• Title/Summary/Keyword: PLASMA SURFACE TREATMENT

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Effect of ultra - violet laser treatment on multi - wall carbon nanotube surface

  • Kim, Jun-Sik;Ahn, Kyoung-Soo;Lee, Chang-Hyo;Kim, Chae-Ok;Hong, Jin-Pyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.689-691
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    • 2002
  • Well-aligned multi-wall carbon nanotubes (MWCNTs) have been grown on both Coming glass and silicon substrates at about 400 $^{\circ}C$ by a modified plasma - enhanced chemical vapor deposition system. We have investigated laser irradiation effect on carbon nanotube surface by using an ultra - violet laser. The laser operated to modify structural defect of was carbon nanotube and to ablate possible contamination of carbon nanotube surface. The morphology and surface transformation of MWCNTs as analyzed by a SEM. In addition, the field emission measurement was also carried out in a vacuum chamber with a $10^{-7}$ Torr base pressure by applying bias voltages up to 1000V.

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A Study on the Surface Wettability of Inorganic Insulator (무기절연물 표면상의 젖음성 변화에 관한 연구)

  • Hwang, Yeong-Han;Eom, Moo-Soo;Lee, Kyu-Chul;Lee, Jong-Ho
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1233-1235
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    • 1993
  • With the Contact angle of phase epoxy resin on the inorganic filler(glass plate) surface treated with air plasma, we have studied about the interface between epoxy resin and glass plate as simple model of a glass fiber reinforced composite materials. The contact angle on the inorganic filler surface varied with ambient temperature and surface treatment conditions.

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Optimization for Electro Deposition Process of PC/ABS Resin Surface Treatment (수지의 하전 입자빔 전처리 공정의 최적화)

  • Park, Young Sik;Shim, Ha-Mong;Na, Myung Hwan;Song, Ho-Chun;Yoon, Sanghoo;Jang, Keun Sam
    • The Korean Journal of Applied Statistics
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    • v.27 no.4
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    • pp.543-552
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    • 2014
  • High bandwidth RF such as Bluetooth, GPRS, EDGE, 3GSM, HSDPA is papular in the mobile phone market. A non-conducting metal coating process requires an e-beam deposition of metal, two steps of UV hard coating primer and top coating; however, it is inefficient. We navigate to the electron beam irradiation conditions(resin surface treatment conditions) in the PC/ABS resin injection process. By analyzing the experimental results, we find the optimum development conditions for the electro deposition pre-treatment process and mass production lines using the plasma generated electron beam source.

Effect of DC Bias on the Growth of Nanocrystalline Diamond Films by Microwave Plasma CVD (마이크로웨이브 플라즈마 CVD에 의한 나노결정질 다이아몬드 박막 성장 시 DC 바이어스 효과)

  • Kim, In-Sup;Kang, Chan Hyoung
    • Journal of the Korean institute of surface engineering
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    • v.46 no.1
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    • pp.29-35
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    • 2013
  • The effect of DC bias on the growth of nanocrystalline diamond films on silicon substrate by microwave plasma chemical vapor deposition has been studied varying the substrate temperature (400, 500, 600, and $700^{\circ}C$), deposition time (0.5, 1, and 2h), and bias voltage (-50, -100, -150, and -200 V) at the microwave power of 1.2 kW, working pressure of 110 torr, and gas ratio of Ar/1%$CH_4$. In the case of low negative bias voltages (-50 and -100 V), the diamond particles were observed to grow to thin film slower than the case without bias. Applying the moderate DC bias is believed to induce the bombardment of energetic carbon and argon ions on the substrate to result in etching the surfaces of growing diamond particles or film. In the case of higher negative voltages (-150 and -200 V), the growth rate of diamond film increased with the increasing DC bias. Applying the higher DC bias increased the number of nucleation sites, and, subsequently, enhanced the film growth rate. Under the -150 V bias, the height (h) of diamond films exhibited an $h=k{\sqrt{t}}$ relationship with deposition time (t), where the growth rate constant (k) showed an Arrhenius relationship with the activation energy of 7.19 kcal/mol. The rate determining step is believed to be the surface diffusion of activated carbon species, but the more subtle theoretical treatment is required for the more precise interpretation.

A surface resistance effect on the fabrication of Dye-sensitized Solar Cell with various widths (셀 폭에 따른 염료 감응형 태양전지의 표면저항 효과)

  • Choi, Jin-Young;Kim, Yong-Cheol;Park, Sung-Jun;Sung, Youl-Moon;Kim, Whi-Young;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.187-191
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    • 2006
  • Sputter deposition followed by surface treatment was studied using reactive RF plasma as a method for preparing titanium oxide $(TiO_2)$ films on the FTO $(SnO_2: F)$ substrate for dye-sensitized solar cells (DSCs). Anatase structure $TiO_2$ films deposited by reactive RF magnetron sputtering under the conditions of $Ar/O_2(5%)$ mixtures, RF power of 600W and substrate temperature of $400^{\circ}C$ were surface-treated by inductive coupled plasma (ICP) with $Ar/O_2$ mixtures at substrate temperature of $400^{\circ}C$, and thus the films were applied to the DSCs. We have chosen a solar cell width as a variable of a large-scaled DSCs and confirmed electric characteristics of an individual cell. As a result, the higher the internal resistance of DSC becomes, the wider the width gets. Internal resistance makes it difficult to collect photoelectron generated from dye. Ultimately up sizing DSC causes the increase of internal resistance and then has a bad effect on the cell characteristics.

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Gas Adsorption Characteristics of by Interaction between Oxygen Functional Groups Introduced on Activated Carbon Fibers and Acetic Acid Molecules (활성탄소섬유에 도입된 산소작용기와 초산 분자와의 상호작용에 따른 가스 흡착 특성)

  • Song, Eun Ji;Kim, Min-Ji;Han, Jeong-In;Choi, Ye Ji;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.30 no.2
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    • pp.160-166
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    • 2019
  • In this study, oxygen functional groups were introduced on activated carbon fibers (ACFs) by oxygen plasma treatment to improve the adsorption performance on an acetic acid which is a sick house syndrome induced gas. The active species was generated more as the flow rate of the oxygen gas increased during the plasma treatment. For this reason, the specific surface area (SSA) of the ACFs decreased with much more physical and chemical etching. In particular, the SSA of the sample (A-O60) injected with an oxygen gas flow rate of 60 sccm was reduced to about $1.198m^2/g$, which was about 6.95% lower than that of the untreated samples. On the other hand, the oxygen content introduced into the surface of ACFs increased up to 35.87%. Also, the adsorption performance on the acetic acid gas of the oxygen plasma-treated ACFs was improved by up to 43% compared to that of using the untreated ACFs. It is attributed to the formation of the hydrogen bonding due to the dipole moments between acetic acid molecules and oxygen functional groups such as O=C-O introduced by the oxygen plasma treatment.

Reforming of Hydrocarbon Fuel Using Water Jet Plasma (Water Jet 플라즈마를 이용한 탄화수소 연료 개질)

  • Kim, Seong-Cheon;Chun, Young-Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.9
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    • pp.949-954
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    • 2006
  • The purpose of this paper is to develop water jet plasma reactor and investigate the optimal condition of the syngas production by reforming of hydrocarbon fuel. Fuel used was propane and plasma was generated by arc discharge on water jet surface. Discharge slipping over the water surface has a number of advantages such as a source of short-wave and UV radiation, and it can be used for biological and chemical purification of water. Parametric screening studies were conducted, in which there were the variations of power ($0.18{\sim}0.74$ kW), water jet flow rate($38.4{\sim}65.6$ mL/min), electrode gap($5{\sim}15$ mm) and treatment time($2{\sim}20$ min). When the variations were 0.4 kW, 53.9 mL/min, 10 mm and 20 min respectively, result of maximum $H_2$ concentration was 61.6%, intermediates concentration were 6.1% and propane conversion rate was 99.8%.

Characteristics of Plasma Electrolytic Oxidation Coatings on Mg-Zn-Y Alloys Prepared by Gas Atomization (가스 분사법으로 제조한 Mg-Zn-Y 합금의 플라즈마 전해 산화 피막 특성에 관한 연구)

  • Chang, Si-Young;Cho, Han-Gyoung;Lee, Du-Hyung;Kim, Taek-Soo
    • Journal of Powder Materials
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    • v.14 no.6
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    • pp.372-379
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    • 2007
  • The microstructure, mechanical and electrochemical properties of plasma electrolytic coatings (PEO) coatings on Mg-4.3 wt%Zn-1.0 wt%Y and Mg-1.0 wt%Zn-2.0 wt%Y alloys prepared by gas atomization, followed by compaction at 320 for 10 min under the pressure of 700 MPa and sintering at 380 and 420 respectively for 24 h, were investigated, which was compared with the cast Mg-1.0 wt%Zn alloy. All coatings consisting of MgO and $Mg_2SiO_4$ oxides showed porous and coarse surface features with some volcano top-like pores distributed disorderly and cracks between pores. In particular, the surface of coatings on Mg-1.0 wt%Zn-2.0 wt%Y alloy showed smaller area of pores and cracks compared to the Mg-4.3 wt%Zn-1.0 wt%Y and Mg-1.0 wt%Zn alloys. The cross section micro-hardness of coatings on the gas atomized Mg-Zn-Y alloys was higher than that on the cast Mg-1.0 wt%Zn alloy. Additionally, the coated Mg-1.0 wt%Zn-2.0 wt%Y alloy exhibited the best corrosion resistance in 3.5%NaCl solution. It could be concluded that the addition of Y has a beneficial effect on the formation of protective and hard coatings on Mg alloys by plasma electrolytic oxidation treatment.

Plasma Treatment Effect of Organic/Organic Core-Shell Acrylic Adhesive Binder (II) (Organic/Organic Core-Shell 아크릴 접착바인더의 플라즈마 처리영향 (II))

  • Seul, Soo-Duk
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.89-96
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    • 2010
  • Adhesive binders with core-shell structure of organic/organic pair were prepared by emulsion polymerization of acrylic monomers, such as methyl methacrylate(MMA), ethyl acrylate(EA), n-butyl acrylate(BA), and styrene(St). Ammonium persulfate (APS) was used as an water soluble initiator in the presence of an anionic surfactant, sodium dodecyl benzene sulfonate (SDBS). Non-woven fabric and leather were impregnated with the adhesive binder. The surface of the impregnated fabric and leather were treated with plasma technique and then kinetics analysis and mechanical properties were measured. The conversions of the polymerization of core-shell binder (MMA/EA, MMA/BA) were greater than 90%. When the core-shell binder was prepared at equimolar conditions, the increasing effect of the core-shell binder on the state peel strength of the impregnated and plasma-treated non-woven/non-woven fabric has the order of MMA/St, EA/BA, BA/MMA, EA/St, and EA/MMA. When the core-shell binder was prepared at non-equimolar conditions, the increasing effect of the core-shell binder on the state peel strength of the non-woven fabric/leather has the order of MMA/BA, BA/EA, MMA/EA, St/MMA, and EA/St.

Effects of Palm Kernel Cake on Performance and Blood Lipids in Rats

  • Loh, T.C.;Foo, H.L.;Tan, B.K.;Jelan, Z.A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.8
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    • pp.1165-1169
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    • 2002
  • Palm kernel cake (PKC), a by-product of oil palm seeds after extraction of their oil. The aim of this study was to investigate the effects of different levels of PKC on growth performance and blood lipids in rats. A total of 64 Sprague-Dawley (8 weeks of age) male rats were assigned individually to four treatments with different levels of PKC in the diet: 0, 15, 20 and 25%. No differences (p<0.05) were found in daily feed intake (6-8 g/day), body weight, growth rate and epididymal fat weight for all the dietary groups. Plasma protein and very low density lipoprotein (VLDL) triacylglycerol (TG) were higher (p<0.05) for 20% PKC fed rats than the control rats. Conversely, the plasma cholesterol and TG and VLDL-phospholipid (PL) concentrations of the control rats were higher (p<0.05) than those of PKC fed rats. The VLDL-protein, total cholesterol, free cholesterol (FC) and cholesteryl ester (CE) were not significantly different (p>0.05) among the treatment groups. Rats fed PKC had greater (p<0.05) ratios of total surface to core lipid components [(FC+PL)/(CE+TG)] than control rats. The results reflect dissimilarities of VLDL particle size between PKC treatment and control rats, where the plasma of the PKC treated rats contained more lipid rich VLDL. In conclusion, there was no adverse effect on growth performance when inclusion of PKC up to 25%. However, fibre content may affect the plasma lipid concentrations.