• Title/Summary/Keyword: PLLA/MMT nanocomposite

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Thermal and Mechanical Properties with Hydrolysis of PLLA/MMT Nanocomposite (PLLA/MMT 나노복합재료의 가수분해에 따른 열적, 기계적 물성)

  • Lee Jong Hun;Lee Yun Hui;Lee Doo Sung;Lee Youn-Kwan;Nam Jae-Do
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.375-379
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    • 2005
  • The morphology and therma]/viscoelastic characteristics were investigated for PLLA/MMT nanocomposite manufactured by incorporating inorganic nanosized silicate nanoplatelets into biodeuadable poly(l-lactic acid) (PLLA). The XRD difiactogram and TEM image may be regarded as a formation of homogeneously dispersed nanocomposites. The melting energy(${\Delta}H_m$) was increased during hydrolysis process because of increase of crystallinity. As MMT played a role of reinforcing agent, the storage modulus was increase in case of PLLA/MMT nanocomposite, it was well coincided with our previous results. From SEM image, many tiny pinholes formed by spinodal decomposition were observed on the surface, and the shape of nanocomposite was maintained during hydrolysis process. In this study, it was shown that the control of biodegradation rate, thermal/mechnical property was possibile by incorporating MMT.