• Title/Summary/Keyword: PM from the atmosphere

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Features on the Vertical Size Distribution of Aerosols using Ballon-borne Optical Particle Counter at Anmyeon (광학입자계수기를 이용한 안면도 연직 에어러솔 수농도 크기 분포 특성)

  • Choi, B.C.;Iwasaka, Y.;Lim, J.C.;Jeong, S.B.;Kim, Y.S.;Dmitri, T.;Nagatani, T.;Yamada, M.;Kim, S.B.;Hong, G.M.;Lee, Y.G.;Yoo, H.J.
    • Atmosphere
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    • v.15 no.3
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    • pp.149-153
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    • 2005
  • A balloon-borne Optical Particle Counter (hereafter "OPC Sonde"), which was developed by the atmospheric research group of Nagoya University, is used for getting the information of vertical profile of particle size and concentration in Anmyeon ($36^{\circ}32^{\prime}N$ $126^{\circ}19^{\prime}E$) on 18 March 2005. A range of five different particle sizes is shown in the vertical profile of aerosol number density estimated from the OPC Sonde. It was found that small size particles have vertically larger aerosol number density than relatively big ones. For all size ranges the vertical aerosol number density shows a decreased pattern as the altitude becomes higher. The aerosol number density of $0.3{\sim}0.5{\mu}m$, $0.5{\sim}0.8{\mu}m$, $0.8{\sim}1.2{\mu}m$ size ranges at the 10km height, which is the tropopause approximately, are $1,000,000ea/m^3$, $100,000ea/m^3$, $10,000ea/m^3$ respectively. The data of OPC Sonde are also compared with the data of PM10 $\beta$-ray) and Micro Pulse Lidar which are operating at Korea Global Atmosphere Watch Observatory in Anmyeon.

Study on Chemical Characterization of $PM^{10}$ Observed in Korean Peninsula, 1998 ~ 2001

  • Bang, So-Young;Oh, S.N.;Choi, J.C.;Choi, B.C
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.61-64
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    • 2003
  • This study was conducted to investigate the chemical characteristics of $PM^{10}$ at Anmyeon-do during the periods from January 1998 to December 2001. The $PM^{10}$ samples ($PM^{10}$) were collected by High Volume Air sampler (HVAS). The measured items were mass concentration of $PM^{10}$ with the major ions ($Cl^{-}$, ${SO_{4}}^{2-}$, ${NO_3}^{-}$, ${Mg}^{2+}$, ${Ca}^{2+}$, ${K}^{+}$etc.) and metallic elements (AI, Fe, Mn, Cr, Zn, Pb etc.). The chemical analysis of major ion components were made by Ion Chromatography (DX-500) and that of metallic elements were made by Inductively Coupled Plasma Spectrometer (ICP-AES, ICP-Mass). The average mass concentration of $PM^{10}$ increased substantially during the heavy dust periods (Asian Dust cases). For water-soluble ions, concentrations of ${Ca}^{2+}$, ${SO_{4}}^{2-}$ and ${NO_3}^{-}$ were remarkably enhanced. Concentrations and mass fraction of crustal elements such as Na, Mg, Ca, Fe, Mn were highly elevated, but those of pollution-derived heavy metals were appreciably decreased. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables.

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The Barium Star HD204075: Iron Abundance and the Absence of Evidence for Accretion

  • Jeong, Yeuncheol;Yushchenko, Alexander;Gopka, Vira;Yushchenko, Volodymyr;Rittipruk, Pakakaew;Jeong, Kyung Sook;Demessinova, Aizat
    • Journal of Astronomy and Space Sciences
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    • v.36 no.3
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    • pp.105-113
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    • 2019
  • Spectroscopic observations of barium star ${\zeta}$ Capricornus (HD204075) obtained at the 8.2 m telescope of the European Southern Observatory, with a spectral resolving power R = 80,000 and signal to noise ratio greater than 300, were used to refine the atmospheric parameters. We found new values for effective temperature ($T_{eff}=5,300{\pm}50K$), surface gravity ($log\;g=1.82{\pm}0.15$), micro-turbulent velocity ($v_{micro}=2.52{\pm}0.10km/s$), and iron abundance ($log\;N(Fe)=7.32{\pm}0.06$). Previously published abundances of chemical elements in the atmosphere of HD204075 were analyzed and no correlations of these abundances with the second ionization potentials of these elements were found. This excludes the possible influence of accretion of hydrogen and helium atoms from the interstellar or circumstellar environment to the atmosphere of this star. The accretion of nuclear processed matter from the evolved binary companion was primary cause of the abundance anomalies. The young age of HD204075 allows an estimation of the time-scale for the creation of the abundance anomalies arising from accretion of interstellar hydrogen and helium as is the case of stars with low magnetic fields; which we estimate should exceed $10^8$ years.

Estimation of Tropospheric Water Vapor using GPS Observation (GPS를 이용한 대류권의 수증기량 추정에 관한 연구)

  • 송동섭;윤홍식;조재명
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.20 no.2
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    • pp.215-222
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    • 2002
  • As the GPS signals propagate from the GPS satellites to the receivers on the ground, they are delayed by the atmosphere. The tropospheric delay consists of two components. The hydrostatic (or "dry") component that is dependent on the dry air gasses in the atmosphere and accounts for approximately 90% of the delay. And the "wet" component that depends on the moisture content of the atmosphere and accounts for the remaining effect of the delay. The Zenith Hydrostatic Delay (ZHD) can be calculated from the local surface pressure. The Total Zenith Delay (TZD) will be estimated and the wet component extracted later. Integrated water Vapor (IWV) gives the total amount of water vapor that a signal from the zenith direction would encounter. Precipitable Water Vapor (PWV) is the IWV scaled by the density of water. The quality of this PWV has been verified by comparison with radiosonde data(at Osan). We processed data for JULY 2 and JULY 14, 1999 from four stations(Cheju, Kwangju, Suwon, Daegu). We found the coincidence between PWV of the estimations using GPS and PWV of pressing the radiosonde data. The average of the difference between PWV using GPS and PWV using radiosonde was 3.77 mm(Std. = $\pm$0.013 mm) and 2.70 mm(Std. = $\pm$0.0011 mm) at Suwon & Kwangju.

Composition of Organic Compounds in the Ambient PM10 of the Anmyon Island (안면도 미세먼지 내 유기성분들의 분포 특성)

  • Lee, Ji Yi;Hwang, Eun Jin;Lim, Hyung Bae;Kim, Yu Won;Kim, Eun Sil;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.187-197
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    • 2013
  • To understand the characteristics of organic aerosol(OA) at the background atmosphere of Korea, an observation of atmospheric PM10 was conducted at a Global Atmospheric Watch(GAW) station operated by the Korean Meteorological Administration at Anmyon Island during 2010. Various organic compounds were analyzed from 26 samples by using a gas chromatography-mass spectrometer. Water soluble organic carbon(WSOC) was also analyzed by using a total organic carbon(TOC) analyzer. Among 6 classes with 68 target compounds detected, the classes of n-alkanoic and alkenoic acids ($326.67{\pm}75.40ngm^{-3}$) and dicarboxylic acids ($323.74{\pm}361.89ngm^{-3}$) were found to be major compound classes in the atmosphere of Anmyon Island. Compared to the previous results reported for 2005 spring samples at Gosan site, the concentrations of organic compounds at Anmyon Island were 3-10 times higher than Gosan site due to the difference of location and sampling period. The concentrations of organic compounds were varied with the atmospheric conditions. Significant increase of the concentrations of dicarboxylic and carboxylic acids in the smog episode indicated that secondary oxidation of organic compounds was major factor to increase OA concentration during smog episode in the Anmyon Island. It was found that the compositions of the OA measured at Anmyon Island were dependent on the air parcel trajectories.

Source Identification of Fine Particle($PM_{2.5}$) in Chongju Using a Chemical Mass Balance Model (수용모델을 이용한 청주시 미세입자($PM_{2.5}$)의 기여도 추정)

  • 강병욱;이학성;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.5
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    • pp.477-485
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    • 2000
  • The data set was collected on fifty-eight different days with a 24-h sampling period from October 27, 1995 through August 25, 1996. From the chemical mass balance (CMB) analysis of $PM_{2.5}$ in the Chongju area, the contributions from soil, gasoline, diesel, light and heavy oil combustion were 2.6%, 15.4%, 9.0%, 28.8% and 1.5%, respectively. Residual $NO_{3}^{-}$), residual $SO_{4}^{2-}$ and residual OC, possibly formed in the atmosphere. represented additional 8.0, 10.2, and 1.6% of the $PM_{2.5}$, respectively. Other unidentified sources constituted the remaining 22.9%. From the CMB analysis, the $PM_{2.5}$ source contribution for fall, winter, spring and summer were 92, 76.8, 77.5 and 59.2%, respectively.

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Dimethylsulfide (DMS) in Seawater and the Overlying Atmosphere of the Masan Bay (해수 및 대기 중 DMS의 분석 : 마산만을 중심으로)

  • 김기현;오재룡;강성현;이수형;이강웅
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.495-504
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    • 1996
  • The concentrations of dimethylsulfide (DMS) were determined from both seawater and the overlying atmosphere from a station located in the Masan Bay area during a ten-day field campaign period of January 1996. The resulting data were also used to derive saturation ratios (SR) as well as sea-to-air fluxes of DMS. The concentrations and fluxes of DMS for both reservoirs varied extensively over two to three orders of magnitude: DMS in air and seawater were measured at 9 to 4,300 pptv (mean: 600 $\pm$ 1, 170, N=18) and at 0.24 to 10 nM (4.0 $\pm$ 3.4, N=13), respectively, while its fluxes were found from 0.02 to 23 mol $m^{-2} day^{-1} (3.1 \pm 6.8, N=11)$. A comparative analysis between our data and previously reported ones indicate that its atmospheric concentrations are abnormalously high, but its seawater counterparts are slightly lower than expected. In light of high pollution levels of organic-rich materials in and the associated high biological productivity of the study area, the sea-to-air-fluxes derived are notably low relative to those values typically reported from the coastal areas. These complicated features of DMS distributions/fluxes in the study site indicate that the near-by port- based anthropogenic activities from various industrial plants strongly interfere with natural processes leading to the production and release of DMS. It was however striking to find out relatively strong signals of diel cycle in its saturation ratios, concentration gradients between seawater and atmosphere, and the associated fluxes. Although it is yet difficult to provide meaningful explanations for the observed phenomena, the existence of clear diel cycle in some DMS-related parameters suggests that the natural processes may nonetheless exert important controls on the regional cycling of atmospheric sulfur species, of particular DMS.

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Distribution of Polycyclic Aromatic Hydrocarbons in PM$_{10}$ and its Adjacent Soil of Urban Atmosphere (도시대기의 미세먼지(PM$_{10}$) 및 주변토양중 다환방향족 탄화수소의 농도분포에 관한 연구)

  • 박기학;최성훈
    • Journal of Environmental Health Sciences
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    • v.24 no.2
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    • pp.1-8
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    • 1998
  • This study was carried out to investigate the distribution of PAHs in atmosphere and soil, and their relationship, accumulation tendency in soil, and its contain burden ratio (%) the PM$_{10}$ and soil were sampled adjacent to a roadside and analysed by HPLC from August 25th 1996 to September 22nd 1996 in Seoul and Kunggido area. The main results are summarized below 1. The concentration of PM$_{10}$ in the ambient air was showed in order of industrial region ($142.70\pm 21.77 \mu g/m^3$), commercial region ($136.51\pm 31.62 \mu g/m^3$), residential region ($110.12\pm 14.98 \mu g/m^3$), greenbelt region ($77.44\pm 12.12 \mu g/m^3$), respectively. 2. Distribution of PAHs concentration level in PM$_{10}$ and soil was showed in order of industrial region, commercial region, residential region, greenbelt region, respectively in all components. 3. The contain burden ratio (%) in PM$_{10}$ was attested that BbF was the highest contain burden component (21.7-32%) and An was the lowest contain burden component (0.35-1.95%) in all region. 4. The contain burden ratio (%) in soil was attested that Pb (20.5%) was the highest and An (0.8%) was the lowest contain burden component in industrial region and BbF (21.9%) and An (0.45%) were the same tendency in commercial region and Py (21.6%) and BkF (3.5%) were in residential region, Py (29%) and An (2.6%) were in greenbelt region. 5. The relationship between concentration of PAHs in PM$_{10}$ and soil was attested that the component of BbF (r=0.514) was very highly correlated, and there were significant in Fl and BaA in soil between industrial region and commercial region (P<0.05).

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Monthly Variation of n-alkanes concentration in PM2.5 of the Anmyeon Island (안면도 대기 중 PM2.5 내 n-alkanes의 월별 농도 분포 특성)

  • Kim, Ki Ae;Lee, Jong Sik;Kim, Eun Sil;Jung, Chang Hoon;Kim, Yong Pyo;Lee, Ji Yi
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.166-176
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    • 2018
  • The n-alkanes which are stable compounds in the atmosphere are emitted by anthropogenic sources and biological sources. The goal of this study is to understand characteristics of n-alkane distributions in $PM_{2.5}$ of the Anmyeon Island which is one of background site in Korea. The concentration of n-alkanes in $PM_{2.5}$ was measured at Anmyeon Island for one year from June 2015 to May 2016. The average concentration of total n-alkanes (${\sum}$ n-alkanes) from C20 to C34 was $14.02{\pm}10.26ng\;m^{-3}$ and ranged from 1.77 to $47.65ng\;m^{-3}$. Various diagnostic parameters were used to identify the source. As a result, it is considered that Anmyeon Island had a large influence of biological sources during non-heating period, while the influence of anthropogenic emission during the heating period was significant. Principle Component Analysis (PCA) was performed and yielded three components that accounted for 93.6% of the total variance in n-alkanes. Factor 1, which accounted for 42.3% of the total variance, indicated anthropogenic source including fossil fuel and biomass combustion, while, Factor 3 was interpreted as the biological sources such as plant wax.

The Numerical Simulation on the Wet Deposition of Particles (입자상 물질의 습성 침적에 관한 수치 모의)

  • Kim, Yu-Geun;Lee, Hwa-Un;Hong, Jeong-Hye
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.5
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    • pp.433-442
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    • 1998
  • The removal procedure of particles in the atmosphere was simulated in the saturated and dry conditions to know the effect of the saturated atmosphere on the size distributions of particles. The particles were divided into 5 ranges, 0.0mm, 0.0∼0.65mm, 0.65∼2mm, 2∼10mm and more than 10mm, and the gases were classified into the smallest range for calculation. At the dry condition, particles grew only by the collision -coalescence and were removed by gravitation. The particles in the range of 2.0∼10mm fell mostly at the 30 km distance from the pollutant source because of gravitation. The particles larger than 10 pm were removed at the 10 km distance from the pollutant source because of their gravity. But the particles larger than 10pm appeared again at more than 30km distance. It is considered that they have been grown during the smaller particles had been advected and diffused at that distance, and it needed about 1 hour from the moment of release. At the saturated condition, particles grew by both the collision-coalescence and condensation. The model showed that the condensation makes more number of particles larger than 10mm and then the particles were removed due to their large gravity. Only a few particles existed at the range of 0.65∼10mm and larger thats 10mm. It is concluded that the saturated atmosphere is effective on removing PM-10.

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