• 환경영향평가
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• 제27권2호
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• pp.215-231
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• 2018

본 연구에서는 지상 기상 및 $PM_{2.5}$ 농도, GOCI 위성의 AOD 등 다양한 관측 자료와 WRF-CMAQ 모델링을 통해 2016년과 2017년의 우리나라 가을철 $PM_{2.5}$ 농도변화 원인을 분석하였다. 지상에서 관측된 2017년 전국 평균 $PM_{2.5}$ 농도는 2016년에 비해 약 12.3% ($3.0{\mu}g/m^3$) 감소한 것으로 나타났다. 두 해간 $PM_{2.5}$ 농도 차이는 10월과 11월의 두 사례(사례1: 10월 11일~10월 20일, 사례2: 11월 15일~19일) 기간에 주로 발생하였으며, 2017년의 기상조건이 2016년에 비하여 국외로부터 대기오염물질의 장거리 수송이 어렵고, 국내의 대기환기 효과를 증가시키는 방향으로 변화한 것이 주요한 원인으로 분석되었다. WRF-CMAQ 모델링 시스템을 이용하여 기상조건 변화가 $PM_{2.5}$ 농도에 미치는 정량적인 영향을 평가한 결과, $PM_{2.5}$ 모의농도는 2016년 대비 2017년의 사례1 기간에는 64.0% ($23.1{\mu}g/m^3$) 감소, 사례2 기간에는 35.7% ($12.2{\mu}g/m^3$) 감소한 것으로 나타나, 관측 농도 기반 감소율인 53.6% (사례1)와 47.8% (사례2)에 상응하는 감소율을 보였다. 따라서 기상조건 변화가 우리나라 가을철 $PM_{2.5}$ 농도 변화에 큰 영향을 미치는 것으로 분석되었다. 기상조건 변화로 인한 우리나라 $PM_{2.5}$ 농도 감소에 미친 국내외 기여율은 사례1 기간에 국외로부터의 장거리 수송영향이 52.8% 그리고 대기환기 효과에 따른 국내영향이 47.2% 로 국내외 영향이 유사하게 나타나지만, 사례2 기간에는 국외영향이 66.4% 그리고 국내영향이 33.6%로서 국외영향의 감소효과가 더 크게 나타났다.

• 한국환경보건학회지
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• 제34권4호
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• pp.300-310
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• 2008

In order to further determine the mass concentration and ion composition of size-segregated particulate matter (PM) during the non-Asian dust storm of spring, $PM_{2.5}$ (fine particle), $PM_{10-2.5}$ (coarse particle), and $PM_{over-10}$ (PM with an aerodynamic diameter larger than $10{\mu}m$) were collected using a MCI (multi-nozzle cascade impactor) sampler of a three-stage filter pack in the spring season of 2007 in the Iksan area. During the sampling period from 5 April to 21 April, a total of 34 samples for size-segregated PM were collected, and then measured for PM mass concentrations by gravimetric measurements and for water-soluble inorganic ion species by using ion chromatography. Average mass concentrations of $PM_{2.5}$, $PM_{10-2.5}$, $PM_{over-10}$ were $35.4{\pm}11.5{\mu}g/m^3$, $13.3{\pm}5.5{\mu}g/m^3$ and $9.5{\pm}4.7{\mu}g/m^3$, respectively. On average, $PM_{2.5}$ accounted for 74% of $PM_{10}$. Compared with the literature from other areas in Korea, the measured concentration of $PM_{2.5}$ were relatively high. Water-soluble inorganic ion fractions in $PM_{2.5}$, $PM_{10-2.5}$, and $PM_{over-10}$ were found to be 47.8%, 28.5%, and 14.7%, respectively. Among the water-soluble inorganic ion species, $SO_4^{2-}$, $NO_3^-$ and $NH_4^+$ were the main components in $PM_{2.5}$, while $NO_3^-$ dominantly existed in both $PM_{10-2.5}$ and $PM_{over-10}$. Non-seasalt $SO_4^{2-}$ (nss-$SO_4^{2-}$ and $NO_3^-$ were found to mainly exist as the neutralized chemical components of $(NH_4)_2SO_4$ and $NH_4NO_3$ in fine particles.

• Asian Journal of Atmospheric Environment
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• 제2권2호
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• pp.90-101
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• 2008

The chemical compositions of $PM_{2.5}$ and $PM_{10}$ and associated high-molecular-weight polycyclic aromatic hydrocarbons (PAHs) were investigated during winter and summer at a roadside and an urban background site in Saitama, Japan. The average concentrations of $PM_{2.5}$ exceeded the United States Environmental Protection Agency standards during both periods. Carbonaceous components were abundant in both the observed and calculated (by means of a mass closure model) chemical composition of $PM_{2.5}$. Traffic-related pollutants (elemental carbon and high-molecular-weight PAHs) were strongly associated with $PM_{2.5}$ rather than with larger particles. The mass concentrations of $PM_{2.5}$, as well as those of EC and PAHs associated with the particles, at the two sites were strongly correlated. Comparison of our data with source profile ratios indicates that diesel-powered vehicles were probably the main source of the measured PAHs. The PAHs concentrations were affected by meteorological conditions during our study. Our results highlight the need for the establishment of standards for $PM_{2.5}$ in Japan.

• 한국임상수의학회지
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• 제25권2호
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• pp.79-84
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• 2008

For estimating the ovulation time in Miniature Schnauzer dogs during the estrous cycle, radioimmunoassay of plasma estradiol-$17{\beta}$ and progesterone concentrations was conducted on blood samples in 21 pregnant and 13 non pregnant dogs. When Day 0 was that plasma progesterone concentrations exceeded 4.0 ng/ml, on Day 64, parturition day, progesterone declined below 1.0 ng/ml with $0.92\;{\pm}\;0.29\;ng/ml$ and when Day 0 was that plasma progesterone concentrations declined below 1.0 ng/ml, on Day -64, progesterone increased above 4.0 ng/ml with $4.56\;{\pm}\;0.87\;ng/ml$. Gestational length was $63.71\;{\pm}\;1.35$ (Mean${\pm}$S.D.) days from plasma progesterone concentrations exceeded 4.0 ng/ml and was $66.29\;{\pm}\;1.98$ days from first male acceptance. The plasma estradiol-$17{\beta}$ concentrations reached maximum value with $28.20\;{\pm}\;2.86\;pg/ml$ on Day .2, and plasma progesterone concentrations reached $5.90\;{\pm}\;0.36 ng/ml, 5.18\;{\pm}\;0.32 ng/ml on Day 0, and the maximum of 61.58\;{\pm}\;10.47 ng/ml on Day 19 and 56.05\;{\pm}\;8.86\;ng/ml$ on Day 16 in pregnant and non pregnant dogs, respectively. Afterward, plasma progesterone concentrations declined below 1.0 ng/ml on Day 64 with $0.92\;{\pm}\;0.29\;ng/ml$ in pregnant cycles and on Day 58 with $0.95\;{\pm}\;0.63\;ng/ml$ in non pregnant dogs. No difference were found pregnant and non pregnant dogs in plasma estradiol-$17{\beta}$ and progesterone concentrations (p<0.01). Based on first male acceptance (Day 0), the maximum of plasma estradiol-$17{\beta}$ concentrations ($29.31\;{\pm}\;3.61\;pg/ml$) occurred on Day -1 and plasma progesterone concentrations exceeded 4.0 ng/ml on Day 2 in pregnant ($5.37\;{\pm}\;0.76\;ng/ml$) and non pregnant ($4.25\;{\pm}\;0.80\;ng/ml$) dogs. These results suggest that in Miniature Schnauzers, the ovulation occurred when plasma progesterone concentrations exceeded 4.0 ng/ml, 3 days after plasma estradiol-$17{\beta}$ peak and 2 days after first male acceptance.

• 한국입자에어로졸학회지
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• 제19권4호
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• pp.111-128
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• 2023

Chungcheongnam-do has various emission sources, including large-scale facilities such as power plants, steel and petrochemical industry complexes, which can lead to the severe PM pollution. Here, we measured concentrations of PM₁₀, PM_2.5, and its metallic elements at a suburban site in Taean, Chungcheongnam-do from September 2017 to June 2022. During the measurement period, the average concentrations of PM₁₀ and PM_2.5 were 58.6 ㎍/m³ (9.6~379.0 ㎍/m³) and 35.0 ㎍/m³ (6.1~132.2 ㎍/m³), respectively. The concentration of PM₁₀ and PM_2.5 showed typical seasonal variation, with higher concentration in winter and lower concentration in summer. When high concentrations of PM_2.5 occurred, particulary in winter, the fraction of Zn and Pb components considerably increased, indicating a significant contribution of Zn and Pb to high-PM_2.5 concentration. In addition, Zn and Pb exhibited the highest correlation coefficient among all other metallic elements of PM_2.5. A backward trajectory cluster analysis and CPF model were performed to examine the origin of PM_2.5. The high concentration of PM_2.5 was primarily influenced by emissions from industrial complexes located in the northeast and northwest areas.

• 한국환경보건학회지
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• 제41권2호
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• pp.126-132
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• 2015

Objectives: The Korean government implemented a smoke-free regulation for pubs with a net indoor area of ${\geq}100m^2$ on January 1, 2014. The purpose of this study was to determine the indoor levels of concentrations of particulate matter smaller than $2.5{\mu}m$ ($PM_{2.5}$) in implemented and non-implemented pubs in Seoul and Changwon. Methods: $PM_{2.5}$ concentrations in fifty-two $100-150m^2$ (implemented) and fifty-seven < $100m^2$ (non-implemented) pubs were measured. A real-time aerosol monitor was used to measure $PM_{2.5}$ concentrations. Field technicians recorded characteristics of the pubs including net indoor area, indoor volume and presence of smoking rooms and counted the number of burning cigarettes, patrons and vents. Results: Differences between indoor and outdoor $PM_{2.5}$ concentrations in $100-150m^2$ and < $100m^2$ pubs were not significantly different in each city. Smoking was observed in 33% of $100-150m^2$ pubs and 51% of < $100m^2$ pubs. Average differences between indoor and outdoor $PM_{2.5}$ concentrations in the $100-150m^2$ and < $100m^2$ pubs were $79.2{\mu}g/m^3$ and $155.6{\mu}g/m^3$, respectively. When smokers were not observed, differences between indoor and outdoor $PM_{2.5}$ concentrations ware $12.4{\mu}g/m^3$ in $100-150m^2$ pubs and $24.5{\mu}g/m^3$ in < $100m^2$ pubs. Conclusion: Although the regulation was implemented only in ${\geq}100m^2$ pubs, a higher difference between indoor and outdoor $PM_{2.5}$ concentrations was observed in implemented and non-implemented pubs with smokers. Strict implementation of the regulation in all pubs is needed for better indoor air quality.

• 한국지구과학회지
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• 제30권2호
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• pp.196-209
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• 2009

2005년 1월부터 12월까지 지속적으로 몽골과 중국 북부의 사막과 건조지대에서 모래폭풍의 발생, 이동 그리고 한국에서 먼지침전(황사)을 모니터링하였다. NOAA 위성의 AVHRR(Advanced Very High Resolution Radiometer) 관측 자료를 직접 수신하여 false colour 합성영상을 만들어 모래폭풍의 발생과 이동 사례를 중점 분석하였다. 또한 모래폭풍 발원지의 풍하측에 위치한 한국 중부의 청원에서 PM10 농도가 $190{\mu}g\;m^{-3}$ 이상인 황사 사례에 대한 PM10, PM2.5농도와 시정 그리고 $O_3,\;NO_2,\;CO,\;SO_2$ 농도의 변동을 분석하였다. 2005년에는 발원지에 적설과 강력한 고기압, 저기압의 이동이 미흡하여 강한 모래폭풍의 발생이 적었고 한국에서도 황사의 발생 빈도가 1997-2005년의 평균과 비교하여 적었다. 한국에는 2005년 총 7회, 11일간의 황사 사례가 발생하였다. 여름에는 발원지가 습하고 바람이 약해 모래폭풍의 발생이 적었으며, 한국에서도 황사의 발생이 없었다. 발원지에서 발생한 모래폭풍이 중국의 대도시와 산업지대를 거치지 않고 한국으로 직접 이동할 경우, 먼지침전에 따른 PM2.5 농도는 PM10 농도의 20% 이하였다. 그러나 모래폭풍이 중국 동부의 산업지역을 거쳐 한국으로 이동할 경우 인위적 대기오염 물질이 함께 유입되어 PM2.5 농도가 증가하여 PM10농도의 25%이상을 나타내었다. 또한 2005년에는 사막에서 날아온 모래 먼지의 PM10농도가 $190{\mu}g\;m^{-3}$ 이하여서 황사로는 미흡한 5개 이상 사례를 관측 및 분석하였다.

• 한국산업보건학회지
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• 제26권4호
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• pp.411-417
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• 2016

Objectives: The aims of this study were to determine the indoor level of environmental tobacco smoke (ETS) and to assess the implementation rate of smoke-free laws at hospitality venues around a university campus by measuring particulate matter smaller than $2.5{\mu}m$ ($PM_{2.5}$) as an indicator of ETS. Materials and Methods: We measured indoor $PM_{2.5}$ concentrations at 20 PC game rooms, 20 pubs, and 20 billiards halls using Sidepak AM510, a direct reading portable real time monitor, from October to December 2015. Results: Smoking was observed in 65% of the PC game rooms, 10% of pubs, and 85% of billiards halls. The average $PM_{2.5}$ concentrations were $98.2{\mu}g/m^3$, $29.0{\mu}g/m^3$, and $134.2{\mu}g/m^3$ at PC game rooms, pubs, and billiards halls, respectively. $PM_{2.5}$ concentrations in PC game rooms and billiards halls were 2 to 2.7 times higher than the 24-hour exposure standard for outdoor $PM_{2.5}$ ($50{\mu}g/m^3$) by the Ministry of Environment. Conclusions: Although a smoking ban has been implemented for PC rooms and pubs, smoking is still taking place in many of these places. More stringent legal action is required for successfully protecting patrons and workers from secondhand smoke exposure. A ban on smoking in billiards halls should be introduced as quickly as possible.

• 분석과학
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• 제30권4호
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• pp.182-193
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• 2017

In order to examine the variation characteristics of chemical compositions in relation to the inflow pathways of Asian dust, $PM_{10}$ and $PM_{2.5}$ aerosols were collected at Gosan site of Jeju Island during the Asian dust days between 2010 and 2015, and their chemical compositions were analyzed. The mean mass concentrations of $PM_{10}$ and $PM_{2.5}$ during Asian dust days were $130.0{\pm}90.2$ and $38.2{\pm}24.7{\mu}g/m^3$, respectively. The composition ratios of major secondary pollutants ($nss-SO_4{^{2-}}$, $NH_4{^+}$, $NO_3{^-}$) were high as 53.7 % for $PM_{10-2.5}$ and 90.6 % for $PM_{2.5}$. When the Asian dusts had been transported to the Korean Peninsula via Loess Plateau of central China, the concentrations of $nss-Ca^{2+}$, $NH_4{^+}$, $nss-SO_4{^{2-}}$, and $NO_3{^-}$ increased more noticeably. Whereas in case when the inflow pathways of Asian dust had been through the Bohai bay, the concentrations of the crustal species such as Al, Fe, and Ca were relatively high in coarse particles. The atmospheric aerosols were acidified largely by sulfuric and nitric acids. They were neutralized mainly by calcium carbonate in coarse particle mode passed through Manchuria area, but by ammonia in fine particle mode passed through Loess plateau and Bohai bay. Ammonium salts are assumed to exist as ammonium sulfate and ammonium nitrate in coarse particles, but mostly as ammonium sulfate in fine particles.

• 분석과학
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• 제24권4호
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• pp.310-318
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• 2011

제주도 고산지역에서 $PM_{10}$과 $PM_{2.5}$ 미세먼지 시료를 채취하여 주요 성분의 화학 조성, 오염 정도, 배출원 특성 등을 조사하였다. 연구기간의 $PM_{10}$과 $PM_{2.5}$ 미세먼지의 질량농도는 각각 $37.6{\pm}20.1{\mu}g/m^3$, $22.9{\pm}14.3{\mu}g/m^3$로 $PM_{2.5}$ 질량농도는 $PM_{10}$의 약 61%를 차지하였다. $PM_{2.5}/PM_{10}$ 농도비를 조사해 본 결과, 인위적 기원의 nss-$SO_4^{2-}$, $NO_3$, $NH_4^+$은 주로 미세입자에, 그리고 nss-$Ca^{2+}$과 $Na^+$, $Cl^-$, $Mg^{2+}$ 성분들은 대부분 조대입자에 많이 분포하였다. 또 미세먼지 조성은 대체적으로 인위적 오염원의 영향이 가장 크고, 다음으로 토양 또는 해양의 영향을 많이 받는 것으로 나타났다. 역궤적 분석법으로 미세먼지 성분들의 유입경로를 조사해 본 결과, nss-$SO_4^{2-}$, $NO_3^-$, $NH_4^+$, nss-$Ca^{2+}$, Pb 성분들은 대체적으로 기류가 중국대륙과 한반도로부터 유입되었을 때 농도가 높게 나타났다. 반면에 북태평양이나 동해를 통해 유입되었을 때는 상대적으로 낮은 경향을 보였다.