• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.220.2-220.2
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• 2011

Biodiesel and biodiesel blend fuel are receiving increasing attention as alternative fuels for diesel engines without substantial modifications. Biodiesel fuels and blending have been widely studied and applied in diesel engine because of biodiesel's lower sulfur, lower aromatic hydrocarbon and higher oxygen content. Biodiesels have the potential to be oxidized in different condition. It has reported that oxidation deterioration of biodiesel is different in the condition of storage and oxidation causes chemical property change of methyl esters. Sunlight intensity, temperature, material of container and contact surface with oxygen are key dominant factors accelerating oxidation deterioration. In this study, we chose temperature among key oxidation conditions and metal container filled with biodiesel was heated at about $110^{\circ}C$ for 10 days in order to accelerate oxidation deterioration. To better understand the effect of biodiesel blends on emission, steady state tests were conducted on a heavy duty diesel engine. The engine was fueled with Ultra Low Sulphur Diesel(ULSD), a blend of 10% and 20%(BD10, BD20) on volumetric basis, equipped with a common rail direct injection system and turbocharger, lives up to the requirements of EURO 3. The experimental results show that the blend fuel of normal biodiesel with BD10 and BD20 increased NOx. The result of PM was similar to diesel fuel on BD10, but the result of PM on BD20 was increased about 63% more than its of diesel. The blend fuel of Oxidation biodiesel with BD10 and BD20 increased NOx as the results of normal biodiesel. But PM was all increased on BD10 and BD20. Especially THC was extremely increased when test fuel contains biodiesel about 140% more than its of diesel. Through this study, we knew that oxidation deterioration of biodiesel affects emission of diesel engine.

• Asian Journal of Atmospheric Environment
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• v.12 no.3
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• pp.274-288
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• 2018

Quantitative data of 50 non-polar organic compounds constituting $PM_{2.5}$ were continuously collected and analyzed from June 2016 to October 2017 (approximately 17 months) at Ichihara, one of the largest industrial areas in Japan. Target non-polar organic compounds including 21 species of polycyclic aromatic hydrocarbons (PAHs), 24 species of n-alkanes and 5 species of phthalate esters(PAEs) were simultaneously measured by gas chromatography/mass spectrometry. Basically, the average concentrations of the total PAHs, n-alkanes and PAEs in each season remained nearly level, and seasonal variations were little throughout the study period. These results suggest that the emission sources, which are not influenced by the seasons, are the dominant inputs for the target organic compounds. Diagnostic ratios of PAHs, assessment of n-alkane homologue distributions, carbon preference index, and the contribution of wax n-alkanes from plants were used to estimate source apportionments. These results indicate that anthropogenic sources were the main contributor for most PAHs and n-alkanes throughout the study period. The concentrations of PAEs selected in this study were low because emission amounts of these chemicals were little within the source areas of the sampling site. To our knowledge, this study is the first attempt to simultaneously measure a high number of non-polar organic compounds in $PM_{2.5}$ collected from the ambient air of Japan, and the resultant data will provide valuable data and information for environmental researchers.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.1
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• pp.181-187
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• 2008

Recently, alternative fuels are drawing more attentions due to the increasing need for lower emission characteristics and fuel consumption rate in automotive engines. The GTL(gas to luquid) is the one of most favored candidates. It has higher cetane number(more than 75) and almost negligible sulphur and aromatic contents. Therefore, enhanced emission characteristics are expected even in the application in diesel engines without any modification. In this study, the cylinder pressure and heat release, emission characteristics with fuel injection timings are compared between diesel and GTL fuel in the single cylinder diesel engine. Noticeable reduction in PM, THC and CO emission are observed due to lower sulphur and aromatic contents in GTL. Also, the ignition delay decreased due to higher cetane number of GTL, which slightly decreased the amount of NOx emissions. With the retards of main injection timing, NOx decreases more for the case of GTL, while the level of THC and CO emissions still remains lower than the case of diesel. Therefore, there is much room for the control of injection timing for NOx reduction without sacrificing THC and CO emissions. With the retards of main injection timing, Small size distribution of PM became lager and there amount increased. But from all conditions, size distribution of PM for the case GTL was lower than Diesel.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.2
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• pp.294-305
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• 2018

Quantitative assessment on the impact from North Korean emissions to surface particulate matter(PM) concentration in the Seoul Metropolitan Area (SMA), South Korea is conducted using a 3-dimensional chemistry transport model. Transboundary transport of air pollutants and their precursors are important to understand regional air quality in East Asian countries. As North Korea locates in the middle of main transport pathways of Chinese pollutants, quantifiable estimation of its impact is essential for policy making in South Korean air quality management. In this study, the Community Multiscale Air Quality Modeling System is utilized to simulate regional air quality and its sensitivity, using the Comprehensive Regional Emissions inventory for Atmospheric Transport Experiment 2015 and the Clean Air Policy Support System 2013 emissions inventories for North and South Korea, respectively. Contributions were estimated by a brute force method, perturbing 50% of North and South Korean emissions. Simulations demonstrate that North Korean emissions contribute $3.89{\mu}g/m^3$ of annual surface PM concentrations in the SMA, which accounts 14.7% of the region's average. Impacts are dominant in nitrate and organic carbon (OC) concentrations, attributing almost 40% of SMA OC concentration during January and February. Clear seasonal variations are also found in North Korean emissions contribution to South Korea (and vice versa) due to seasonal characteristics of synoptic weather, especially by the change of seasonal flow patterns.

• Journal of Environmental Health Sciences
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• v.35 no.4
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• pp.304-314
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• 2009

A new harbor as been constructing in Gadukdo. However, a lot of fugitive dust gas been often generated from construction site reclaiming sea sand, especially when the Northwester is blown strongly. It has resulted insome appeals of residents in Gadukdo. In this study, we estimated the amount of fugitive dust caused by new harbor construction using Fugitive dust formula. Also, the concentration of PM10 for recipient is predicted by AERMOD. The amount of fugitive dust is 26.56 ${\mu}g/sec{\cdot}m^2$ and 11.84 ${\mu}g/sec{\cdot}m^2$ respectively by the Fugitive dust formula. PM10 outlet concentration and the amount of fugitive dust increase according to wind velocity and directions. AERMOD is performed on the basis of weather data and the amount of fugitive dust generated with wind velocity. As a result of AERMOD, the PM10 concentration of Sunchang and Oinul are predicted over 100 ${\mu}g/m^3$. The PM10 concentration of Sunchang and Oinul are predicted over 130 ${\mu}g/m^3$ when wind velocity of northwester in winter is over 11 m/s (Air Quality for Particulate Matter (100 ${\mu}g/m^3$ for 24 hours)). Also, the measured error between AERMOD and actual measurement is lower than 5%.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.27 no.4
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• pp.361-370
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• 2017

Objectives: This study evaluated the diesel engine exhaust (DEE) exposure levels of door-to-door deliverers in Daegu from July to September. Methods: We measured exposure levels of DEE surrogates for the same door-to-door deliverers who joined the particulate matter 2.5 exposure study previously published in this journal. Black carbon(BC) concentrations were measured using real-time BC monitoring devices with 1 minute interval. $NO_2$ concentrations were monitored using passive badges. DEE exposure data were analyzed using the same characteristics and GPS information as the first study. Results: A total of 40 measurements of BC concentrations and $NO_2$ concentrations were collected during delivery of parcels. The average exposure levels to BC, and $NO_2$ were $2.23{\mu}g/m^3$ ($0.001-350.85{\mu}g/m^3$) and 21.26 ppb(3.3-61.37 ppb), respectively. Exposure levels to BC according to the day of a week and coverage areas were not significantly different(p>0.05). Delivery trucks manufactured before 2006 caused significantly higher exposure to BC than the trucks manufactured after 2006(p<0.05). Exposure levels of BC integrated for each time in residential area and roadsides were $1.96{\mu}g/m^3$ and $3.46{\mu}g/m^3$, respectively, and the difference was statistically significant(p<0.001). The Pearson correlation coefficients between the ambient $PM_{2.5}$ and BC was significant, r=0.26(p<0.01); however, the correlations between $PM_{2.5}$ and ambient $PM_{2.5}$, and between BC of DEE and $PM_{2.5}$ of DEE did not show a significant correlation Conclusions: BC and $NO_2$ exposure levels were significantly lower when door-to-door deliverers drove newer trucks. BC exposure levels of deliverers were higher in roadsides than in residential area. DEE from nearby vehicles through open windows might be the main source of BC exposure.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.3
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• pp.153-159
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• 2007

Nano-Particles are influenced on the environmental protection and human health. The relationships between transient vehicle operation and nano-particle emissions are not well-known, especially for diesel passenger vehicles with DPF. In this study, a diesel passenger vehicle was measured on condition of DPF regeneration and no regeneration on a chassis dynamometer test bench. The particulate matter (PM) emission from this vehicle was measured by its number, size and mass measurement. The mass of the total PM was evaluated with the standard gravimetric measurement method while the total number and size concentrations were measured on a NEDC driving cycle using Condensation Particle Counter (CPC) and EEPS. Total number concentration by CPC was $1.5{\times}10^{1l}N/km$, which was 20% of result by EEPS. This means about 80% of total particle emission is consist of volatile and small-sized particles(<22nm). During regeneration, particle emission was $6.2{\times}10^{12}N/km$, was emitted 400 times compared with the emission before regeneration. As for the particle size of $22{\sim}100nm$ was emitted mainly, showing peak value of near 40nm in size. This means regeneration decreased the mean size of particles. Regarding regeneration, PM showed no change while the particle number showed about 6 times difference between before and after regeneration. It seems that the regeneration influences on particle number emissions are related to DPF-fill state and filtration efficiency.

• Journal of Environmental Health Sciences
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• v.36 no.3
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• pp.182-190
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• 2010

We examined the association of particulate matter with an aerodynamic diameter < $10\;{\mu}m$ ($PM_{10}$) with asthma-related hospitalization, stratified by socioeconomic status (SES), among children less than 15 years of age in Seoul, Korea, between 2003 and 2005. In addition, we estimated the reduction in the number of asthma-related hospitalizations that would result from implementing the World Health Organization (WHO) guideline. SES was defined based on data concerning health insurance premium grades, and grouped into two levels: lower-income group and control group. The lower-income group was classified as having an accumulated income which did not exceed the 50th percentile of the median income. Time-series analysis was performed to evaluate the association between $PM_{10}$ and asthma-related hospitalization. The Environmental Benefits Mapping and Analysis Program was used to analyze the impact on children's health. Based upon an increase of $10\;{\mu}g/m^3$ of $PM_{10}$, the asthma-related hospitalization risk for the lower-income group was increased by 1.78% (95% confidence intervals (CI) = 0.79-2.78%), while the risk for the control group was increased by 0.83% (95% CI = 0.34-1.32%). Attaining the WHO guideline, relative to the concentration in 2007, would result in a reduction in asthma-related hospitalizations of 18 cases per 100,000 of the children population in the lower-income group, and 7 cases in the control group. The health benefits of improved air quality for children in the lower-income group were thus 2.5 times greater than for children in the control group. Our results show that the lower-income group is disproportionately burdened with asthma-related hospitalization arising from air pollution. Therefore, biologically- and socioeconomically-disadvantaged populations should be considered in public health interventions in order to protect the children's health.

• Journal of odor and indoor environment
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• v.17 no.4
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• pp.337-345
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• 2018

In this study, we measured the concentration of Particulate Matter($PM_{10}$), Formaldehyde(HCHO), and Total Bacteria Count (TBC) at two facilities: day care centers, and postnatal care centers located in the cities of Gyeonggi, Gangwon, Jeolla and Gyeongsang from January 1, 2012 to December 31, 2015. $PM_{10}$ concentration was similar to the day care centers and postnatal care centers. HCHO concentration was the highest in the postnatal care centers. TBC concentration was the highest in the day care centers. Comparing the different cities, $PM_{10}$ concentration was the highest in Gyeonggi, HCHO concentration was the highest in Gyeonggi, and TBC concentration was the highest in Gyeonggi. As a result of HCHO's risk assessment, it was found that adults exceeded the carcinogenicity tolerance of $10^{-6}$ specified by the US EPA. This study is expected to be helpful in preventing damage to health from the contaminated indoor air at sensitive facilities, and can be used as basic data for indoor air quality management.

• Journal of Korean Tunnelling and Underground Space Association
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• v.22 no.5
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• pp.591-610
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• 2020

Concrete with activated carbon and titanium dioxide (TiO₂) has been used to reduce the particulate matter (PM) in underground structures (e.g., tunnels) due to the high performance of nitrogen oxides (NOx) abatement. Damage (e.g. crack, spalling, or detachment) can be caused by the environmental and ageing effects on the surface of the particulate matter reduction concrete, installed on the tunnel lining. Therefore, it is important to evaluate the existence of spalling on the concrete surface for maintaining performance of NOx reduction. In this study, a basic research was performed for feasibility of spalling evaluation using electrical resistivity characteristics. Given the test results, the electrical resistivity was decreased as the ratios of activated carbon (0~15%) and TiO₂ (0~25%) were increased for specimens. Under a dry condition, electrical resistivity of cement specimens, mixed with activated carbon and TiO₂, was decreased up to 2.3 times, compared with the normal cement specimen. In addition, under saturation conditions (degree of saturation: 85~98%), electrical resistivity of cement specimens with activated carbon, was decreased up to 3.5 times, compared with the normal cement specimen. Regardless of the condition (dry or saturated), the difference of electrical resistivity values shows the range of 2.3~2.8 times between the mixing specimen (with activated carbon (15%) and TiO₂ (25%)) and the normal cement specimen. This study can help to provide basic knowledge for spalling evaluation using the electrical resistivity on the surface of the particulate matter reduction concrete in tunnels.