplet size was smaller with bigger polarity of oil, less hydrocarbon, longer hydrophilic chain of surfactant and higher concentration of glycerine. SQ and LP systems showed very stable but AB and ISB system unstable microemulsion.

• 한국응용과학기술학회지
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• 제12권2호
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• pp.13-19
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• 1995

Spin finish(SF) for nylon filament was prepared. The influence on the properties of filament obtained by treating the prepared spin finish in this study(SF-2) and foreign-made spin finish(Spinnar N-100) was compared. SF-2 prepared by blending of spindle oil 70g, paraffin wax 10g, glyceryl mono-oleate 5g, POE(6) nonylphenyl ether 4g, POE(10) nonylphenyl ether 4g, POE(10) octylphenyl ether 2g, POE(14) mono-oleate 4g and water 1g was excellent in its characteristics. Some of the properties of Nylon filament treated with SF-2 were better than those treated with Spinnar N-100. Also, optimal physical conditions of nylon filament according to the number of revolution of oil roller were obtained at conditions of 5rpm of number of revolution oil roller, 1.25% of SF-2 oil pick up, and denier 69D.

• 공업화학
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• 제7권1호
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• pp.145-152
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• 1996

비수유화법을 이용한 미세 O/W에멀젼의 제조 기술에 관한 연구로 표면장력, 계면장력, 탁도 및 전이온도를 통하여 비수용매/기름에서의 POE(25)octyldodecyl ether의 거동을 연구하였다. POE(25)octyldodecyl ether는 물 용매에서의 미셀 형성과는 달리 비수용매에서는 용해되었다. 글리세린과 같은 용매에서는 POE(25)octyldodecyl ether의 용해력은 약했으며 표면으로 이동되었다. 표면에서 포화된 후 POE(25)octyldodecyl ether는 석출 현상을 보였다. 최종 에멀젼의 평균입자 크기는 230nm 이었으며 한달 동안의 0, 25, 40, $50^{\circ}C$ 및 순환시험에 안정하였으나 일반적인 에멀젼은 불안정하였다. 따라서 적절한 용매의 조합에 의해 계면활성제의 흡착 효율을 증가시킬 수 있었다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.1672-1677
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• 2003

Carbon dioxide($CO_2$, R-744) has become a very popular issue in application to refrigeration and air conditioning systems as a natural refrigerant. An experimental study has been carried out to investigate the vapor pressure and miscibility of refrigerant R-744 in the presence of lubricant oil. This is of particular interest in the selection of the lubricant oil for the compressor of a refrigeration system or an air conditioning system using the refrigerant R-744. This apparatus consists of the test section, measuring devices, the vacuum pump, the constant temperature bath and relevant connecting pipes made of stainless steel. Two lubricant oils, such as mineral oil(Naphthenic) and polyol ester(POE) oil, are considered in the present study. For this purpose, test runs were conducted with the oil concentration range from 5 to 50 wt%, and the temperature range from -10 to $10^{\circ}C$ with $2^{\circ}C$ intervals. The results are correlated with the vapor pressure. and showed with the miscibility as visualization for the individual text components.

• 설비공학논문집
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• 제13권1호
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• pp.1-8
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• 2001

This paper deals with refrigerant-oil mixtures in a dehumidifying cycle. Two different oils such as Alkylbenzene(AB) and Polyol-esters(POE) lubricants are used for R134a to investigate the effect of miscibility on oil returnability. It was found that R134a/AB mixture had more unstable interface between oil and refrigerant than R134a/POE mixture. However, overall flow patterns of both refrigerant-oil mixtures were almost same. The minimum height of oil measured in the compressor was as high as twice of the least permissible height of oil in the compressor required to insure its reliability. Thus, it is considered that immiscible oil, i. e., AB for R134a can be used without causing oil returnability problem.

• 설비공학논문집
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• 제19권3호
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• pp.213-219
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• 2007

An experimental apparatus was constructed to obtain vapor-liquid equilibrium data for $CO_2/oil$ mixtures using mass analysis method with sample cylinder. Lubricants employed were POE (poly-ol ester) and PAG (poly alkylene glycol). The phase equilibria of $CO_2/oil$ mixtures prevailed in an equilibrium cell were observed through a couple of sight glasses at the opposite ends. Data were obtained over the temperatures $-10^{\circ}C,\;-5^{\circ}C,\;0^{\circ}C,\;5^{\circ}C,\;10^{\circ}C,\;25^{\circ}C,\;40^{\circ}C,\;60^{\circ}C,\;and\;80^{\circ}C$ under pressures up to 14 MPa and then mole fractions were calculated, respectively In general, more solubility of $CO_2$ is observed in POE than in PAG. Miscibility gap is closed for $CO_2/POE$ mixture but not for $CO_2/PAG$.