• Title/Summary/Keyword: PMMA 판재

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Preparation and Mechanical Properties of PMMA Panels (PMMA 판재의 제조 및 기계적 특성)

  • 길기승;김의식;김대수
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.142-151
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    • 2003
  • PMMA panels are made by two fabrication methods; cell molding and belt molding processes. But these methods have disadvantages in productivity and cost. So plastic processing engineers are very interested in developing a new production method for PMU panels using plastic films as molds because the new method can reduce production cost of belt molding method as well as can improve productivity of cell molding method. To give a solution for developing such a new molding method, the effects of melthyl methacrylate compound composition and curing reaction condition on the processability and mechanical strength of PMMA panels were investigated in this study. Poly(vinyl acetate) film was used as molds in producing PMMA panels. To determine an MMA compound showing good processability and good mechanical properties after curing, ingredients and their compositions were optimized step by step. Acrylic acid, as a coupling agent and a modifier, played an important role in increasing mechanical strength of PMMA panels.

Characteristics of PMMA Sheet with Phosphorous Flame Retardant Additives (인계 첨가제를 이용한 PMMA판재의 난연성 물성 특성)

  • Kim, Yong-Ryeol;Lim, Sun-Young
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.224-230
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    • 2012
  • In this paper, flame-resisting PMMA(polymethyl methacrylate) sheet was manufactured and its characteristics were tested. PMMA was synthesized by bulk polymerization of a monomer methyl methacrylate with addition of phosphorous flame retardant, triethyl phosphate and ethylene glycol dimethacrylate as a cross linking agent. PMMA sheet was manufactured by using the cell molding method, which does not alter or affect the existing property of PMMA. Then the characteristics of PMMA sheet were tested for the TEP content, the content and curing time of EGDMA. As TEP content increases, the length of carbonization lessens and the amount of char production increases. As a result, it strengthened the effect of flame retardants. But the hardness of the sheet decreased as TEP content increased. However, hardness increased when EGDMA was added up to 3 wt% while curing time was decreased from 3 hours to 2 hours. There was no change of hardness when more than 3 wt% of EGDMA was used.