• Title/Summary/Keyword: PHR

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Flame Retardancy and Electrical Characteristics of LDPE/EVA Blend Involving Mg(OH)2 and Zinc-borate

  • Ryu, Boo-Hyung;Kim, Gyu-Baek;Jung, Sang-Ho;Cho, Young-Suk
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.6
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    • pp.309-312
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    • 2006
  • This study shows to blend ethylene vinyl acetate(EVA) and a flame retardant agent, $Mg(OH)_{2}$, and synergists, zinc borate for improving flame retardancy of low density polyethylene(LDPE). And it studied the property of flame retardancy of LDPE/EVA blend by the amount of addition through LOI and TGA, estimated the electrical characteristics such as volume resistivity and breakdown strength. The flame retardancy of LDPE/EVA blend was much improved in case of adding zinc borate with 6phr degree, and the electrical characteristics were more or less decreased depending on increasing the amount of addition. Zinc borate used for improving the flame retardancy of LDPE/EVA blend let the added amount of a flame retardant agent, $Mg(OH)_{2}$ limited, and the electrical characteristics decreased extremely by adding a good deal of $Mg(OH)_{2}$.

Recycling of Waste Rubber by De-link System (I) (De-link R를 이용한 폐고무 재활용(I))

  • Hwang, Sung-Hyuk;Hong, John-Hee;Yoo, Tae-Uook;Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.79-85
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    • 2001
  • It goes to be serious with environmental pollution cause waste rubber. That is why there are lot of studies for efficient recycle. The purpose of this study is to improve the physical properties of EPDM powder by using De-link system. We changed on the size of waste rubber powder and De-link contents. we examined the physical, rheological, mechanical properties. And also examined cross-link state at various De-link. Also we carried out morphological studies after making the weather strip's feature by optical microscope.

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The Effect of $SiO_2$ Affect to Thermally Stimulated Current of Insulating Silicone Rubbers (절연용 실리콘 고무의 열자격 전류에 미치는 $SiO_2$의 영향)

  • 이성일
    • Journal of the Korean Society of Safety
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    • v.11 no.2
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    • pp.60-66
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    • 1996
  • In order to look into the internal structure and electrical properties of insulating Silicone rubbers added reinforcing fillers ; Silica(0-140 phr ), and to examine the behavior of charged particles, and the properties of thermally stimulated current (TSC) are investigated, respectively. From the TSC which are formed by applying the electric field of 2~5 ㎸/mm to specimen at temperature range from -150 to $270^{\circ}C$, the results arp as following. In the case of non-filled specimen, four peaks of $\delta$, $\gamma$ , $\beta$ and u are obtained at the temperature of $-120^{\circ}C$, $-60^{\circ}C$, $20^{\circ}C$ and $130^{\circ}C$, respectively and the case of filled specimen, three peaks of $\delta$, ${\alpha}_2$ and ${\alpha}_1$ are observed at the temperature of of $-120^{\circ}C$, $80^{\circ}C$ and $130^{\circ}C$, respectively. The origins of these peaks are that, the $\delta$ peak seems to the result from the contribution of side chain methyl radical, and the $\beta$ peak from the depolarization of space charge polarization owing to added imputity during during manufacturing specimens, and the $\beta$ peak from the orientation of $Si-CH_3$dipole, and the ${\alpha}_2$ near the temperature of $130^{\circ}C$ from carboxyl acid that is formed by the thermal oxidation of high temperature.

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AC Electrical and Mechanical Properties of Epoxy-Nano-Microsilica Mixed Composites for Eco-Friendly GIS Spacer (친환경 GIS Spacer용, 에폭시-나노-마이크로실리카 혼합 콤포지트의 교류 전기적, 기계적 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.9
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    • pp.1181-1188
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    • 2018
  • In order to develop new insulating materials for GIS Spacer using environmentally friendly insulating gas, three kinds of dispersed liquid nano composites of solid epoxy /nano layered silicate filled material were prepared. And the epoxy/nano/micro silica composite was prepared by mixing epoxy/nano 3 phr dispersion/4 kinds of filler contents(40,50,60, 70wt%). The electrical insulation breakdown strengths of the nano and nano/micro mixed composites were evaluated by using 8 kinds of samples including the original epoxy. The mechanical tensile strength of the epoxy / nano / micro silica composite were evaluated, also. The TEM was measured to evaluate the internal structure of nano/micro composites. As a result, it was confirmed that the layered silicate nano particles was exfoliated through the process of inserting epoxy resin between silicate layers and the layers. In addition, dispersion of nano / micro silica resulted in improvement of electrical insulation breakdown strength with increase of filling amount of dense tissue with nanoparticles inserted between microparticles. In addition, the tensile strength showed a similar tendency, and as the content of microsilica filler increased, the mechanical improvement was further increased.

The Change of the Cyclic Aging Characteristics under Salt-fog/Heating on Silicone Rubber by ATH Additions (ATH 첨가에 의한 실리콘 고무의 염무/열 반복열화 특성 변화)

  • Lee, Chung;Kim, Ki-Yup;Kim, Gyu-Baek;Ryu, Boo-Hyung
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.58-63
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    • 2005
  • In this research, silicone rubber with additions of inorganic filler, alumina trihydrate$(Al(OH)_3\;:\;ATH)$, was aged acceleratedly and cyclically by the salt-fog and heating. The optimum amount of ATH addition to silicone rubber have been investigated by measurements of leakage current in the change of electrical properties and tensile strength, %elongation in mechanical properties and FT-IR, TG, SEM in the change of the chemical properties. With regard to un-aged silicone rubber, as the ATH addition amount increases, conductive path formation time was shortened in the electrical properties and tensile strength was increased, %elongation was decreased. In case of identical ATH addition amount, as cyclic aging increases, surface resistivity, tensile strength and %elongation were decreased. Considering the cyclic aging, the most effective amount of ATH addition was about 90phr.

Cure Behaviors and Physical Properties of Recycled/Virgin Nitrile Rubber (NBR) Blends by High Temperature Shear-Crushing Technique (고온전단분쇄기술을 이용한 재생/신재 니트릴고무(NBR) 블렌드물의 가황거동 및 물리적 특성)

  • Park, Hyun-Ho;Kim, Joon-Hyung;Lee, Chang-Seop;Na, Seong-Taek
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.842-847
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    • 2005
  • Virgin NBR and recycled NBR particles, which were pulverized from NBR scraps by high temperature shear-crushing technique, were blended with different mixing ratio. The effects of the recycled NBR content on the cure characteristics and physical properties of these blends were investigated and resistance properties of these blends to heat and various fluids were also studied. The study of cure characteristics showed that the viscosity increased but the scorch time decreased. The physical properties of rubber blends were improved with the addition of the recycled NBR for heat resistance and various fluid tests.

Effect of Synthetic Hydrotalcite on Salt Water Resistance of Chloroprene rubber Foam (Synthetic Hydrotalcite가 클로로프렌 고무 발포체의 내염수성에 미치는 영향 연구)

  • Park, Eun Young;Seo, Eun Ho;Lim, Sung Wook
    • Textile Coloration and Finishing
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    • v.31 no.3
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    • pp.177-186
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    • 2019
  • In this study, we investigated for synthetic hydrotalcite in chloroprene rubber foam. Experiments were carried out to find the optimum content ratio by controlling the contents of MgO and Hydrotalcite. Swelling test in toluene immersion was made to measure the crosslinking density of CR foams, and the cure properties were investigated with flat die rheometer and Mooney viscosity. The difference of hardness, tensile strength and elongation at break were observed after immersing in 7% NaCl or 21% NaCl solutions for a day and four days. In addition, the volume change and water content remaining in CR foam were measured after immersing NaCl solution. As content of MgO increased, the value of the cure torque tended to increase, but it was almost constant above 2phr of MgO. However, the Mooney viscosity decreased with increasing MgO content. The crosslinking density, determined by the swelling ratio, showed that the CR compound without MgO showed a higher degree of swelling. When the content of hydrotalcite/MgO was 3:2, it was the lowest volume change of CR form. Also, As the content of hydrotalcite decreased, the difference of mechanical properties before and after immersion NaCl solution increased.

A Study on the Manufacturing and Physical Properties of Conducting Rubber (II) -Barium ferrite System Conducting Rubber- (전도성(導電性)고무의 제조(製造) 및 물성(物性)에 관한(關)한 연구(硏究) (II) -Barium Ferrite 혼합계(混合系) 도전성(導電性)고무-)

  • Lee, Young-Man;Yun, Ju-Ho;Choi, Sei-Young
    • Elastomers and Composites
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    • v.30 no.3
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    • pp.218-228
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    • 1995
  • To make filler loaded conducting rubber which has excellent electronical and physical properties, CR and NBR were mixed with barium ferrite(BaO.6Fe2O3). From the result of this study, vulcanization characteristics shows that curve is upgraded as the filler concentration increases and CR has higher torque than NBR. In physical properties, elongation being higher, modulus comes to decrease. Tear strength gradually decrease after showing the maximum point when is in the 100phr in CR. Resilience is not good to cause the increase in filler concentration. In electrical properties, conductivity becomes low when filler concentration increase. The increase of voltage makes a conductivity grown, but the rate change is weak. The influence of temperature hardly changes on increasing temperature. The morphology and the dispersion of a conductivity filler in vulcanizates through SEM were good. The more filler concentration increases, the shorter the particle interval is.

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Planar Hall Sensor Used for Microbead Detection and Biochip Application

  • Thanh, N.T.;Kim, D.Y.;Kim, C.G.
    • Journal of Magnetics
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    • v.12 no.1
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    • pp.40-44
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    • 2007
  • The Planar Hall effect in a spin valve structure has been applied as a biosensor being capable of detecting $Dynabeads^{(R)}$ M-280. The sensor performance was tested under the application of a DC magnetic field where the output signals were obtained from a nanovoltmeter. The sensor with the pattern size of $50{\times}100{\mu}m^2$ has produced high sensitivity; especially, the real-time profiles by using that sensor revealed significant performance at external applied magnetic field of around 7.0 Oe with the resolution of 0.04 beads per $\mu m^2$. Finally, a successful array including 24 patterns with the single sensor size of $3{\times}3{\mu}m^2$ has shown the uniform and stable signals for single magnetic bead detection. The comparison of this sensor signal with the others has proved feasibility for biosensor application. This, connecting with the advantages of more stable and high signal to noise of PHR sensor's behaviors, can be used to detect the biomolecules and provide a vehicle for detection and study of other molecular interaction.

Preparation and Characterization of Biodegradable Poly(butylene succinate)(PBS) Foams

  • Lim, Sang-Kyun;Jang, Suk-Goo;Lee, Seok-In;Lee, Kwang-Hee;Chin, In-Joo
    • Macromolecular Research
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    • v.16 no.3
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    • pp.218-223
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    • 2008
  • In order to obtain crosslinked poly(butylene succinate) (PBS) foams with a closed-cell structure, a commercial-grade PBS was first modified in the melt using two different branching agents to increase the melt viscosity. The rheological properties of the branched and crosslinked PBS were examined by varying the amount of the branching agents. The complex viscosity of the crosslinked PBS increased with increasing amount of the branching agent. However, it decreased with increasing frequency. When 2 phr of the branching agent was added to PBS, the storage modulus (G') was higher than the loss modulus (G") throughout the entire frequency range, showing that the addition of a branching agent increases the melt viscosity and elasticity of PBS effectively. Closed-cell PBS foams were prepared by mixing the chemical blowing agent with the crosslinked PBS. The effect of the foaming conditions such as temperature and time, and the amount of the crosslinking agent on the structure of the expanded PBS foams were also investigated.