• Journal of Soil and Groundwater Environment
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• v.28 no.6
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• pp.58-70
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• 2023

The improper management of radioactive waste or accidents caused by natural disasters can result in the release of radioactive materials into the surrounding environment, potentially leading to soil and groundwater contamination by radionuclides. In this study, adsorption-desorption behaviors of the radionuclides (cobalt and strontium) in natural soil, montmorillonite, Mn-PILC, Fe-PILC, and fishbone were investigated. Several models were used to predict adsorption isotherms of radionuclides on various absorbents. Adsorption isotherms of cobalt and strontium in several adsorbents were examined at pH 5.5. The amount of sorbed cobalt and strontium were represented fishbone > natural soil > Mn-PILC > Fe-PILC > montmorillonite and natural soil > Mn-PILC > fishbone > Fe-PILC > montmorillonite, respectively. Adsorption datas were fitted with several models such as Freundlich, Langmuir, Sips, Redlich-Peterson, Khan, and Generalized model. The results of curve fitting showed R²> 0.98 in all of adsorption models, except Sr²⁺ adsorption onto montmorillonite. For modified clays (Mn-PILC, Fe-PILC), it is suggested that, unlike natural soils and fish bones, there are not only single adsorption mechanisms but also adsorption mechanisms based on chemical adsorption and surface charge. In the case of fish bones, due to the relatively higher adsorption capacity than modified clays and its characteristic of significant desorption, it is expected more suitable for the removal of radionuclides in aquatic environments than for the immobilization of radionuclides in soil.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.05b
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• pp.99-99
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• 2003

육상에서 발생하는 공해 물질뿐만 아니라 해상에서 발생하는 공해 물질에 대한 관심이 높아진 가운데 선박에서 발생하는 탄화수소, 질소산화물, 일산화탄소, 이산화황 및 입자상 물질의 규제에 관한 방안이 가시화되고 있는 현실이다. 선박엔진에서 발생하는 질소산화물 제거 연구를 위해서 당사에서는 엔진 연료 분사 시스템에 관한 연구와 더불어 후처리 설비인 SCR 연구를 병행하고 있다. 본 연구는 당사 개발 촉매인 PILC(Pillared Interlayer Clay)를 이용한 SCR 적용에 관한 연구 결과중 촉매 특성에 관한 부분이다. (중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2005.11a
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• pp.179-180
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• 2005

• Journal of the Korean Applied Science and Technology
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• v.34 no.4
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• pp.799-806
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• 2017

The potential use of modified clays in the adsorption of vapor phase benzene and toluene was investigated. The modified clays OC-CPC, IOC, and Al-PILC were prepared for comparative purposes and were characterized using infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction. It was confirmed the intercalation of the aluminium pillar in IOC and Al-PILC, as well as the introduction of cetylpyridinium. The adsorption studies showed a great affinity of benzene and toluene for OC-CPC due to the hydrophobic character that resulted and also to the increase in the interlaminar distance. IOC showed a lower affinity for the benzene and toluene, followed by Al-PILC. Natual clay had no affinity for benzene and toluene due to its hydrophilic nature. Clay materials having a laminar structure can be chemically modified, changing their physiochemical characteristics, such as interlaminar distance, surface area, pore size, and chemical affinity. In this study, it was focused on obtaining modified clays to be used for the adsorption of volatile organic chemicals.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.23-24
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• 2006

The International Maritime Organization announced that the regulation of nitrogen oxide put into force for vessels constructed after 2000 from May, 2005 as agenda is satisfied on May, 2004. A honeycomb-typed Pillared Inter-Layered Clay(PILC) catalyst was developed for do-NOx SCR system in 2004. This catalyst has been applied to 9H25/33 engine that is one of the main diesel engines in Engine Machinery Division of the Hyundai Heavy Industries CO., LTD. In addition, we have tried to develop better catalysts in the aspects of easy synthetic method and performance.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07a
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• pp.353-356
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• 2005

We have characterized the mechanical stability of the Pixel-Isolated Liquid Crystal (PILC) mode for plastic LC display applications. In our device, the LC molecules are fully isolated in the pixels by the phase-separated polymer walls. The experimental results of microscopic observation and electro-optic characterization show that our flexible PILC device has good mechanical stability against external point pressure or bending distortion due to the polymer walls in our structure.

• The KIPS Transactions:PartC
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• v.9C no.2
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• pp.197-212
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• 2002

Transmission Control Protocol (TCP) [1] has been tuned as a reliable transfer protocol for traditional networks comprising wired links and stationary hosts with same link characteristics. TCP assumes that congestion in the network be a primary cause for packet losses and unusual delays. TCP performs welt over such networks adapting to end-to-end delays and congestion losses, by standard congestion control mechanisms, such as slow-start, congestion avoidance, fast retransmit and recovery. However, networks with wireless and other lossy links suffer from significant losses due to bit errors and handoffs. An asymmetry network such as ADSL has different bandwidth for both directions. As a result, TCP's standard mechanisms incur end-to-end performance degradation in various links. In this paper, we analyze the TCP problems in wireless, satellite, and asymmetry links, and measure the new TCP mechanisms that are recommended by IETF Performance Implications of Link Characteristics (PILC) WG[2], by using Network Simulator 2 (NS-2).

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.931-934
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• 2009

EHA(ethylhexyl acrylate), well known for the prepolymer used for PDLC, was used for the LC/polymer composite system for pixel isolated LC (PILC). In order to improve the polymer wall structures of EHA, various acrylate prepolymers were blended with EHA prepolymer.

• Environmental Engineering Research
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• v.25 no.2
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• pp.186-196
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• 2020

Pillared clays with Zr and Fe/Cu/Zr polycations have been prepared from natural clays found in large deposits of Kazakhstan and assessed as catalysts for the catalytic wet peroxide oxidation (CWPO), using 4-nitrophenol (4-NP) as model compound. The performance of the catalysts was followed by measuring the concentration of 4-NP, H₂O₂ and the total organic carbon (TOC), considering C_4-NP = 5 g L^-1, $C_{H_2O_2}$ = 17.8 g L^-1, C_cat = 2.5 g L^-1, initial pH = 3.0 and T = 50℃. At those selected conditions, the pillared clays showed higher activity than natural clays in the CWPO of 4-NP. The conversion of the model pollutant was complete when Fe/Cu/Zr-PILCs were used, with the TOC removal reaching 78.4% after 24 h with the best Fe/Cu/Zr-PILC. The H₂O₂, 4-NP and TOC time-evolution was well described by a kinetic model based on TOC lumps in three blocks, considering the initial TOC (corresponding to 4-NP), the production of oxidizable intermediates and the formation of refractory products.

• Journal of Korea Water Resources Association
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• v.55 no.spc1
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• pp.1223-1234
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• 2022

Efforts for reducing greenhouse gas emission coping with climate change have also been performed in the field of water and wastewater works. In particular, the technical development for reducing energy has been applied in operating water distribution system. The reduction of energy in water distribution system can be achieved by reducing structural loss induced by topographic variation and operational loss induced by leakage and friction. However, both analytical and numerical approaches for analyzing energy budget of water distribution system has been challengeable because energy components are affected by the complex interaction of affecting factors. This research drew mathematical equations for 5 types of state (hypothetical, ideal, leak-included ideal, leak-excluded real, and real), which depend on the assumptions of topographic variation, leakage, and friction. Furthermore, the derived equations are schematically illustrated and applied into simple water network. The suggested method makes water utilities quantify, classify, and evaluate the energy of water distribution system.